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1Clinical characteristics of 24 asymptomatic infections with COVID-19 screened among close contacts in Nanjing,China显示文摘Previous studies have showed clinical characteristics of patients with the 2019 novel coronavirus disease(COVID-19)and the evidence of person-to-person transmission.Limited data are available for asymptomatic infections.This study aims to present the clinical characteristics of 24 cases with asymptomatic infection screened from close contacts and to show the transmission potential of asymptomatic COVID-19 virus carriers.Epidemiological investigations were conducted among all close contacts of COVID-19 patients(or suspected patients)in Nanjing,Jiangsu Province,China,from Jan 28 to Feb 9,2020,both in clinic and in community.Asymptomatic carriers were laboratory-confirmed positive for the COVID-19 virus by testing the nucleic acid of the pharyngeal swab samples.Their clinical records,laboratory assessments,and chest CT scans were reviewed.As a result,none of the 24 asymptomatic cases presented any obvious symptoms while nucleic acid screening.Five cases(20.8%)developed symptoms(fever,cough,fatigue,etc.)during hospitalization.Twelve(50.0%)cases showed typical CT images of ground-glass chest and 5(20.8%)presented stripe shadowing in the lungs.The remaining 7(29.2%)cases showed normal CT image and had no symptoms during hospitalization.These 7 cases were younger(median age:14.0 years;P=0.012)than the rest.None of the 24 cases developed severe COVID-19 pneumonia or died.The median communicable period,defined as the interval from the first day of positive nucleic acid tests to the first day of continuous negative tests,was 9.5 days(up to 21 days among the 24 asymptomatic cases).Through epidemiological investigation,we observed a typical asymptomatic transmission to the cohabiting family members,which even caused severe COVID-19 pneumonia.Overall,the asymptomatic carriers identified from close contacts were prone to be mildly ill during hospitalization.However,the communicable period could be up to three weeks and the communicated patients could develop severe illness.These results highlighted the importance of close contact tracing and longitudinally surveillance via virus nucleic acid tests.Further isolation recommendation and continuous nucleic acid tests may also be recommended to the patients discharged.Zhiliang Hu Ci Song Chuanjun Xu Guangfu Jin Yaling Chen Xin Xu Hongxia Ma Wei Chen Yuan Lin Yishan Zheng Jianming Wang Zhibin Hu Yongxiang Yi Hongbing Shen 2020Science China(Life Sciences)2020,63,5:77
2Phosphorus recovery from biogas fermentation liquid by Ca-Mg loaded biochar显示文摘Shortage in phosphorus(P) resources and P wastewater pollution is considered as a serious problem worldwide. The application of modified biochar for P recovery from wastewater and reuse of recovered P as agricultural fertilizer is a preferred process. This work aims to develop a calcium and magnesium loaded biochar(Ca–Mg/biochar) application for P recovery from biogas fermentation liquid. The physico-chemical characterization, adsorption efficiency, adsorption selectivity, and postsorption availability of Ca-Mg/biochar were investigated. The synthesized Ca–Mg/biochar was rich in organic functional groups and in Ca O and Mg O nanoparticles. With the increase in synthesis temperature, the yield decreased, C content increased, H content decreased, N content remained the same basically, and BET surface area increased. The P adsorption of Ca–Mg/biochar could be accelerated by nano-Ca O and nano-Mg O particles and reached equilibrium after 360 min.The process was endothermic, spontaneous, and showed an increase in the disorder of the solid–liquid interface. Moreover, it could be fitted by the Freundlich model. The maximum P adsorption amounts were 294.22, 315.33, and 326.63 mg/g. The P adsorption selectivity of Ca–Mg/biochar could not be significantly influenced by the typical p H level of biogas fermentation liquid. The nano-Ca O and nano-Mg O particles of Ca–Mg/biochar could reduce the negative interaction effects of coexisting ions. The P releasing amounts of postsorption Ca–Mg/biochar were in the order of Ca–Mg/B600 > Ca–Mg/B450 > Ca–Mg/B300. Results revealed that postsorption Ca–Mg/biochar can continually release P and is more suitable for an acid environment.Ci Fang Tao Zhang Ping Li Rongfeng Jiang Shubiao Wu Haiyu Nie Yingcai Wang 2015Journal of Environmental Sciences2015,27,3:21
