| 10 | Asymmetric Meerwein-Ponndorf-Verley reduction catalyzed by a new type of chiral binaphthol-samarium complex显示文摘A new type of chiral 1,1’-binaphthol(BINOL) derived samarium complex, preparedfrom (R)- or (S)-BINOL and SmCl3, serves as an enantioselective catalyst for the Meerwein-Ponndorf-Verley (MPV) reduction in the presence of Molecular Sieves 4A(MS 4A). Moderate enantioselectivity was obtained. Kinetic studies show slight decrease of the enantiomeric excess with the conversion. | Ding, ZB Cheng, KJ Wu, SH | 1996 | Chinese Journal of Chemistry1996，14，6： | 0 |
您所在的机构暂未开通此部分的功能，请联系管理员