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1The Auxin-Regulated Protein ZmAuxRPI Coordinates the Balance between Root Growth and Stalk Rot Disease Resistance in Maize显示文摘To optimize fitness, plants must efficiently allocate their resources between growth and defense. Although phytohormone crosstalk has emerged as a major player in balancing growth and defense, the genetic basis by which plants man age this balance remai ns elusive. We previously ide ntified a quantitative disease . resistance locus, qRfg2, in maize (Zea mays) that protects against the fungal disease Gibberella stalk rot. Here, through map-based cloning, we demonstrate that the causal gene at qRfg2 is ZmAuxRPI, which encodes a plastid stroma-localized auxin-regulated protein. ZmAuxRPI responded quickly to pathogen challenge with a rapid yet transient reduction in expression that led to arrested root growth but enhanced resista nee to Gibberella stalk rot and Fusarium ear rot. ZmAuxRPI was show n to promote the biosynthesis of indole-3-acetic acid (IAA), while suppressing the formation of benzoxazinoid defense compounds. ZmAuxRPI presumably acts as a resource regulator modulating indole-3-glycerol phosphate and/or indole flux at the branch point between the IAA and benzoxazinoid biosynthetic pathways. The concerted interplay between IAA and benzoxazinoids can regulate the growth-defense balance in a timely and efficient manner to optimize plant fitness.Jianrong Ye Tao Zhong Dongfeng Zhang Chuanyu Ma Lina Wang Lishan Yao Qianqian Zhang Mang Zhu Mingliang Xu 2019Molecular Plant2019,12,3:19
2Combined genome-wide association study and transcriptome analysis reveal candidate genes for resistance to Fusarium ear rot in maize显示文摘Fusarium ear rot,caused by Fusarium verti-cillioides,is a devastating fungal disease in maize that re-duces yield and quality;moreover,F.verticillioides pro-duces fumonisin mycotoxins,which pose serious threats to human and animal health.Here,we performed a genome-wide association study(GWAS)under three en-vironmental conditions and identified 34 single-nucleotide polymorphisms(SNPs)that were significantly associated with Fusarium ear rot resistance.With reference to the maize B73 genome,69 genes that overlapped with or were adjacent to the significant SNPs were identified as potential resistance genes to Fusarium ear rot.Comparing transcriptomes of the most resistant and most susceptible lines during the very early response to Fusarium ear rot,we detected many differentially expressed genes enriched for pathways related to plant immune responses,such as plant hormone signal transduction,phenylpropanoid bio-synthesis,and cytochrome P450 metabolism.More than one-fourth of the potential resistance genes detected in the GWAS were differentially expressed in the tran-scriptome analysis,which allowed us to predict numbers of candidate genes for maize resistance to ear rot,in-cluding genes related to plant hormones,a MAP kinase,a PR5-like receptor kinase,and heat shock proteins.We propose that maize plants initiate early immune responses to Fusarium ear rot mainly by regulating the growth-defense balance and promoting biosynthesis of defense compounds.Lishan Yao Yanmei Li Chuanyu Ma Lixiu Tong Feili Du Mingliang Xu 2020Journal of Integrative Plant Biology2020,62,10:13
3Singularity Analysis of a 3-RPS Parallel Manipulator Using Geometric Algebra显示文摘Singular configurations must be avoided in path planning and control of a parallel manipulator. However, most studies rarely focus on an overall singularity loci distribution of lower-mobility parallel mechanisms. Geometric algebra is employed in analysis of singularity of a 3-RPS parallel manipulator. Twist and wrench in screw theory are represented in geometric algebra. Linear dependency of twists and wrenches are described by outer product in geometric algebra. Reciprocity between twists and constraint wrenches are reflected by duality. To compute the positions of the three spherical joints of the 3-RPS parallel manipulator, Tilt-and-Torsion angles are used to describe the orientation of the moving platform. The outer product of twists and constraint wrenches is used as an index for closeness to singularity(ICS) of the 3-RPS parallel manipulator. An overall and thorough perspective of the singularity loci distribution of the 3-RPS parallel manipulator is disclosed, which is helpful to design, trajectory planning and control of this kind of parallel manipulator.LI Qinchuan XIANG Ji'nan CHAI Xinxue WU Chuanyu 2015Chinese Journal of Mechanical Engineering2015,28,6:12