3Comparison of Headspace Solid-Phase Microextraction with Simultaneous Steam Distillation Extraction for the Analysis of the Volatile Constituents in Chinese Apricot显示文摘Volatile constituents in fully mature fruits of apricot (Prunus armeniaca L.) cultivar Xinshiji were extracted using headspace solid-phase microextraction (HS-SPME) and simultaneous steam distillation extraction (SSDE) and then analyzed using capillary gas chromatography and gas chromatography-mass spectrometry. A total of 70 components were identified by HS- SPME, including 20 esters, 19 hydrocarbons, 5 alcohols, 5 ketones, 4 acids, 4 lactones, 3 aldehydes, and 10 miscellaneous components, with the esters being the dominant constituent. On the basis of the odor unit values, it is believed that the following compounds probably contributed to the fresh apricot odor: hexyl acetate, β-ionone, butyl acetate, (E)-2-hexenal, linalool, limonene, γ-decalactone, and hexanal. A total of 49 components were also detected by SSDE, including 13 hydrocarbons, 9 alcohols, 7 aldehydes, 9 esters, 4 ketones, 4 lactones, 2 acids, and 1 miscellaneous component, of which the monoterpene alcohols were the dominant constituents. It could be judged from the odor unit values that the following compounds were the major contributors to boiled apricot aroma: β-ionone, linalool, hexyl acetate, γ-dodecalactone, γ- decalactone, (E)-2-hexenal, hexanal, γ-octalactone, phenylacetaldehyde, butyl acetate, limonene, α-terpineol, and δ-decalactone. The results show that HS-SPME is a simple, rapid, and solvent-free method, which is an alternative to the classical SSDE.CHEN Mei-xia CHEN Xue-sen WANG Xin-guo CI Zhi-juan LIU Xiao-li HE Tian-ming ZHANG Li-jie 2006Agricultural Sciences in China2006,5,11:20
4Combined subfascial endoscopic perforator surgery and endovenous laser treatment without impact on the great saphenous vein for management of lower-extremity varicose veins显示文摘GAN Shu-jie QIAN Shui-xian ZHANG Ci MAO Jie-qi LI Ke TANG Jing-dong 2013Chinese Medical Journal2013,,3:18
5Functional traits of tree species with phylogenetic signal co-vary with environmental niches in two large forest dynamics plots显示文摘Aims While using phylogenetic and functional approaches to test the mechanisms of community assembly,functional traits often act as the proxy of niches.However,there is little detailed knowledge regarding the correlation between functional traits of tree species and their niches in local communities.We suggest that the co-varying correlation between functional traits and niches should be the premise for using phylogenetic and functional approaches to test mechanisms of community assembly.Using functional traits,phylogenetic and environmental data,this study aims to answer the questions:(i)within local communities,do functional traits of co-occurring species covary with their environmental niches at the species level?and(ii)what is the key ecological process underlying community assembly in Xishuangbanna and Ailaoshan forest dynamic plots(FDPs)?Methods We measured seven functional traits of 229 and 36 common species in Xishuangbanna and Ailaoshan FDPs in tropical and subtropical China,respectively.We also quantified the environmental niches for these species based on conditional probability.We then analyzed the correlations between functional traits and environmental niches using phylogenetic independent contrasts.After examining phylogenetic signals of functional traits using Pagel’sλ,we quantified the phylogenetic and functional dispersion along environmental gradients within local tree communities.Important Findings For target species,functional traits do co-vary with environmental niches at the species level in both of the FDPs,supporting that functional traits can be used as a proxy for local-scale environmental niches.Functional traits show significant phylogenetic signals in both of the FDPs.We found that the phylogenetic and functional dispersion were significantly clustered along topographical gradients in the Ailaoshan FDP but overdispersion in the Xishuangbanna FDP.These patterns of phylogenetic and functional dispersion suggest that environmental filtering plays a key role in structuring local tree assemblages in Ailaoshan FDP,while competition exclusion plays a key role in Xishuangbanna FDP.Jie Yang Xiuqin Ci Mengmeng Lu Guocheng Zhang Min Cao Jie Li Luxiang Lin 2014Journal of Plant Ecology2014,7,2:16
