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| 1 | New Catalysts for Coal to Ethylene Glycol显示文摘 | Zhiqiao Wang Zhongning Xu Siyan Peng Zhangfeng Zhou Pengbin Pan Lin Lin Yeyan Qin Guocong Guo Yuangen Yao | 2017 | Chinese Journal of Chemistry2017,35,6: | 6 |
| 2 | New methyl formate synthesis method:Coal to methyl formate显示文摘Methyl formate is one of the most important intermediates in C1 chemistry, which has been employed in a wide range of industrial applications. Current synthesis methods for methyl formate mainly include esterification of methanol and formic acid, liquid-phase methanol carbonylation, oxidative dehydrogenation of methanol, one-step syngas synthesis, and carbon dioxide hydrogenation and condensation with methanol. Liquid-phase methanol carbonylation is currently a main commercially viable process developed by BASF Corp. for the industrial production of methyl formate. Recently, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences has developed a new synthesis method to convert coal to methyl formate(denoted as CTMF). Different from the liquid-phase methanol carbonylation using homogeneous catalysts, CTMF method features with vapor-phase methanol carbonylation using heterogeneous nanocatalysts, which can effectively utilize the coal-based syngas and produce value-added fine chemicals(i.e., methyl formate). The newly developed method not only provides a new methyl formate synthesis technology but also contributes to the development of strategies for synthesizing valuable chemicals from coal. In this review, we firstly provide introduction on the development of existing methyl formate synthesis methods and then highlight the research progress of CTMF method. Finally, a perspective on the future of CTMF is given. | Lingyun Rong Zhongning Xu Jing Sun Guocong Guo | 2018 | Journal of Energy Chemistry2018,27,1: | 3 |
| 3 | Syntheses,structures and properties of five chiral quaternary sulfides,AlxLn_3(Si_yAl_(1-γ))S_7 (Ln=Y,Gd,Dy) and In_(0.33)Sm_3SiS_7显示文摘Five new quaternary isostructural rare-earth sulfides, Al0.57Gd3(Si0.27Al0.73)S7 (1), Al0.55Dy3(Si0.34Al0.66)S7 (2), Al0.50Y3(Si0.50Al0.50)S7 (3), Al0.44Gd3(Si0.70Al0.30)S7 (4) and In0.33Sm3SiS7 (5), have been synthesized by facile solid-state reactions. They crystallize in the 3-D ALn3EQ7 structure type in the hexagonal chiral space group P63. The structures feature a 3-D host framework constructed by Ln-S bicapped trigonal prisms, in which the octahedral and tetrahedral interspaces are occupied by A and E atoms, respectively. The investigation of optical and magnetic properties of 4 indicates that it is a semiconductor and behaves antiferromagnetic-like interaction. | GUO ShengPing, GUO GuoCong & HUANG JinShun State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China | 2009 | Science China Chemistry2009,52,10: | 2 |
| 4 | Cross-layer optimization for OFDM wireless networks-part II: algorithm develop- ment显示文摘 | Song Guocong Li Ye | 2005 | IEEE Transaction on Wireless Communica- tions2005,4,2: | 1 |
| 5 | Al-doped TiO2 mesoporous materials: synthesis and photodegradation properties显示文摘 | Shaoyou Liu Guocong Liu Qingge Feng | 2010 | Journal of Porous Materials2010,,2: | 1 |
| 6 | Cross-Layer optimization for OFDM wireless network-Part Ⅰ:theoretical framework显示文摘 | Song Guocong Li Ye | | 0,,02: | 1 |
| 7 | Cross-layer optimization for OFDM wireless networks: part Ⅱ: algorithm development 显示文摘 | SONG GUOCONG LI Ye | 2005 | IEEE Trans Wireless Commun2005,4,2: | 1 |
| 8 | Two-phase flow and heat transfer显示文摘 | Yu Guocong Yuan Xigang Dong Guoqiang | 1992 | ISME1992,,2: | 1 |
