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您的检索式：作者名="Brian Seger"
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| 1 | Copper-indium hydroxides derived electrocatalysts with tunable compositions for electrochemical CO_(2) reduction显示文摘Bimetallic Cu-In hybrid electrocatalysts are promising noble metal-free catalysts for selective electrochemical CO_(2) reduction reaction(ECO_(2) RR).Most reports show Cu-In catalysts are selective towards CO evolutio n.However,few show similarly high selectivity towards formate.Herein we fabricated composition tunable Cu-In hydroxides(Cu_xIn_y-OH) by the hydrothermal method and studied their composition effect on electrochemical CO_(2) reduction in detail. We found that the selectivity of CO_(2) reduction products shifted from CO to formate when the content of In increased in the Cu_xIn_y-OH electrocatalysts.The Cu rich electrocatalyst mostly produced CO,which could achieve a Faradaic efficiency(FE) to 75.8% at-0.59 V vs.RHE(Cu_(76)In_(24)based electrocatalysts).In comparison,the In rich electrocatalysts selectively produced formate,which possessed the FE of formate up to 85% at-1.01 V vs.RHE.Our work systematically illustrates the composition effect on hybrid catalysts,and provides insights into the design of highly selective catalysts for ECO_(2) RR. | Qixian Xiea Gaston O.Larrazabal Ming Ma Ib Chorkendorff Brian Seger Jingshan Luo | 2021 | Journal of Energy Chemistry2021，30，12： | 2 |
| 2 | 显示文摘 | Ryan Muszynski Brian Seger Prashant V | 2008 | Journal of Physical Chemistry C2008，112，： | 1 |
| 3 | Decorating Graphene Sheets with Gold Nanoparticles显示文摘 | Muszynski Ryan Seger Brian Kamat Prashant V | 2008 | J Phys Chem C2008，112，14： | 1 |
| 4 | TiO2-Graphene Nanocomposites, UV-Assisted Photocatalytic Reduction of Graphene Oxide显示文摘 | Williams Graeme Seger Brian Kamat Prashant V | 2008 | ACS Nano2008，2，7： | 1 |
| 5 | A Comprehensive Approach to Investigate CO_(2)Reduction Electrocatalysts at High Current Densities显示文摘As electrochemical CO_(2)reduction studies progress from beaker or H-cell devices operating at low current densities to gas diffusion electrode(GDE)-based devices that sustain high reaction rates and provide an avenue toward commercialization,the overall system becomes significantly more complex.While the current densities may vary for the different approaches,it is essential to maintain the same scientific rigor when analyzing these systems.The mass transfer optimizations used in GDE based approaches necessarily add complexity and provide new challenges that need to be analyzed and overcome in terms of both engineering as well as analysis techniques.This Account puts into perspective our recent works analyzing high current density CO_(2)electrolysis performance via a comprehensive investigation of the entire system.In particular,we show the importance of monitoring(i)the gas flow rates at the outlet of the cathodic compartment,(ii)the anodic gas composition for CO_(2)/O_(2)ratio,and(iii)pH variations in the electrolyte.A rigorous analysis of these parameters allows us to achieve a complete carbon balance,in addition to accounting for a total of 100%Faradaic efficiency.By analyzing both the cathode outlet and anodic CO_(2):O_(2)ratio,we demonstrate that these methods can be used to self-validate results providing robustness.We show that this analysis approach holds for both a zero-gap membrane electrode assembly device and a flowing-catholyte device.In addition,a comprehensive monitoring approach reveals that having an alkaline environment in the vicinity of the cathode can absorb substantial amounts of CO_(2),which may greatly distort Faradaic efficiencies if not accounted for.While monitoring the outlet flow rate of a reactor appears a simple task,the mixed gases and small flow rates in lab-scale reactors can add challenges and we discuss various methods to measure these flow rates.While pH is well-known to play a role in the activity and selectivity of CO_(2)reduction,we demonstrate that(i)the operational pH is not necessarily the pH of the initial electrolyte,(ii)there are long transients in pH before steady state is reached(on the order of hours),and(iii)the pH of the anolyte and catholyte can be significantly different over the duration of the electrolysis.By varying the membrane type in a flowing-catholyte reactor(anion exchange,cation exchange,or bipolar membrane),we can use this monitoring approach to quantitatively identify the major differences in CO_(2)reduction performance related to these distinct membrane types.The overall conclusion is that complex engineering processes entail that a thorough monitoring of parameters is necessary to accurately analyze the performance of high current density electrochemical CO_(2)reduction devices. | Gastón O.Larrazábal Ming Ma Brian Seger | 2021 | Accounts of Materials Research2021，2，4： | 1 |
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