6COVID-19: Challenges to GIS with Big Data显示文摘The outbreak of the 2019 novel coronavirus disease(COVID-19)has caused more than 100,000 people infected and thousands of deaths.Currently,the number of infections and deaths is still increasing rapidly.COVID-19 seriously threatens human health,production,life,social functioning and international relations.In the fight against COVID-19,Geographic Information Systems(GIS)and big data technologies have played an important role in many aspects,including the rapid aggregation of multi-source big data,rapid visualization of epidemic information,spatial tracking of confirmed cases,prediction of regional transmission,spatial segmentation of the epidemic risk and prevention level,balancing and management of the supply and demand of material resources,and socialemotional guidance and panic elimination,which provided solid spatial information support for decision-making,measures formulation,and effectiveness assessment of COVID-19 prevention and control.GIS has developed and matured relatively quickly and has a complete technological route for data preparation,platform construction,model construction,and map production.However,for the struggle against the widespread epidemic,the main challenge is finding strategies to adjust traditional technical methods and improve speed and accuracy of information provision for social management.At the data level,in the era of big data,data no longer come mainly from the government but are gathered from more diverse enterprises.As a result,the use of GIS faces difficulties in data acquisition and the integration of heterogeneous data,which requires governments,businesses,and academic institutions to jointly promote the formulation of relevant policies.At the technical level,spatial analysis methods for big data are in the ascendancy.Currently and for a long time in the future,the development of GIS should be strengthened to form a data-driven system for rapid knowledge acquisition,which signifies ts that GIS should be used to reinforce the social operation parameterization of models and methods,especially when providing support for social management.Chenghu Zhou Fenzhen Su Tao Pei An Zhang Yunyan Du Bin Luo Zhidong Cao Juanle Wang Wen Yuan Yunqiang Zhu Ci Song Jie Chen Jun Xu Fujia Li Ting Ma Lili Jiang Fengqin Yan Jiawei Yi Yunfeng Hu Yilan Liao Han Xiao 2020Geography and Sustainability2020,1,1:13
7Walnut-inspired microsized porous silicon/graphene core-shell composites for high-performance lithium-ion battery anodes显示文摘Wei Zhai Qing Ai Lina Chen Shiyuan Wei Deping Li Lin Zhang Pengchao Si Jinkui Feng Lijie Ci 2017Nano Research2017,10,12:12
8Cortical plasticity and nerve regeneration after peripheral nerve injury显示文摘With the development of neuroscience, substantial advances have been achieved in peripheral nerve regeneration over the past decades. However, peripheral nerve injury remains a critical public health problem because of the subsequent impairment or absence of sensorimotor function. Uncomfortable complications of peripheral nerve injury, such as chronic pain, can also cause problems for families and society. A number of studies have demonstrated that the proper functioning of the nervous system depends not only on a complete connection from the central nervous system to the surrounding targets at an anatomical level, but also on the continuous bilateral communication between the two. After peripheral nerve injury, the interruption of afferent and efferent signals can cause complex pathophysiological changes, including neurochemical alterations, modifications in the adaptability of excitatory and inhibitory neurons, and the reorganization of somatosensory and motor regions. This review discusses the close relationship between the cerebral cortex and peripheral nerves. We also focus on common therapies for peripheral nerve injury and summarize their potential mechanisms in relation to cortical plasticity. It has been suggested that cortical plasticity may be important for improving functional recovery after peripheral nerve damage. Further understanding of the potential common mechanisms between cortical reorganization and nerve injury will help to elucidate the pathophysiological processes of nerve injury, and may allow for the reduction of adverse consequences during peripheral nerve injury recovery. We also review the role that regulating reorganization mechanisms plays in functional recovery, and conclude with a suggestion to target cortical plasticity along with therapeutic interventions to promote peripheral nerve injury recovery.Ci Li Song-Yang Liu Wei Pi Pei-Xun Zhang 2021Neural Regeneration Research2021,16,8:12
