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3篇 您的检索式:作者名="Guo Hengjun"
    题名 作者 年代 出处 被引量
1Conceptual design of an extractive distillation process for the separation of azeotropic mixture of n-butanol-isobutanol-water显示文摘In many chemical processes, large amounts of wastewater containing butanol and isobutanol are produced.Given that n-butanol-isobutanol-water can form triple azeotrope, high-purity butanol cannot be recovered from the wastewater by ordinary distillation. To economically and effectively recover butanol from this kind of wastewater, 1,4-butanediol is selected as an extractant to break the formation of the azeotropes, and a doubleeffect extractive distillation process is proposed. The conceptual design of the proposed process is accomplished based on process simulation. With the proposed process, the purity of recovered butanol and water is greater than 99.99 wt%. In comparison with the conventional azeotropic distillation process, economic analysis shows that the operating cost of the proposed process is lower: when the capacity of wastewater treatment is 100 t·h^(-1), the total operating cost decreases by 5.385 ×10~6 USD per year, and the total annual cost of the new process decreases by 5.249 ×10~6 USD per year. In addition, in the extractive distillation system, variable effects on separation purities and cost are more complex than those in the ordinary distillation system. The method and steps to optimize the key variables of the extractive distillation system are also discussed in this paper and can provide reference for similar studies.Hengjun Gai Kaiqiang Lin Yirong Feng Meng Xiao Kai Guo Hongbing Song 2018Chinese Journal of Chemical Engineering2018,26,10:5
2Template-free synthesis of hollow TiO2 nanospheres supported Pt for selective photocatalytic oxidation of benzyl alcohol to benzaldehyde显示文摘Heterogeneous photocatalytic system are widely applied to degrade organic pollutants or converse into high value-added chemicals. Both environmental and energy aspects should be considered to improve these chemical processes, favoring reaction conditions that involve room temperature and ambient O2 pressure. In the present work, hollow titanium dioxide nanospheres were fabricated via template-free method. The prepared samples were characterized by X-ray diffraction, N2 adsorption–desorption isotherms, transmission electron microscopy, and X-ray photoelectron spectroscopy. The photocatalytic activity was evaluated by photocatalytic oxidation of benzyl alcohol to benzaldehyde with visible light under atmospheric pressure at room temperature. The designed hollow structure(2%Pt–TiO2–5) not only exhibited a very high surface area,but also promoted photonic behavior and multiple light scattering, which as an efficient photocatalyst performed moderate conversion(about 20%) and high selectivity(> 99%) for oxidation of benzyl alcohol to benzaldehyde at room temperature with visible light in solvent of toluene.This work suggests that both hollow structure and Pt nanoparticles have great potential for execution of oxidative transformations under visible light.Hongbing Song Zong Liu Yongjie Wang Na Zhang Xiaofei Qu Kai Guo Meng Xiao Hengjun Gai 2019Green Energy & Environment2019,4,3:2
3Effect of low temperature stress on the protective-enzyme activity of grafted cucumber seedling and own-root cucumber seedling显示文摘Feng Xin Yu Xianchang Guo Hengjun 2002Journal of Shan Dong Agricultural University(Natural Science)2002,33,3:1
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