4MVS-Pheno:A Portable and Low-Cost Phenotyping Platform for Maize Shoots Using Multiview Stereo 3D Reconstruction显示文摘Plant phenotyping technologies play important roles in plant research and agriculture.Detailed phenotypes of individual plants can guide the optimization of shoot architecture for plant breeding and are useful to analyze the morphological differences in response to environments for crop cultivation.Accordingly,high-throughput phenotyping technologies for individual plants grown in field conditions are urgently needed,and MVS-Pheno,a portable and low-cost phenotyping platform for individual plants,was developed.The platform is composed of four major components:a semiautomatic multiview stereo(MVS)image acquisition device,a data acquisition console,data processing and phenotype extraction software for maize shoots,and a data management system.The platform’s device is detachable and adjustable according to the size of the target shoot.Image sequences for each maize shoot can be captured within 60-120 seconds,yielding 3D point clouds of shoots are reconstructed using MVS-based commercial software,and the phenotypic traits at the organ and individual plant levels are then extracted by the software.The correlation coefficient(R^(2))between the extracted and manually measured plant height,leaf width,and leaf area values are 0.99,0.87,and 0.93,respectively.A data management system has also been developed to store and manage the acquired raw data,reconstructed point clouds,agronomic information,and resulting phenotypic traits.The platform offers an optional solution for high-throughput phenotyping of field-grown plants,which is especially useful for large populations or experiments across many different ecological regions.Sheng Wu Weiliang Wen Yongjian Wang Jiangchuan Fan Chuanyu Wang Wenbo Gou Xinyu Guo 2020Plant Phenomics2020,2,1:11
5Preparation and Electrochemical Performance of Nano-Co_3O_4 Anode Materials from Spent Li-Ion Batteries for Lithium-Ion Batteries显示文摘A hydrometallurgical process for the recovery of cobalt oxalate from spent lithium-ion batteries was used to recycle cobalt compound by using alkali leaching,reductive acid leaching and chemical deposition of cobalt oxalate.The recycled cobalt oxalate was used to synthesize nano-Co3O4 anode material by sol-gel method. The samples were characterized by thermal gravity analysis and differential thermal analysis(TGA/DTA),X-ray diffraction(XRD),scanning electron microscopy(SEM) and charge/discharge measurements.The influence of molar ratio of Co2+ to citric acid and calcination temperature on the structure and electrochemical performance of nano-Co3O4 was evaluated.As the molar ratio of Co2+ to citric acid is 1:1,the face-centered cubic(fcc) Co3O4 powder shows the discharge capacity of 760.9 mA h g-1,the high coulombic efficiency of 99.7%in the first cycle at the current density of 125 mA g-1,and the excellent cycling performance with the reversible capacity of 442.3 mA h g-1after 20 cycles at the current density of 250 mA g-1.Chuanyue Hu Jun Guo Jin Wen Yangxi Peng 2013Journal of Materials Science & Technology2013,29,3:8
6Focal adhesion protein Kindlin-2 regulates bone homeostasis in mice显示文摘Our recent studies demonstrate that the focal adhesion protein Kindlin-2 is critical for chondrogenesis and early skeletal development. Here, we show that deleting Kindlin-2 from osteoblasts using the 2.3-kb mouse Col1 a1-Cre transgene minimally impacts bone mass in mice, but deleting Kindlin-2 using the 10-kb mouse Dmp1-Cre transgene, which targets osteocytes and mature osteoblasts, results in striking osteopenia in mice. Kindlin-2 loss reduces the osteoblastic population but increases the osteoclastic and adipocytic populations in the bone microenvironment. Kindlin-2 loss upregulates sclerostin in osteocytes,downregulates β-catenin in osteoblasts, and inhibits osteoblast formation and differentiation in vitro and in vivo. Upregulation ofβ-catenin in the mutant cells reverses the osteopenia induced by Kindlin-2 deficiency. Kindlin-2 loss additionally increases the expression of RANKL in osteocytes and increases osteoclast formation and bone resorption. Kindlin-2 deletion in osteocytes promotes osteoclast formation in osteocyte/bone marrow monocyte cocultures, which is significantly blocked by an anti-RANKLneutralizing antibody. Finally, Kindlin-2 loss increases osteocyte apoptosis and impairs osteocyte spreading and dendrite formation.Thus, we demonstrate an important role of Kindlin-2 in the regulation of bone homeostasis and provide a potential target for the treatment of metabolic bone diseases.Huiling Cao Qinnan Yan Dong Wang Yumei Lai Bo Zhou Qi Zhang Wenfei Jin Simin Lin Yiming Lei Liting Ma Yuxi Guo Yishu Wang Yilin Wang Xiaochun Bai Chuanju Liu Jian QFeng Chuanyue Wu Di Chen Xu Cao Guozhi Xiao 2020Bone Research2020,8,1:8