9Soil Organic Carbon Mineralization as Affected by Cyclical Temperature Fluctuations in a Karst Region of Southwestern China显示文摘The diurnal fluctuation in soil temperature may influence soil organic carbon(SOC) mineralization, but there is no consensus on SOC mineralization response to the cyclical fluctuation in soil temperature. A 56-d incubation experiment was conducted to investigate the effects of constant and variable temperatures on SOC mineralization. Three soils were collected from the karst region in western Guizhou Province, southwestern China, including a limestone soil under forest, a limestone soil under crops and a yellow soil under crops. According to the World Reference Base(WRB) classification, the two limestone soils were classified as Haplic Luvisols and the yellow soil as a Dystric Luvisol. These soils were incubated at three constant temperatures(15, 20 and 25?C) and cyclically fluctuating temperatures(diurnal cycle between 15 and 25?C). The results showed that the 56-d cumulative SOC mineralized(C56)at the fluctuating temperatures was between those at constant 15 and 25?C, suggesting that the cumulative SOC mineralization was restricted by temperature range. The SOC mineralization responses to the fluctuating temperatures were different among the three soils, especially in contrast to those at constant 20?C. Compared with constant 20?C, significant(P < 0.05) decreases and increases in C56 value were found in the limestone soil under forest and yellow soil under crops at the fluctuating temperatures, respectively. At the fluctuating temperatures, the forest soil with lower temperature coefficient Q10(the relative change in SOC mineralization rate as a result of increasing the temperature by 10?C) had a significantly(P < 0.05) lower SOC mineralization intensity than the two cropland soils. These indicated that differences in temperature pattern(constant or fluctuating) could significantly influence SOC mineralization, and SOC mineralization responses to the fluctuating temperatures might be affected by soil characteristics.Moreover, the warmer temperatures might improve the ability of soil microbes to decompose the recalcitrant SOC fraction, and cyclical fluctuations in temperature could influence SOC mineralization through changing the labile SOC pool size and the mineralization rate of the recalcitrant SOC in soils.CI En Mahdi M.AL-KAISI WANG Liange DING Changhuan XIE Deti 2015Pedosphere2015,25,4:12
10Controlled Nanocutting of Graphene显示文摘Rapid progress in graphene-based applications is calling for new processing techniques for creating graphene components with different shapes,sizes,and edge structures.Here we report a controlled cutting process for graphene sheets,using nickel nanoparticles as a knife that cuts with nanoscale precision.The cutting proceeds via catalytic hydrogenation of the graphene lattice,and can generate graphene pieces with specifi c zigzag or armchair edges.The size of the nanoparticle dictates the edge structure that is produced during the cutting.The cutting occurs along straight lines and along symmetry lines,defined by angles of 60ºor 120º,and is defl ected at free edges or defects,allowing practical control of graphene nano-engineering.Lijie Ci Zhiping Xu Lili Wang Wei Gao Feng Ding Kevin F.Kelly Boris I.Yakobson Pulickel M.Ajayan 2008Nano Research2008,1,2:11
11Amino-functionalized poloxamer 407 with both mucoadhesive and thermosensitive properties:preparation, characterization and application in a vaginal drug delivery system显示文摘Lack of mucoadhesive properties is the major drawback to poloxamer 407(F127)-based in situ hydrogels for mucosal administration. The objective of the present study was to construct a novel mucoadhesive and thermosensitive in situ hydrogel drug delivery system based on an aminofunctionalized poloxamer for vaginal administration. First, amino-functionalized poloxamer 407(F127-NH2) was synthesized and characterized with respect to its micellization behavior and interaction with mucin. Then using acetate gossypol(AG) as model drug, AG-loaded F127-NH2-based in situ hydrogels(NFGs) were evaluated with respect to rheology, drug release, ex vivo vaginal mucosal adhesion, in vivo intravaginal retention and local irritation after vaginal administration to healthy female mice. The results show that F127-NH2 is capable of forming a thermosensitive in situ hydrogel with sustained drug release properties. An interaction between positively charged F127-NH2 and negatively charged mucin wasrevealed by changes in the particle size and zeta potential of mucin particles as well as an increase in the complex modulus of NFG caused by mucin. Ex vivo and in vivo fluorescence imaging and quantitative analysis of the amount of AG remaining in mouse vaginal lavage all demonstrated greater intravaginal retention of NFG than that of an unmodified F127-based in situ hydrogel. In conclusion, amino group functionalization confers valuable mucoadhesive properties on poloxamer 407.Liqian Ci Zhigang Huang Yu Liub Zhepeng Liu Gang Wei Weiyue Lu 2017Acta Pharmaceutica Sinica B2017,7,5:11
