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1篇 您的检索式:作者名="G.Karthick"
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1Phase evolution and mechanical properties of novel nanocrystalline Y_(2)(TiZrHfMoV)_(2)O_(7) high entropy pyrochlore显示文摘High entropy pyrochlores(HEP)are potential candidates as dispersoids in the oxide dispersed strengthened steels or alloys,which can be used in nuclear reactors and supercritical boilers.For the first time,HEP oxides Y_(2)(TiZrHfMoV)_(2)O_(7) were synthesized with Y_(2)Ti_(2)O_(7) as a base structure with the B site(Ti)substituted with five cations through reverse co-precipitation technique in the nanocrystalline form at lowest synthesis temperature.The synthesis parameters for Y_(2)(TiZrHfMoV)_(2)O_(7)(5C)and other derived compositions(five compositions of four cationic systems with each cation eliminated at B site from 5 C)are optimised to obtain lower crystallite and particle sizes.5C has a smaller crystallite size(27 nm)than other single-phase compositions.The cation’s influence,oxidation state,and oxygen vacancy in the phase formation were analysed through XPS.The single-phase HEPs are consolidated through spark plasma sintering.Y_(2)(TiZrHfMo)_(2)O_(7)(4 C-V)shows the highest hardness among the compositions reported so far due to its finer grain size,and Y_(2)(TiHfMoV)_(2)O_(7)(4 C-Zr)has a higher Young’s modulus compared to other single-phase composition due to its higher degree of order in the structure.G.Karthick Lavanya Raman B.S.Murty 2021Journal of Materials Science & Technology2021,,23:2
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