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| 1 | Study of simulation experiments on the TSR system and its effect on the natural gas destruction显示文摘The TSR process may be one of the reasons to result in the natural gas destruction in deep carbonate reservoirs. The work on this field has been the subject of much research in recent years. In this paper, thermal simulation experiments on the reaction of CH4-CaSO4 were carried out using autoclave at high temperature and high pressure. The products were charac-terized by some advanced analytical methods. The thermodynamics and kinetics were discussed and the reaction mechanism was investigated tentatively. It is found that the reaction can pro-ceed spontaneously to produce H2S, H2O and CaCO3 as the main products at the temperature range of 550―700℃ . The activation energy and geological reaction rate calculated from the ki-netic model can be compared with those from previous work. The results obtained in this paper can provide important information on the explanation of geochemical depth limit for natural gas and on the exploration of gas reservoirs. | YUE Changtao LI Shuyuan DING Kangle ZHONG Ningning | 2005 | Science China Earth Sciences2005，48，8： | 8 |
| 2 | Simulation experiments on the reaction system of CH_4-MgSO_4-H_2O显示文摘H2S-rich gas in carbonate reservoirs is usually attributed to thermochemical sulfate reduction (TSR). In this paper, thermal simulation experiments on the reaction system of CH4-MgSO4-H2O were carried out using autoclave at 425℃―525℃. The threshold temperature for initiating TSR is much lower than our previous studies (550 ℃ ). Properties of the reaction products were analyzed by microcoulometry, gas-chromatography (GC), Fourier transform-infrared spectrometry (FT-IR) and X-ray diffraction (XRD) methods. Thermodynamics and reaction kinetics of TSR processes were investigated on the basis of the experimental data. The results show that thermochemical reduction of magnesium sulfate with methane can proceed spontaneously to produce magnesium oxide, hydrogen sulfur, and carbon diox-ide as the main products, and high temperature is thermodynamically favorable to the reaction. Ac-cording to the reaction model, the calculated activation energy of TSR is 101.894 kJ/mol, which is lower than that by most previous studies. Mg2+ may have played a role of catalytic action in the process of TSR. The elementary steps of TSR and reaction mechanism were discussed tentatively. The study can provide important information on the explanation of geochemical depth limit for natural gas and on the generation of high H2S gas in deep carbonates reservoirs. | DING KangLe LI ShuYuan YUE ChangTao ZHONG NingNing | 2008 | Chinese Science Bulletin2008，53，7： | 3 |
| 3 | Pyrite-hydrocarbon Interaction under Hydrothermal Conditions: an Alternative Origin of H_2S and Organic Sulfur Compounds in Sedimentary Environments显示文摘Sulfate rocks and organic sulfur from sedimentary organic matter are conventionally assumed as the original sulfur sources for hydrogen sulfide(H_2S) in oil and gas reservoirs. However,a few recent experiments preliminarily indicate that the association of pyrite and hydrocarbons may also have implications for H_2S generation,in which water effects and natural controls on the evolution of pyrite sulfur into OSCs and H_2S have not been evaluated. In this study,laboratory experiments were conducted from 200 to 450° C to investigate chemical interactions between pyrite and hydrocarbons under hydrothermal conditions. Based on the experimental results,preliminary mechanism and geochemical implications were tentatively discussed. Results of the experiments showed that decomposition of pyrite produced H_2S and thiophenes at as low as 330°C in the presence of water and n-pentane. High concentrations of H_2S were generated above 450°C under closed pyrolysis conditions no matter whether there is water in the designed experiments. However,much more organic sulfur compounds(OSCs) were formed in the hydrous pyrolysis than in anhydrous pyrolysis. Generally,most of sulfur liberated from pyrite at elevated temperatures was converted to H_2S. Water was beneficial to breakdown of pyrite and to decomposition of alkanes into olefins but not essential to formation of large amounts of H_2S,given the main hydrogen source derived from hydrocarbons. In addition,cracking of pyrite in the presence of 1-octene under hydrous conditions was found to proceed at 200°C,producing thiols and alkyl sulfides. Unsaturated hydrocarbons would be more reactive intermediates involved in the breakdown of pyrite than alkanes. The geochemistry of OSCs is actually controlled by various geochemical factors such as thermal maturity and the carbon chain length of the alkanes. This study indicates that the scale of H_2S gas generated in deep buried carbonate reservoirs via interactions between pyrite and natural gas should be much smaller than that of thermochemical sulfate reduction(TSR) due to the scarcity of pyrite in carbonate reservoirs and the limited amount of long-chained hydrocarbons in natural gas. Nevertheless,in some cases,OSCs and/or low contents of H_2S found in deep buried reservoirs may be associated with the deposited pyrite-bearing rock and organic matters(hydrocarbons),which still needs further investigation. | DING Kangle MEI Ping LUO Yue | 2016 | Acta Geologica Sinica(English Edition)2016，90，6： | 2 |
| 4 | Thermodynamics and kinetics of reactions between C1-C3 hydrocarbons and calcium sulfate in deep carbonate reservoirs显示文摘 | Yue Changtao Li Shuyuan Ding Kangle | 2006 | Geochemistry2006，40，1： | 1 |
| 5 | A Study Into the Causes of the Dispute in China's Rural Areas显示文摘 | Kangle Ding Jingsheng Li | 2015 | Journal of Sociology Study2015，5，5： | 0 |
| 6 | Experimental,Thermodynamic and Kinetic Studies for the Adsorption of Phenolic Compounds Derived from Oilfield Wastewater by the Corncob Hydrochar显示文摘The corncob hydrochar is prepared by using a stainless autoclave at 230?C for 8 h.The products are characterized by elemental analyzer,Fourier Transform infrared spectroscopy(FT-IR),X-ray diffraction(XRD)and scanning electron microscope(SEM).The effects of hydrochar dosage,pH,adsorption time and phenol concentration on the adsorption performance of hydrochar are investigated by means of single-factor experimental analysis.Based on the experiments the adsorption thermodynamic and kinetics are tentatively discussed.The results show that abundant oxygen-containing functional groups are scattered on the surface of the corncob hydrochar.The adsorption kinetics of phenol on the hydrochar corresponds well with pseudo-second-order kinetic model.Thermodynamic studies indicate that Freundlich adsorption isotherm model is much better than Langmuir model in describing the adsorption of phenol on the corncob hydrochar at 25?C-45?C.This study provides scientific basis for the development of cheap and efficient adsorbents for the removal of phenols derived from oilfield wastewater. | Liangcheng Xie Kangle Ding Yan Liu Mei Zou Chao Han | 2019 | Open Journal of Yangtze Oil and Gas2019，4，4： | 0 |
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