12Building a Cloud-Based Energy Storage System through Digital Transformation of Distributed Backup Battery in Mobile Base Stations显示文摘Battery energy storage systems(ESS) have been widely used in mobile base stations(BS) as the main backup power source. Due to the large number of base stations, massive distributed ESSs have largely stayed in idle and very difficult to achieve high asset utilization. In recent years, the fast-paced development of digital energy storage(DES) technology has revolutionized the traditional operation and maintenance of ESSs by transforming them into digital assets, further enabling battery energy storage services, raising up a new way to achieve a much higher utilization of such kind of largely idle ESS resources. In this paper, the disruptive DES technology will be introduced and its application under the context of mobile BSs will be studied, and then a cloud-based energy storage(CES) platform is proposed based on a large scale distributed DESs to provide a new cyber-enabled energy storage service to the local utility company. A real-world case study shows the effectiveness and efficiency of the CES platform.Song Ci Yanglin Zhou Yuan Xu Xingjian Diao Junwei Wang 2020China Communications2020,17,4:10
13Genetic characterization and linkage disequilibrium mapping of resistance to gray leaf spot in maize(Zea mays L.)显示文摘Gray leaf spot(GLS),caused by Cercospora zeae-maydis,is an important foliar disease of maize(Zea mays L.)worldwide,resistance to which is controlled by multiple quantitative trait loci(QTL).To gain insights into the genetic architecture underlying the resistance to this disease,an association mapping population consisting of 161 inbred lines was evaluated for resistance to GLS in a plant pathology nursery at Shenyang in 2010 and 2011.Subsequently,a genome-wide association study,using 41,101 single-nucleotide polymorphisms(SNPs),identified 51 SNPs significantly(P<0.001)associated with GLS resistance,which could be converted into 31 QTL.In addition,three candidate genes related to plant defense were identified,including nucleotidebinding-site/leucine-rich repeat,receptor-like kinase genes similar to those involved in basal defense.Two genic SNPs,PZE-103142893 and PZE-109119001,associated with GLS resistance in chromosome bins 3.07 and 9.07,can be used for marker-assisted selection(MAS)of GLS resistance.These results provide an important resource for developing molecular markers closely linked with the target trait,enhancing breeding efficiency.Liyu Shi Xiangling Lv Jianfeng Weng Hanyong Zhu Changlin Liu Zhuanfang Hao Yu Zhou Degui Zhang Mingshun Li Xiaoke Ci Xinhai Li Shihuang Zhang 2014The Crop Journal2014,2,Z1:9
14Mercury in leaf litter in typical suburban and urban broadleaf forests in China显示文摘To study the role of leaf litter in the mercury (Hg) cycle in suburban broadleaf forests and the distribution of Hg in urban forests, we collected leaf litter and soil from suburban evergreen and deciduous broadleaf forests and from urban forests in Beijing. The Hg concentrations in leaf litter from the suburban forests varied from 8.3 to 205.0 ng/g, with an average (avg) of (49.7 ± 36.9) ng/g. The average Hg concentration in evergreen broadleaf forest leaf litter (50.8 ± 39.4) ng/g was higher than that in deciduous broadleaf forest leaf litter (25.8 ± 10.1) ng/g. The estimated Hg fluxes of leaf litter in suburban evergreen and deciduous broadleaf forests were 179.0 and 83.7 mg/(ha·yr), respectively. The Hg concentration in organic horizons (O horizons) ((263.1 ± 237.2) ng/g) was higher than that in eluvial horizons (A horizons) ((83.9 ± 52.0) ng/g). These results indicated that leaf litterfall plays an important role in transporting atmospheric mercury to soil in suburban forests. For urban forests in Beijing, the Hg concentrations in leaf litter ranged from 8.8-119.0 (avg 28.1 ± 16.6) ng/g, with higher concentrations at urban sites than at suburban sites for each tree. The Hg concentrations in surface soil in Beijing were 32.0-25300.0 ng/g and increased from suburban sites to urban sites, with the highest value from Jingshan (JS) Park at the centre of Beijing. Therefore, the distribution of Hg in Beijing urban forests appeared to be strongly influenced by anthropogenic activities.Zhenchuan Niu Xiaoshan Zhang Zhangwei Wang Zhijia Ci 2011Journal of Environmental Sciences2011,23,12:9