7Dynamic characteristics of dwarf Chinese hickory trees under impact excitations for mechanical fruit harvesting显示文摘Mechanical vibration is an effective fruit harvesting method.To evaluate the dynamic characteristics of dwarf Chinese hickory(Carya cathayensis Sarg.)trees and the influence of the tree structure on transmission and attenuation of dynamic response,a new method was proposed based on acceleration admittance measurement on dwarf Chinese hickory trees in orchard environment under impact excitation.The primary resonance frequencies of the tree can be determined based on the acceleration admittance measurement.The effect of the tree structure on the vibratory transmission was quantified using the attenuation ratio of the acceleration admittance.A 5-year-old dwarf Chinese hickory tree sample was tested.The responses at three resonance frequencies(5,9 and 12 Hz)were analyzed because they were identified as the most effective bands of excitation for the main part of the tree specimen.The results reveal that the variation of the dynamic response along the testing tree is greatly related to the Chinese hickory tree structure.The attenuation ratio of the acceleration admittance at the branch crotches indicates the leader top crotch may amplify the acceleration admittance no matter what the crotch angle and the branch diameter is.Unlike the crotches,the branch chain nodes generally have negative influence on the acceleration admittance along the branch chains which heavily depend on the branch chain configuration.The branch chains with a chain angle no less than 150°and a wood diameter ratio close to 1.0 could produce little influence on the vibration transmission.For those branches with chain angle less than 150°,the vibration was generally attenuated at their chain nodes at three resonance frequencies.To impose impact excitations on the tree,high mechanical harvesting efficiency could be achieved on those branch chains which are almost straight and uniform.Du Xiaoqiang Wu Chuanyu He Leiying Tong Junhua 2015International Journal of Agricultural and Biological Engineering2015,8,1:8
8Mobility,Constraint Singularity and Isotropy of the 3-R Translational Parallel Mechanism显示文摘The non-overconstrained 3-degrees of freedom(DOF) translational parallel mechanism(TPM) has received much attention due to its advantages in reduced cost of fabrication and assembly. Researches are being conducted in the area of type synthesis, kinematic analysis and dimensional synthesis. Mobility, constraint singularity and isotropy of a 3-R non-overconstrained TPM are studied, where P denote the prismatic pair, R the revolute pair and the overline indicates the same axis direction of the kinematic pair. The different arrangements of the three limbs affect the kinematic performance of this kind of TPM. First, the mobility analysis, actuation selection, and the constraint singularity of the general 3-R TPM are conducted based on screw theory. For a general 3-R TPM, the three prismatic pairs cannot be chosen as actuators and two kinds of constraint singularities are identified. In the first constraint singularity, the moving platform has four instantaneous DOFs. In the second constraint singularity, the moving platform has five instantaneous DOFs. Then, an orthogonal 3-R TPM is proposed, which can be actuated by three prismatic pairs and has no constraint singularities. Further, the forward and inverse kinematic analysis of the orthogonal TPM are presented. The input-output equations of the orthogonal TPM are totally decoupled. The full isotropy of the orthogonal TPM is proved by establishing the Jacobian matrix , which is an identity 3×3 diagonal matrix in the whole workspace. The orthogonal3-R TPM has great potential in application like fast pick-and-place manipulator, parallel machine and micro-motion manipulator.CHEN Qiaohong LI Qinchuan WU Chuanyu LI Yi 2009Chinese Journal of Mechanical Engineering2009,22,6:7
