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| 1 | 微生物降解葡萄皮单宁研究显示文摘为降低葡萄皮单宁的分子量和聚合度,选取青霉(Penicillium sp.)和米曲霉(Aspergillus oryzae)为微生物菌株对葡萄皮单宁进行生物降解。以儿茶素的生成量和转化率为指标,分析碳源、氮源、时间、温度、pH和诱导培养基中单宁质量浓度对降解效果的影响。结果表明:外加碳源和氮源有利于青霉和米曲霉菌株的生长;时间为葡萄皮单宁降解得到不同中间产物的关键参数;温度、pH和葡萄皮单宁的质量浓度对菌株活性和降解能力均有不同程度影响;青霉对葡萄皮单宁的降解效果好于米曲霉。青霉最佳降解条件:培养时间24 h,温度28℃,pH6.5,单宁质量浓度12.5 g/L,儿茶素最大生成质量浓度0.32 mg/mL,转化率52.3%;米曲霉最佳降解条件:培养时间36 h,温度28℃,pH 6.5,单宁质量浓度10.0 g/L,儿茶素最大生成质量浓度0.16 mg/mL,转化率32.2%。因此,可通过生物降解法调控葡萄皮单宁的化学组成,适当降低单宁的分子量和聚合度。 | 兰平 马泽宇 叶柳青 BROSSE Nicolas CHRUSCIEL Laurent | 2017 | 林业工程学报2017,2,5: | 5 |
| 2 | 无机复合型阻燃剂对稻草刨花板阻燃性能的影响显示文摘选用氢氧化铝(ATH)与硼酸锌(ZB)组成的无机复合型阻燃剂压制阻燃稻草刨花板,采用锥形量热仪法研究不同配比的ATH和ZB对稻草刨花板阻燃性能的影响。结果表明:无机复合型阻燃剂能有效减少稻草刨花板的热释放和烟释放,减少烟气中CO和CO2的释放浓度,降低燃烧过程中的质量损失速率,表现出良好的阻燃抑烟效果;ATH与ZB具有协同阻燃作用,ZB的加入能有效提高复合阻燃剂的阻燃效果,减少ATH的用量,10%的ATH用量可达到比较好的阻燃效果。 | 兰平 黄润州 周定国 Nicolas Brosse | 2015 | 林业科技开发2015,29,2: | 1 |
| 3 | Synthesis of N-(protected)aminophthalimid es: application to the synthesis of singly labeled isoniazid 显示文摘 | Brosse Nicolas | 1998 | Journal of the Chemical Society-Perkin Transactions 11998,,22: | 1 |
| 4 | 不同提取方法对葡萄渣凝缩类单宁化学组成的影响(英文)显示文摘分别采用酸沉淀法和冷冻干燥法从葡萄渣中提取凝缩类单宁,借助碳核磁共振波谱法(13C-NMR)和基质辅助激光解吸/电离飞行时间质谱法(MALDI-TOF),分析不同的提取方法对凝缩类单宁提取物化学结构和组成的影响。结果表明:这两种单宁提取物以原花青定类凝缩单宁为主,少量的原花青定上含有葡萄糖基取代基和没食子酸取代基,单宁单体间以C4-C8键连接;酸化凝缩类单宁分子聚合度高于冻干凝缩类单宁;同时,酸化凝缩类单宁的中碳水化合物含量低于冻干凝缩类单宁,但儿茶酸含量高于冻干凝缩类单宁。 | 兰平 黄润州 周定国 BROSSE Nicolas CHRUSCIEL Laurent | 2015 | 南京林业大学学报(自然科学版)2015,39,4: | 0 |
| 5 | Use of Additive Based on Non-Timber Forest Products for the Ecological Stabilization of Raw Earth:Case of the Parkia Biglobosa Nut and Vitellaria Paradoxa显示文摘The housing sector today uses elaborate materials such as cement,iron,sand,often prohibitively expensive and whose production generates a strong environmental impact(scarcity of resources,transport,greenhouse gas greenhouse,etc.).In order to meet the challenges of sustainable development,earth construction is experiencing a resurgence of interest these days.Despite its many advantages,raw earth material has drawbacks,in particular its low mechanical resistance and its loss of geometric characteristics in the face of water,which slow down its development.As part of this study,the mechanical characteristics and durability of raw earth were improved by using residual water from the processing of Parkia Biglobosa(nere)and Vitellaria Paradoxa(shea)nuts in order to optimize its use for the construction of modern buildings.To this end,the decoctions resulting from the artisanal transformation of the nut of the Parkia Biglobosa into African mustard and of the Vitellaria Paradoxa into shea butter were added to the raw earth according to volume proportions of 25%,50%,75%and 100%of the aqueous solution to obtain the projected composites.Thus,mechanical characterization and durability tests were carried out on the composites obtained.The results revealed that the decoctions of Vitellaria Paradoxa and Parkia Biglobosa improve the compressive strength of the material by up to 90%and 260%,respectively.Furthermore,these decoctions improved the resistance to water penetration of the 100%additive composite by 1.5 times for Vitellaria Paradoxa and 5 times for Parkia Biglobosa.This study shows that it is possible to use decoctions as raw earth stabilizers to build modern,ecological buildings at lower energy costs.However,more in-depth studies on surface wettability and long-term durability are planned to better characterize the geomaterial. | Bio Chéïssou Koto Tamou Jean-Michel Mechling Crespin Prudence Yabi Gildas EdjrossèF.Godonou Edmond Codjo Adjovi Mohamed Gibigaye AndréLecomte Nicolas Brosse | 2023 | Journal of Renewable Materials2023,11,12: | 0 |
| 6 | Lignocellulosic Micro and Nanofibrillated Cellulose Produced by Steam Explosion for Wood Adhesive Formulations显示文摘The reinforcing impact of Lignocellulosic micro and nanofibrillated cellulose(L-MNFCs)obtained from Eucalyp-tus Globulus bark in Urea-Formaldehyde UF adhesive was tested.L-MNFCs were prepared by an environmentally friendly,low-cost process using a combination process involving steam explosion followed by refining and ultra-fine grinding.Obtained L-MNFCs showed a web-like morphology with some aggregates and lignin nanodroplets.They present a mixture of residual fibers and fine elements with a width varying between 5 nm to 20μm,respec-tively.The effects of the addition of low amounts of L-MNFCs(1%wt.)on the properties of three different adhe-sives(Urea-Formaldehyde UF,Phenol-Formaldehyde PF,and Tannin-Hexamine TH)were studied by the evolution of the pH,the viscosity,and the mechanical properties.Results showed that the viscosity of PF and UF adhesives increased with the addition of L-MNFCs,unlike TH.Meanwhile,the addition led to better mechan-ical behavior for the three adhesives.Particleboards were then prepared using modified UF with L-MNFCs and tested.Results showed that an amount of 1%wt.of L-MNFCs was sufficient to increase the internal bonding by≈67%,the modulus of elasticity by≈43%,and the modulus of rupture by≈29%. | Saad Nader Felipe Guzman Raphael Becar Cesar Segovia Cecilia Fuentealba Miguel Peirera Evelyne Mauret Nicolas Brosse | 2022 | Journal of Renewable Materials2022,10,2: | 0 |