15Confining MOF-derived SnSe nanoplatelets in nitrogen-doped graphene cages via direct CVD for durable sodium ion storage显示文摘Tin-based compounds are deemed as suitable anode candidates affording promising sodium-ion storages for rechargeable batteries andhybrid capacitors.However,synergistically tailoring the electrical conductivity and structural stability of tin-based anodes to attain durablesodium-ion storages remains challenging to date for its practical applications.Herein,metal-organic framework(MOF)derived SnSe/C wrappedwithin nitrogen-doped graphene(NG@SnSe/C)is designed targeting durable sodium-ion storage.NG@SnSe/C possesses favorable electricalconductivity and structure stability due to the'inner'carbon framework from the MOF thermal treatment and'outer'graphitic cage from thedirect chemical vapor deposition synthesis.Consequently,NG@SnSe/C electrode can obtain a high reversible capacity of 650 mAh·g^-1 at 0.05 A·g^1,a favorable rate performance of 287.8 mAh·g^1 at 5 A·g^1 and a superior cycle stability with a negligible capacity decay of 0.016%percycle over 3,200 cycles at 0.4 A·g^1.Theoretical calculations reveal that the nitrogen-doping in graphene can stabilize the NG@SnSe/Cstructure and improve the electrical conductivity.The reversible Na-ion storage mechanism of SnSe is further investigated by in-situ X-raydiffraction/ex-s/tu transmission electron microscopy.Furthermore,assembled sodium-ion hybrid capacitor full-cells comprising our NG@SnSe/Canode and an active carbon cathode harvest a high energy/power density of 115.5 Wh·kg^-1/5,742 W·kg^-1,holding promise for next-generationen ergy storages.Chen Lu Zhenzhu Li Zhou Xia Haina Ci Jingsheng Cai Yingze Song Lianghao Yu Wanjian Yin Shixue Dou Jingyu Sun Zhongfan Liu 2019Nano Research2019,12,12:7
16Response and adaptation to the accumulation and distribution of photosynthetic product in peanut under salt stress显示文摘To clarify the response and adaptability of peanut under salt stress,Huayu 25 was used as the material,and non-salt stress(CK),0.15% salt stress(S1),and 0.3% salt stress(S2) were applied as three treatments.The study analysed the effects of salt stress on photosynthetic characteristics,photosynthetic substances accumulation and distribution as well as the ecological adaptability of peanuts.The results showed that net photosynthetic rate(Pn),SPAD value,leaf area,and peanut yield were reduced under salt stress.Pn in CK was 13.71 and 28.72% higher than that in S1 and S2 at the 50 th day after planting,respectively.At the same growth period,the SPAD value among treatments was ranked as follows: CK>S1>S2.The 100-pod mass,100-kernel mass,kernel rate to pod,and pod mass per plant were reduced under salt stress,and the trend was CK>S1>S2.The distribution proportion of dry matter in different organs of peanut plant was changed to adapt to such stress.Roots under salt stress intensively distributed in a 0-40 cm soil layer for salt resistance.Dry mass proportion in stems and pods increased during the vegetative stage and early period of reproductive stage,respectively.The maximum growth rates of the pod volume,pod dry weight,and seed kernel dry weight all declined,and the pod and kernel volume at harvest were reduced,improving the seed plumpness under salt stress.This finding could be useful in growing peanut in saline soil.ZHANG Guan-chu DAI Liang-xiang DING Hong CI Dun-wei NING Tang-yuan YANG Ji-shun ZHAO Xin-hua YU Hai-qiu ZHANG Zhi-meng 2020Journal of Integrative Agriculture2020,19,3:7
17Composite solid electrolyte of Na3PS4-PEO for all-solid-state SnS2/Na batteries with excellent interfacial compatibility between electrolyte and Na metal显示文摘High ionic conductivity and superior interfacial stability of solid electrolytes at the electrodes are crucial factors for high-performance all-solid-state sodium batteries. Herein, a composite solid electrolyte Na3PS4-polyethylene oxide is synthesized by the solution-phase reaction method with an improved ionic conductivity up to 9.4 × 10-5 S/cm at room temperature. Moreover, polyethylene oxide polymer layer is wrapped homogeneously on the surface of Na3PS4 particles, which could effectively avoid the direct contact between Na3PS4 electrolyte and sodium metal, thus alleviate their side reactions. We demonstrate that all-solid-state battery SnS2/Na with the composite solid electrolyte Na3PS4-polyethylene oxide delivers an enhanced electrochemical performance with 230 m Ah/g after 40 cycles.Xiaoyan Xu Yuanyuan Li Jun Cheng Guangmei Hou Xiangkun Nie Qing Ai Linna Dai Jinkui Feng Lijie Ci 2020Journal of Energy Chemistry2020,29,2:7