9Migfilin promotes migration and invasion in glioma by driving EGFR and MMP-2 signalings:A positive feedback loop regulation显示文摘Glioma is the most common type of primary brain tumors in the central nervous system(CNS). Migfilin occurs in human glioma and enhances cellular motility via the epidermal growth factor receptor(EGFR)pathway. However, the underlying molecular mechanism is not fully understood. In this study, we found that Migfilin promoted matrix metalloproteinase-2(MMP-2) activity, and restrained the expression of tissue inhibitor of metalloproteinase 2(TIMP2), which is an MMP-2 inhibitor. Functional and structural studies showed that the LIM1 domain of Migfilin was required for Migfilin-mediated TIMP2 expression inhibition and MMP-2 activity, and was also necessary in promoting cell motility. Furthermore, Migfilininduced EGFR phosphorylation was greatly reduced by MMP-2 inhibitor(GM6001) or si RNA, while Migfilin-induced MMP-2 activation was also blocked by the EGFR inhibitor(AG1478) or si RNA. MMP-2 and EGFR inhibitors and their si RNAs can block Migfilin-induced migration and invasion, respectively.These results demonstrated that EGFR and MMP-2 signalings may form a positive feedback loop to enhance Migfilin-induced migration and invasion. Finally, we detected that the expression of Migfilin,EGFR phosphorylation(Tyr1173) and MMP-2 activity had a positive correlation in the clinical glioma sample. Taken together, these results suggest that Migfilin is a critical regulator in cellular motility by driving the EGFR-MMP-2 feedback loop, and may be considered as a potential therapeutic target in glioma.Yunwei Ou Qingnan Wu Chuanyue Wu Xuefeng Liu Yongmei Song Qimin Zhan 2017Journal of Genetics and Genomics2017,44,12:7
10Preparation of superhydrophobic CdS cotton using visible light response and its application for the control of water pollution显示文摘Sewage discharge produced by homes and industries contains both oil and water-soluble components. In order to remove oil from water, materials with specific wettability can be used;however, these materials cannot remove dissolved contaminants from water. In this research, we prepared a superhydrophobic Cd S cotton for water purification. This material has the ability to adsorb different types of oil due to its non-wettability(WCA = 152°). Moreover, its response behavior towards visible light enables it to remove water-soluble pollutants as well. The highest oil absorption rate of superhydrophobic Cd S cotton is nearly 30 times, and it can absorb light below 564 nm and produce ·OH to degrade water soluble pollutants. Finally, based on Mott-Schottky curve,the position of Fermi energy level was determined(–0.55 e V). Also, the positions of valence and conduction bands were calculated based on the analysis of band gap which helps in proving photoelectric response characteristics.GE Bo REN GuiNa ZHAO PengFei JIN ChuanYu LI WenZhi ZHANG ZhaoZhu 2019Science China(Technological Sciences)2019,62,12:5
11Fabrication of BiOBr-silicone aerogel photocatalyst in an aqueous system with degradation performance by sol-gel method显示文摘It is a challenge to endow the material with the ability to pollutants degradation while maintaining the oil/water separation performance. Herein, the mixed dispersion of BiOBr photocatalyst and silicone sol was adsorbed in melamine foam. Superhydrophobic BiOBr-silicone aerogel(WCA=154°) was obtained through the transfer melamine foam to an autoclave and reaction at 80℃ for 20 h. The prepared superhydrophobic BiOBr-silicone aerogel can effectively remove the water soluble pollutants which remain within the water phase after oil/water separation. The band gap of the superhydrophobic BiOBr-silicone aerogel was calculated to be 2.71 eV, which shows sensitivity to visible light(458 nm). Through mechanism analysis, it is found that the VB position of BiOBr is at 1.07 eV and the position of CB is at-1.64 eV. Finally, we prepared a superhydrophobic BiOBr-silicone aerogel(5 cm×5 cm×3 cm) for the verification of the large scale preparation.GE Bo REN GuiNa YANG Hang YANG JingJing PU XiPeng LI WenZhi JIN ChuanYu ZHANG ZhaoZhu 2020Science China(Technological Sciences)2020,63,5:4
