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1篇 您的检索式:作者名="FENG Menran"
    题名 作者 年代 出处 被引量
1Self-assembly of Gradient Copolymer Synthesized by Spontaneous Batch RAFT Emulsion Polymerization and Its Application on Encapsulating Ag Nanoparticles显示文摘The gradient copolymers of acrylic acid and trifluoroethyl methacrylate(coded as P(TFEMAgrad-AA)) were synthesized via reversible addition-fragmentation transfer(RAFT) emulsifier-free emulsion polymerization. The spontaneous batch feeding approach was used to control the gradient chain sequence. Transmission electron microscopy(TEM) analysis revealed that the P(TFEMA-grad-AA) can self-assemble to form spherical micelles, rodlike micelles or vesicles in selective solvents. Morphological transition of the P(TFEMA-grad-AA) micelles was sensitive to the water content of the dioxane/water mixed solvent. More interestingly, Ag nanoparticles(NPs) were encapsulated by the P(TFEMA-grad-AA) micelles during the selfassembly process. The gradient chain sequence made the Ag NPs easily enter the core of the micelles, even when P(TFEMA-grad-AA) had less hydrophobic fluoro-units and more hydrophilic units. TEM images with energy dispersive spectrometer indicated that the nanocomposite micelles consisted of a Ag NPs core and a gradient copolymer shell.秦超然 FENG Menran LUO Wen LIU Mingyang HAN Mei MA Shuai 王艺峰 2018Journal of Wuhan University of Technology(Materials Science)2018,33,4:0
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