18Nitrogen-doped graphene nanosheets as high efficient catalysts for oxygen reduction reaction显示文摘It is of great significance in exploring alternative catalysts to platinum (Pt)-based materials for oxygen reduction reaction (ORR),because this reaction is invariably involved in various fuel cells and metal-air batteries.We herein reported the nitrogen doped graphene nanosheets (NGNSs) with pore volume of as high as 3.42 m 3 /g and investigated their potential application as ORR catalysts,it was demonstrated the NGNSs featured high activity,improved kinetics and excellent long-term stability for ORR.The NGNSs were successfully used as cathode catalysts of microbial fuel cells (MFCs) and performed even better than the commercial Pt/C (Pt 10%) catalysts at the maximum power output.CI SuQin WU YongMin ZOU JianPing TANG LongHua LUO ShengLian LI JingHong WEN ZhenHai 2012Chinese Science Bulletin2012,57,23:7
19Synthesis of magnetic polyphosphazene-Ag composite particles as surface enhanced Raman spectroscopy substrates for the detection of melamine显示文摘Magnetic polyphosphazene(MPZS) particles coated by Ag nanoparticles(MPZS-Ag) have been developed as surface enhanced Raman spectroscopy(SERS) substrates for sensitive detection of melamine in aqueous solutions and milk samples.5,5’-Dithiobis-(2-nitrobenzoic acid)(DTNB) was used as model analyte to test the SERS activity of the MPZS-Ag particles.The prepared MPZS-Ag particles possess both magnetic responsiveness and excellent SERS properties.SERS detection of different concentrations of melamine aqueous solutions and spiked milk samples were performed by the MPZS-Ag particles.The limit of detection(LOD) of the melamine in aqueous solutions was 10^-7 mol/L(0.0126 mg/L) and 0.6 mg/L in real milk samples using the MPZS-Ag particles as SERS substrates.The LOD of the melamine are much lower than the safety values of Food and Drug Administration and Codex Alimentarius Commission.These results indicate that the MPZS-Ag particles have promising application prospect for SERS analysis in food safety fields.Ci Huang Feifei Lu Ke Xu Guanjun Ding Lijun You Jiabin Wang Qiqing Zhang 2019Chinese Chemical Letters2019,30,12:6
20Microstructure and tensile properties of DD32 single crystal Ni-base superalloy repaired by laser metal forming显示文摘In this work,the microstructure and tensile properties of DD32 single-crystal(SC)superalloy repaired by laser metal forming(LMF)using pulsed laser have been studied in detail.The microstructures of the deposited samples and the tensile-ruptured samples were characterized by optical microscopy(OM),transmission electron microscope(TEM)and scanning electron microscope(SEM).Due to high cooling rate,the primary dendrite spacing in the deposited area(17.2μm)was apparently smaller than that in the substrate area(307μm),and the carbides in the deposited samples were also smaller compared with that in the substrate area.The formation of(γ+γ’)eutectic in the initial layer of repaired SC was inhibited because of the high cooling rate.As the deposition proceeded,the cooling rate decreased,and the(γ+γ’)eutectic increased gradually.The(γ+γ’)eutectic at heat-affected zone(HAZ)in the molten pool dissolved partly because of the high temperature at HAZ,but there were still residual eutectics.Tensile test results showed that tensile behavior of repaired SC at different temperatures was closely related to the MC carbides,solidification porosity,γ’phase,and(γ+γ’)eutectic.At moderate temperature,the samples tested fractured preferentially at the substrate area due to the fragmentation of the coarse MC carbide in the substrate area.At elevated temperature,the(γ+γ’)eutectic and solidification porosity in the deposited area became the source of cracks,which deteriorated the high-temperature properties and made the samples rupture at the deposited area preferentially.Shiwei Ci Jingjing Liang Jinguo Li Yizhou Zhou Xiaofeng Sun 2020Journal of Materials Science & Technology2020,42,10:6
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