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您的检索式：作者名="Cuiling GAO"
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| 1 | Construction of PS/PNIPAM core-shell particles and hollow spheres by using hydrophobic interaction and thermosensitive phase separation显示文摘This paper reports an easy and effective way to fabricate polystyrene/poly(N-isopropylacrylamide)(PS/PNIPAM)core-shell particles and PNIPAM hollow spheres.The main point of the method is to take advantage of the hydrophobic interaction between initiator and PS particles.The hydrophobic azodiisobutyronitriles automatically concentrate around the PS particles and initiate polymerization of N-isopropylacrylamide(NIPAM)and the crosslinkermethylene bisacrylamide(MBA),which dissolve in the aqueous phase,at the surface of the PS nanoparticles.Then,PNIPAM adheres to the PS particles to form a coreshell structure as a result of their hydrophobic interaction.This interaction is due to the unique property of PNIPAM,namely,its ability to transition from hydrophilic to hydrophobic when the temperature rises to 32℃.Furthermore,the hollow PNIPAM spheres were obtained by etching the PS core with chloroform. | Dongmei ZHU Fei WANG Cuiling GAO Zheng XU | 2008 | Frontiers of Chemical Science and Engineering2008，2，3： | 1 |
| 2 | Entropy-driven self-assembly of tethered Janus nanoparticles on a sphere显示文摘Understanding the effect of curvature and topological frustration on self-assembly yields insight into the mechanistic details of the ordering of identical subunits in curved spaces,such as the assembly of viral capsids,growth of solid domains on vesicles,and the self-assembly of molecular monolayers.However,the self-assembly of nanoparticles with anisotropic surface topology and compartmentalization on curved surfaces remains elusive.By combining large-scale molecular simulations as well as theoretical analysis,we demonstrate here that the interplay among anisotropy,curvature,and chain conformation induces tethered Janus nanoparticles to self-assemble into diverse novel structures on a sphere,including binary nanocluster(C_(B)),trinary nanocluster(C_(T)),nanoribbon(R_(N))and hexagon with centered reverse(HR),which are mapped on a phase diagram related to the length asymmetry of tethered chains and Janus balance of the nanoparticles.The dynamical mechanism for the formation of these structure states is analyzed by examining the detailed kinetic pathways as well as free energy.We also show that the centered-reverse state is more prone to emerging around the topological defects,indicating the defect-enhanced entropy effect on a curved surface.Finally,the analytical model that rationalizes the regimes of these structure states is developed and fits simulations reasonably well,resulting in a mechanistic interpretation based on the order through entropy.Our findings shed light on curvature engineering as a versatile strategy to tailor the superstructures formed by anisotropic building blocks toward unique properties. | Guolong Zhu Yuming Wang Lijuan Gao Ziyang Xu Xuanyu Zhang Xiaobin Dai Lijun Dai Cuiling Hou Li-Tang Yan | 2021 | Fundamental Research2021，1，5： | 0 |
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