12Factors Affecting Small Axial Cooling Fan Performance显示文摘Many factors such as outer diameter,hub ratio,blade numbers,shape and stagger angle affect the performance of small cooling fans.A small cooling fan was simulated using CFD software for three blade stagger angles (30.5°,37.5°,44.5°)and obtained the internal flow field and the static characteristics.Research indicated that the stagger angle has an obvious effect on the static characteristics of a fan.For flow rates below 0.0104 m3/s,total pressure is the greatest when the stagger angle is 37.5°;flow rates higher than 0.0104 m3/s,the total pressure is greatest when the stagger angle is 44.5° For the same flow rates,the velocity at inlet of pressure surface increases with increasing stagger angle,but the change of velocity on the suction surface is very small.For one model,vortices and the speed of revolution surfaces decrease with tip clearance increasing.But for other three models,increasing the stagger angle,the vortex intensity and speed of revolution surfaces at same height tip clearance increases,simultaneously,the position of vortex offset from the top of the rotor blade to the suction surface.Lihong Wang,Yingzi Jin,Baoling Cui,Yuzhen Jin,Jin Lin,Yanping Wang and Chuanyu Wu College of Mechanical Engineering & Automation,Zhejiang Sci-Tech University,Xiasha Education Zone,Hangzhou 310018,China 2010Journal of Thermal Science2010,19,2:4
13Age, estimated glomerular filtration rate and ejection fraction score predicts contrast-induced acute kidney injury in patients with diabetes and chronic kidney disease: insight from the TRACK-D study显示文摘Li Jing Li Yi Wang Xiaozeng Yang Shuguang Gao Chuanyu Zhang Zheng Yang Chengming Jing Quanming Wang Shouli Ma Yingyan Wang Zulu Liang Yanchun Han Yaling 2014Chinese Medical Journal2014,,12:3
14A state-of-the-art review on low-frequency nonlinear vibration isolation with electromagnetic mechanisms显示文摘Vibration isolation is one of the most efficient approaches to protecting host structures from harmful vibrations,especially in aerospace,mechanical,and architectural engineering,etc.Traditional linear vibration isolation is hard to meet the requirements of the loading capacity and isolation band simultaneously,which limits further engineering application,especially in the low-frequency range.In recent twenty years,the nonlinear vibration isolation technology has been widely investigated to broaden the vibration isolation band by exploiting beneficial nonlinearities.One of the most widely studied objects is the'three-spring'configured quasi-zero-stiffness(QZS)vibration isolator,which can realize the negative stiffness and high-static-low-dynamic stiffness(HSLDS)characteristics.The nonlinear vibration isolation with QZS can overcome the drawbacks of the linear one to achieve a better broadband vibration isolation performance.Due to the characteristics of fast response,strong stroke,nonlinearities,easy control,and low-cost,the nonlinear vibration with electromagnetic mechanisms has attracted attention.In this review,we focus on the basic theory,design methodology,nonlinear damping mechanism,and active control of electromagnetic QZS vibration isolators.Furthermore,we provide perspectives for further studies with electromagnetic devices to realize high-efficiency vibration isolation.Bo YAN Ning YU Chuanyu WU 2022Applied Mathematics and Mechanics(English Edition)2022,43,7:3
15Interaction Between Variations in Dopamine D2 and Serotonin 2A Receptor is Associated with Short-Term Response to Antipsychotics in Schizophrenia显示文摘Dear Editor,Schizophrenia is a chronic and debilitating brain disorder,which has a strong genetic component with heritability ranging from 66%to 85%[1,2].Currently,antipsychotic drugs remain the most effective treatment for the psychotic symptoms of schizophrenia[3].Because of the severe sideeffects of first-generation antipsychotics(FGAs),secondgeneration antipsychotics(SGAs)have become more widely used in the treatment of schizophrenia.Liansheng Zhao Huijuan Wang Yamin Zhang Jinxue Wei Peiyan Ni Hongyan Ren Gang Li Qiang Wang Gavin P Reynolds Weihua Yue Wei Deng Hao Yan Liwen Tan Qi Chen Guigang Yang Tianlan Lu Lifang Wang Fuquan Zhang Jianli Yang Keqing Li Luxian Lv Qingrong Tan Yinfei Li Hua Yu Hongyan Zhang Xin Ma Fude Yang Lingjiang Li Chuanyue Wang Huiyao Wang Xiaojing Li Wanjun Guo Xun Hu Yang Tian Xiaohong Ma Jeremy Coid Dai Zhang Chao Chen Tao Li Chinese Antipsychotics Pharmacogenomics Consortium 2019Neuroscience Bulletin2019,35,6:3
