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| 1 | Rational structure design to realize high-performance SiOx@C anode material for lithium ion batteries显示文摘Silicon suboxide(SiOx)is considered to be one of the most promising materials for next-generation anode due to its high energy density.For its preparation,the wet-chemistry method is a cost-effective and readily scalable route,while the so-derived SiOx usually shows lower capacity compared with that prepared by high temperature-vacuum evaporation route.Herein,we present an elaborate particle structure design to realize the wet-chemistry preparation of a high-performance SiOx/C nanocomposite.Dandelion-like highly porous SiOx particle coated with conformal carbon layer is designed and prepared.The highly-porous SiOx skeleton provides plenty specific surface for intimate contact with carbon layer to allow a deep reduction of SiOx to a low O/Si ratio at relatively low temperature(700℃),enabling a high specific capacity.The abundant mesoscale voids effectively accommodate the volume variation of SiOx skeleton,ensuring the high structural stability of SiOx@C during lithiation/delithiation process.Meanwhile,the three-dimensional(3D)conformal carbon layer provides a fast electron/ion transportation,allowing an enhanced electrodereaction kinetics.Owing to the optimized O/Si ratio and well-engineered structure,the prepared SiOx@C electrode delivers an ultra-high capacity(1,115.8 mAh·g^-1 at 0.1 A·g^-1 after 200 cycles)and ultra-long lifespan(635 mAh·g^-1 at 2 A·g^-l after 1,000 cycles).To the best of our knowledge,the achieved combination of ultra-high specific capacity and ultra-long cycling life is unprecedented. | Zhaolin Li Hailei Zhao Jie Wang Tianhou Zhang Boyang Fu Zijia Zhang Xin Tao | 2020 | Nano Research2020，13，2： | 3 |
| 2 | Identification, evolution and geological indications of solid bitumen in shales: A case study of the first member of Cretaceous Qingshankou Formation in Songliao Basin, NE China显示文摘On the basis of sorting out current understanding of solid bitumen (SB) in shales and taking organic-rich shales in the first member of the Cretaceous Qingshankou Formation in the Songliao Basin as an example, the definition, classification, occurrence and evolution path of SB are systemtically studied, and the indicative significance of SB reflectance (Rob) on maturity and its influence on the development of reservoir space are discussed and summarized. The results show that the difference of primary maceral types is primarily responsible for the different evolution paths of SB. Most of the pre-oil bitumen is in-situ SB with only a small amount being of migrated SB, while most of the post-oil bitumen and pyrobitumen are migrated SB. From the immature to early oil maturity stage, bituminite, vitrinite, and inertinite can be distinguished from SB based on their optical characteristics under reflected light, and alginite can be differentiated from SB by their fluorescence characteristics. Under scanning electron microscope, in-situ SB and migrated SB can be effectively identified. Rob increases linearly with increasing vitrinite reflectance (Ro), as a result of a decrease of aliphatic structure and the enhancement of aromatization of SB. Within the oil window three types of secondary pores may develop in SB, including modified mineral pores, devolatilization cracks and bubble holes. At a high maturity stage spongy pores may develop in pyrobitumen. Scanning electron microscopy combined with in-situ SEM-Raman spectroscopy can further reveal the structral information of different types of SB, thus providing crucial data for understanding for understanding OM migration paths, dynamics, and distances at micro-scale. | LIU Bo WANG Liu FU Xiaofei HUO Qiuli BAI Longhui LYU Jiancai WANG Boyang | 2023 | Petroleum Exploration and Development2023，50，6： | 0 |
| 3 | Estimating water distribution of the rotating sprinkler with pulsating pressure on sloping land显示文摘Pulsating pressure plays an important role in improving the poor irrigation quality and the uneven water distribution caused by the terrain slope.Water distribution is one of the key factors in design of the sprinkler irrigation system,however,it is difficult to measure in practice.To provide appropriate technical parameters for the design of sprinkler irrigation system with pulsating pressure on sloping land,a mathematical model was established according to the water conservation principle and finite element idea,and its accuracy was experimentally verified.The model was applied to study the effects of terrain slope,sprinkler arrangement,sprinkler spacing and average pulsating pressure on water distribution on sloping land.The results showed that the water distribution was more favorable under the gentle terrain slope,when slope decreased from 25%to 5%,the uniformity increased from 74.47%to 86.22%.Sprinklers arranged in equilateral triangle and with the spacing close to R_(0)had the best water distribution uniformity,the uniformity coefficient(CU)of which was 11.43%and 8.75%higher than that in square and rectangular arrangement,respectively.The CU increased with the increase of the average pulsating pressure.However,the effect of increasing water pressure on promoting the uniformity of water distribution gradually decreases.Therefore,when using the Rainbird R5000 sprinkler on sloping land with pulsating pressure,it is suggested that the sprinkler irrigation systems should be arranged below the terrain slope of 20%,and operated at the average pulsating pressure of 300 kPa.The suitable sprinkler arrangement is the equilateral triangle,and with the spacing of 0.8R_(0)to 1.0R_(0). | Boyang Fu Yu Huang Lin Zhang | 2022 | International Journal of Agricultural and Biological Engineering2022，15，2： | 0 |
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