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2篇 您的检索式:作者名="CUI Tongdi"
    题名 作者 年代 出处 被引量
1Experimental measurement of the electrical conductivity of single crystal olivine at high temperature and high pressure under different oxygen fugacities显示文摘At 1.0-4.0 GPa and 1123-1473 K and under oxygen fugacity-controlled conditions (Ni + NiO, Fe + Fe3O4, Fe + FeO and Mo+ M0O2 buffers), a YJ-3000t Model six-anvil solid high-pressure apparatus and a Sarltron-1260 Impedance/Gain-Phase analyzer were employed to conduct an in situ measurement of the electrical conductivity of single crystal olivine. Experimental results showed that: (1) within the range of experimentally selected frequencies (103-106 Hz), the electrical conductivity of the sample is of great dependence on the frequency; (2) with the rise of temperature ( T), the electrical conductivity (σ) will increase, and the Arrenhius linear relationship is established between lgσ and 1/T; (3) under the control of oxygen buffer Fe+ Fe3O4, with the rise of pressure, the electrical conductivity tends to decrease whereas the activation enthalpy and independent-of-temperature preexponential factor tend to increase, with the activation energy and activation volume of the sample estimated at (1. 25 ± 0.08) eV and (0.105 ±0.025) cm3/mol, respectively; (4) under given pressure and temperature conditions, the electrical conductivity tends to increase whereas the activation energy tends to decrease with increasing oxygen fugacity; and ( 5) the mechanism of electrical conduction of small polarons can provide insight into the behavior of electrical conduction of olivine under high pressure and high temperature.DAI Lidong LI Heping LIU Congqiang CUI Tongdi SHAN Shuangming YANG Changjun LIU Qingyou DENG Heming 2006Progress in Natural Science:Materials International2006,16,4:9
2Experimental Study on the Electrical Conductivity of Orthopyroxene at High Temperature and High Pressure under Different Oxygen Fugacities显示文摘At presure 1.0–4.0 GPa and temperature 1073–1423 K and under oxygen partial pressure conditions, a YJ-3000t multi-anvil solid high-pressure apparatus and Sarltron-1260 Impedance/Gain-Phase analyzer were employed toconduct an in-situ measurement of the electrical conductivity of orthopyroxene. The buffering reagents consist of Ni+NiO,Fe+Fe3O4, Fe+FeO and Mo+MoO2 in order to control the environmental oxygen fugacity. Experimental results made clearthat: (1) within the measuring frequency range from 10? to 106 Hz, the complex impedance (R) is of intensive dependence 1on the frequency; (2) The electrical conductivity (σ) tends to increase along to the rise of temperature (T), and Log σ vs. 1/T fit the Arrenhius linear relations; (3) Under the control of oxygen buffer Fe+Fe3O4, with the rise of pressure, theactivation enthalpy tends to increase whereas the electrical conductivity tends to decrease. The activation energy andactivation volume of the main current carriers of orthopyroxene have been obtained, which are (1.715±0.035) eV and (0.03±0.01) cm3/mol, respectively; (4) Under given pressure and temperature, the electrical conductivity tends to increase withincreasing oxygen fugacity, while under given pressure the activation enthalpy tends to decrease with increasing oxygenfugacity; and (5) The sample’s small polarons mechanism has provided a reasonable explanations to the conductionbehavior at high temperature and high pressure.DAI Lidong LI Heping LIU Congqiang SHAN Shuangming CUI Tongdi SU Genli 2005Acta Geologica Sinica(English Edition)2005,79,6:4
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