1篇
您的检索式：作者名="Cunmeng Lin"
|
|
|
题名
|
作者
|
年代
|
出处
|
被引量
|
| 1 | DL-Serine covalently modified multinuclear lanthanide-implanted arsenotungstates with fast photochromism显示文摘A series of DL-serine covalently modified multinuclear lanthanide implanted arsenotungstates K_(2)[{Ln(H_(2)O)_(7)}_(2){As_(4)W_(44)O_(137)(OH)_(18)(H_(2)O)_(2)(DL-Ser)_(2)}{Ln_(2)(H_(2)O)_(5)(DL-Ser)}_(2)]·65H_(2)O(DL-Ser=DL-serine,Ln=La(1),Ce(2),Pr(3))are obtained.Crystal structure analysis shows that these compounds are isomorphic and contain the basic[{As_(4)W_(44)O_(137)(OH)_(18)(H_(2)O)_(2)(DL-Ser)_(2)}{Ln_(2)(H_(2)O)_(5)(DL-Ser)}_(2)]^(8–)polyoxoanion constituted by two{As_(2)W_(19)O_(59)(OH)_(8)(H_(2)O)}^(6–)subunits,a[W_(6)O_(2)_(3)(OH)_(2)(DL-Ser)_(2)]_(14)–fragment,and two embedded[Ln_(2)(H_(2)O)_(5)(DL-Ser)]^(5+)groups,which further build into one dimensional linear chainlike structure via two peripheral Ln^(3+)ions.Most remarkably,these compounds exhibit rapid photochromic behaviors,which changed color quickly from white(1),yellow(2),green(3)to blue(1),brown(2)and glaucous(3)in ten minutes under UV irradiation,and that the colors gradually recovered in the dark for approximately 22 h. | Kangting Zheng Bingxue Niu Cunmeng Lin Yizhen Song Pengtao Ma Jingping Wang Jingyang Niu | 2023 | Chinese Chemical Letters2023，34，2： | 0 |
您所在的机构暂未开通此部分的功能，请联系管理员