16Application of Human Adenovirus Genotyping by Phylogenetic Analysis in an Outbreak to Identify Nosocomial Infection显示文摘Nosocomial infections are common in pediatric patients and can be fatal in infants and immunocompromised patients. In September 2018, a high positive rate of human adenovirus HAdV was occurred among hospitalized children in the Children's Hospital Affiliated to the Capital Institute of Paediatrics in Beijing. To investigate whether this outbreak of HAdV was related to nosocomial infections or the result of community infections, we collected respiratory specimens from patients with acute respiratory infections in a respiratory ward during June to December 2018, and screened for respiratory viruses. Among 1,840 cases included, 95(5.2%, 95/1840) were positive for HAdV and 81 were genotyped based on phylogenetic analysis, including seven as HAdV-1(8.6%), 30 HAdV-3(37.0%), two HAdV-6(2.5%), and 42 HAdV-7(51.9%). More HAdV-positive samples were collected in August(4.7%, 12/255), September(15.0%, 41/274) and October(6.9%, 17/247), with a peak in September 2018. By combining the results of HAdV phylogenetic analysis with clinical data of patients, there were 77 cases(4.2%, 77/1840;81.1%, 77/95) excluded from nosocomial infections, eight cases representing possible infections transmitted by visitors or attending parents, three cases without sequences that might have been due to infection transmitted by roommates positive for HAdV, one case of a roommate without an HAdV sequence, and six cases that shared highly homologous sequences with those of their roommates, for which nosocomial infections might be considered. In conclusion, genotyping of HAdVs based on phylogenetic analysis combined with clinical information provides a powerful method to distinguish nosocomial infections from community acquired infection, especially when tracing the origins of nosocomial infections.Chuanyu Yang Chunmei Zhu Yuan Qian Jie Deng Baoyuan Zhang Runan Zhu Fang Wang Yu Sun Dongmei Chen Qi Guo Yutong Zhou Lei Yu Ling Cao Linqing Zhao 2021Virologica Sinica2021,36,3:3
17Testing the role of genetic variation of the MC4R gene in Chinese population in antipsychotic-induced metabolic disturbance显示文摘Antipsychotic-induced metabolic disturbance(AIMD) is a common adverse effect of antipsychotics with genetics partly underpinning variation in susceptibility among schizophrenia patients. Melanocortin4 receptor(MC4 R) gene, one of the candidate genes for AIMD, has been under-studied in the Chinese patients. We conducted a pharmacogenetic study in a large cohort of Chinese patients with schizophrenia. In this study, we investigated the genetic variation of MC4 R in Chinese population by genotyping two SNPs(rs489693 and rs17782313) in 1,991 Chinese patients and examined association of these variants with the metabolic effects that were often observed to be related to AIMD. Metabolic measures, including body mass index(BMI), waist circumference(WC), glucose, triglyceride, high-density lipoprotein(HDL), and low-density lipoprotein(LDL) levels were assessed at baseline and after 6-week antipsychotic treatment. We found that interaction of SNP×medication status(drug-na?ve/medicated) was significantly associated with BMI, WC, and HDL change %, respectively. Both SNPs were significantly associated with baseline BMI and WC in the medicated group. Moderate association of rs489693 with WC, Triglyceride, and HDL change % were observed in the whole sample. In the drug-na?ve group, we found recessive effects of rs489693 on BMI gain more than 7%, WC and Triglyceride change %, with AA incurring more metabolic adverse effects. In conclusion, the association between rs489693 and the metabolic measures is ubiquitous but moderate. Rs17782313 is less involved in AIMD. Two SNPs confer risk of AIMD to patients treated with different antipsychotics in a similar way.Yamin Zhang Hongyan Ren Qiang Wang Wei Deng Weihua Yue Hao Yan Liwen Tan Qi Chen Guigang Yang Tianlan Lu Lifang Wang Fuquan Zhang Jianli Yang Keqing Li Luxian Lv Qingrong Tan Hongyan Zhang Xin Ma Fude Yang Lingjiang Li Chuanyue Wang Dai Zhang Liansheng Zhao Huiyao Wang Xiaojing Li Wanjun Guo Xun Hu Yang Tian Xiaohong Ma Tao Li Chinese Antipsychotics Pharmacogenomics Consortium 2019Science China(Life Sciences)2019,62,4:3
