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3篇 您的检索式:作者名="Chengda Ge"
    题名 作者 年代 出处 被引量
1Enhanced CO catalytic oxidation by Sr reconstruction on the surface of LaxSr1-xCoO3-δ显示文摘Surface electronic structure of solid materials plays a critical role in heterogeneous catalysis. However,surface chemical composition of the perovskite oxides is usually dominated by segregated A-site cations and the amount of oxygen vacancies is relatively low, which seriously restricts their catalytic oxidation property. Here, we prepare perovskite La_xSr_(1-x)CoO_(3-δ)(x = 0.3, 0.5, 0.7) with different Sr doping amount and experiment results show that perovskite LSCO with higher content of surface Sr possesses more oxygen vacancies and better catalytic activity. On this basis, we develop a new experimental strategy to create more surface oxygen vacancies to promote their CO catalytic activity. In this method, we use high active hydrogen atoms(BH^(4-)) as reductant to realize surface in-situ chemical composite modification of La_xSr_(1-x)CoO_(3-δ)(x = 0.3, 0.5, 0.7), which causes their surface reconstruction(surface Sr enrichment).The regulation mainly focuses on the atomic layer level without damaging their bulk phase structure.Different from traditional high temperature annealing under reducing atmosphere, this method is high-efficiency, green and controllable. Furthermore, we study the surface reconstruction process and demonstrated that it is atomic layer engineering on the surface of La_xSr_(1-x)CoO_(3-δ)(x = 0.3, 0.5, 0.7) by X-ray photoelectron spectroscopy(XPS) and X-ray absorption fine structure(XAFS). Our experiment results also show that these samples treated by this method exhibit superior activity for CO oxidation compared with original samples.Xiyang Wang Keke Huang Jingyu Qian Yingge Cong Chengda Ge Shouhua Feng 2017Science Bulletin2017,62,9:5
2Stable and Highly Flexible Perovskite Solar Cells with Power Conversion Efficiency Approaching 20% by Elastic Grain Boundary Encapsulation显示文摘Here,we show that flexible perovskite solar cells(PSCs)with high operational stability and power conversion efficiency(PCE)approaching 20%were achieved by elastic grain boundary(GB)encapsulation.An introduction of trimethyltrivinylcyclotrisiloxane(V3D3)and solvent annealing(SA)resulted in an in situ cross-linking reaction between GBs and enlarged grain size that enabled oriented charge-transport properties to be achieved synchronously,leading to reduced sheet resistance with a high fill factor(FF)up to 82.93%in flexible PSCs.Chengda Ge Ziqi Yang Xiaoting Liu Yilong Song Anran Wang Qingfeng Dong 2021CCS Chemistry2021,3,7:1
3Multiple Hydrogen Bond-Induced Structural Distortion for Broadband White-Light Emission in Two-Dimensional Perovskites显示文摘Low-dimensional hybrid lead-halide perovskites with broadband white-light emission upon near-UV excitation have attracted immense scientific interest due to their potential application for the next generation of solid-state lighting as well as scintillators for radiation detection.Recently,broadband emission material is mostly reported in structural distorted perovskites.However,it is still unclear how to generate structural distortion in low-dimensional perovskites.Xiaoting Liu Ziqi Yang Chengda Ge Hanming Li Mingwei Hao Chenlian Wan Yilong Song Bao Li Qingfeng Dong 2021CCS Chemistry2021,3,10:0
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