| 9 | The simulation of liquid distribution based on Markov process 显示文摘 | Zhang Zeting Yu Guocong | 1990 | J Chem Ind And Eng1990,5,1: | 1 |
| 10 | A new mathematical model for mass transfer in a packed column 显示文摘 | Zhang Zeting Wang Shuying Yu Guocong | 1990 | J Chem Ind And Eng1990,5,2: | 1 |
| 11 | Illuminations for constructions of scintillating lanthanide–organic complexes in sensitive X-ray detection and high-resolution radiative imaging显示文摘X-ray detection and imaging via scintillators has been utilized in missions worldwide within areas of scientific research,medical industry,military defense and homeland security.Commercial scintillators are costly with high energy consumption through the sintering.It is of great significance to seek alternative scintillating materials for sensitive X-ray detection in the next-generation.Herein,eight structure-defined Ln(Ⅲ)-based metal-organic frameworks(Ln-MOFs)were prepared,2D[Ln_(2)(1,4-ndc)_(3)(DMF)_(4)]_(n)·nH_(2)O(Ln=Sm 1,Eu 2,Dy 3,Tb 4)and 3D[Ln_(4)(2,6-ndc)_(6)(μ_(2)H_(2)O)2(H_(2)O)_(4)]n·2nH_(2)O(Ln=Sm 5,Eu 6,Dy 7,Tb 8),where 1,4-H_(2)ndc=1,4-naphthalene dicarboxylate acid,2,6-H_(2)ndc=2,6-napthalene dicarboxylate acid,DMF=N,N-dimethylformamide.Merely compounds 2 and 6 show remarkable X-ray scintillation performance via the characteristic red emissions of Eu(Ⅲ)ions,in which the absorbed energy from the triplet states of the organic moieties can be transferred more efficiently to the resonance emission levels of Eu(Ⅲ)ions than other lanthanide(Ⅲ)ions.The X-ray dosage rate detection limits of 2 and 6 are superior to the standard for the medical X-ray diagnosis dosage rate.As proofs-of-concepts,matrix-mixed membranes fabricated with 2 and 6 have achieved remarkable X-ray imaging with high resolution for practical object shooting. | Juan Gao Jian Lu Baoyi Li Wenfei Wang Meijuan Xie Shuaihua Wang Fakun Zheng Guocong Guo | 2022 | Chinese Chemical Letters2022,33,12: | 1 |
| 12 | A grain boundary defect modle for ZnO ceramic varistors by deep heat treatment显示文摘 | CHEN Zhixiong LIN Guocong FU Gang | 1998 | Science in China(Series A)1998,41,1: | 1 |
| 13 | Solid-liquid phase equilibria of musk ketone, musk xylene and 1,3-dimethyl-2,4-dinitro-5-tert-butyl benzene显示文摘 | Qu Hongmei Bai peng Yang Zhicai and Yu guocong | 2004 | Chinese J Chem Eng2004,12,2: | 1 |
| 14 | Cross-layer Optimization for OFDM Wireless Networks-Part I: Theoretical Framework 显示文摘 | SONG Guocong LI Ye | 2005 | IEEE Transactions on Wireless Communications2005,4,1: | 1 |
| 15 | Synthesis and characterization of monoclinic BiVO4 nanorods and nanoplates via microemulsion-mediated hydrothermal method显示文摘 | Li Haibin Liu Guocong | 2011 | Physica E: Low-dimensional Systems and Nanostructures2011,43,7: | 1 |
| 16 | Cross-layer optimization for OFDM wireless networks-part Ⅰ:theoretical framework显示文摘 | Song Guocong Li Ye | 2005 | IEEE Trans on Wireless Comm2005,4,2: | 1 |
| 17 | Utility-based resource allocation and scheduling in OFDM-based wireless broadband networks显示文摘 | Song Guocong Li Ye | 2005 | IEEE Commun Mag2005,43,12: | 1 |
| 18 | Al-doped TiO 2 mesoporous materials: synthesis and photodegradation properties显示文摘 | Shaoyou Liu Guocong Liu Qingge Feng | 2010 | Journal of Porous Materials2010,,2: | 1 |
| 19 | Cross-layer optimization for OFDM wireless networks-Part II:algorithm development显示文摘 | GUOCONG S YE L | 2005 | IEEE Transactions on Wireless Communications2005,4,2: | 1 |
| 20 | Adsorptive distillation-novel hybrid separation process显示文摘 | Zhou Ming Xu Chunjian Yu Guocong | 1996 | progress in Natural Science1996,5,3: | 1 |