18Oxidative degradation of phenol by sulfidated zero valent iron under aerobic conditions:The effect of oxalate and tripolyphosphate ligands显示文摘After adding either organic or inorganic ligands,sulfidated nano-zero-valent iron(Sn ZVI)was used for aerobic degradation of phenol,and the effect of the ligand species on oxidation performance was investigated.We found that Sn ZVI hardly degraded phenol in the absence of ligand addition.Ligands initiated and promoted the degradation of pollutants by Sn ZVI.The data herein show that a characteristic inorganic ligand,tripolyphosphate(TPP),is more effective in enhancing oxidation than a characteristic organic ligand oxalate.In addition to the scavenging of reactive oxidants by the organic ligand,more ferrous ion(Fe(Ⅱ))dissolution from Sn ZVI in the TPP system is another cause for the superior enhancement by the inorganic ligand.In the oxalate system,as the sulfur content of Sn ZVI increased,the oxidation efficiency increased because Fe S shell promoted the transfer of electrons to produce more reactive oxygen species(ROS).In TPP system,the effect of sulfur content on oxidation performance is more complex.The Sn ZVI with low sulfur content showed poor oxidation performance compared with that of n ZVI.Further experiments proved that sulfidation might weaken the complexation of TPP with surface bound Fe,which would slow down the ionic Fe(II)dissolution rate.Therefore,sulfidation has the dual effects of enhancing electron transfer and inhibiting the complexation of inorganic ligands.In addition,the mechanisms of ROS generation in different ligand systems were investigated herein.Results showed that the critical ROS in both the oxalate and TPP systems are hydroxyl radicals,and that they are produced via one-electron activation of O_(2).Xianglong Kong Chengwu Zhang Jingyi Zhang Lishuang Xuan Chuanyu Qin 2021Journal of Environmental Sciences2021,33,2:2
19Current helicity pattern of large-scale magnetic field on the photosphere显示文摘Following Pevtsov and Latushko, we study the current helicity pattern of the large-scale magnetic field on the photosphere. We use the same technique as theirs to derive the vector magnetic field (Br,Bθ,Bφ) from full-disk longitudinal magnetograms based on the assumption that large-scale magnetic fields evolve rather slowly and the variations of the longitudinal magnetic fields within certain time duration are caused by the changing position angles only. Different from their study, we have calculated the current helicity maps directly from the derived vector magnetograms, rather than from obtaining the latitudinal variation of hc by ignoring the role of Bθ component and averaging Br and Bφ over all solar longitudes. This approach significantly strengthens the evidence of the hemispheric rule presented in the reconstructed vector magnetic field. Our study shows that the established hemispheric sign rule, that is, positive helicity sign in the southern hemisphere and negative helicity sign in the northern hemisphere, is applicable everywhere in the global magnetic field, namely, also evident in weak fields outside active regions, and that the obtained sign pattern is independent of the longitudinal magnetograms and the parameters that we have used.WANG ChuanYu ZHANG Mei 2009Science China(Physics,Mechanics & Astronomy)2009,52,11:2
20Eddy induced SST variation and heat transport in the western North Paci?c Ocean显示文摘Vigorous mesoscale eddies and significant sea surface temperature(SST)variations are found in the northern edge of the Pacific warm pool that features large SST gradient.However,the relations between SST gradient,eddies,and SST variations in this region remain unexplored.In this study,by combining multi-altimeter sea surface height(SSH),satellite microwave SST observations and a mesoscale eddy dataset,we investigated the two-dimensional structures of SSTa(SST anomalies)in two subareas,which have different eddy characteristics and can be discriminated in the intensity of background SST gradient.The eddy characteristics of this region,focusing on their concentration to 21°N,are also described.We found that eddies can result in two distinct patterns of eddy-induced SST anomalies,with two different horizontal processes respectively.One is a monopole pattern that is caused by elevation/depression of the isopycnals,and another is a dipole pattern caused by eddy's rotation and stirring of the background SST field.In addition,contributions of both parts to the total SSTa and the SSTa variations were evaluated.The intensity of surrounding SST gradient plays an important role in shaping the SSTa structure:when SST gradient is larger,the eddy-associated SSTa pattern organizes more dipole.The distinct annual cycle in two components of SSTa is associated with the seasonal modulation of the warm pool's horizontal structure.SUN Bowen LIU Chuanyu WANG Fan 2020Journal of Oceanology and Limnology2020,38,1:2
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