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1篇 您的检索式:作者名="Ana P.Heitmann"
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1PET-modified red mud as catalysts for oxidative desulfurization reactions显示文摘This work describes the synthesis of catalysts based on red mud/polyethylene terephthalate(PET) composites and their subsequent heat treatment under N2 atmosphere.The materials were characterized by scanning electron microscopy(SEM),temperature programmed reduction(TPR),Fourier transform infrared spectroscopy(FT–IR),X-ray diffraction(XRD),thermogravimetric(TG) analysis and N2adsorption/desorption.The catalysts were evaluated in the oxidative desulfurization reaction of dibenzothiophene(DBT) in a biphasic system.The results indicated that the PET impregnation on red mud increased the affinity of the catalyst with the nonpolar phase(fuel),in which the contaminant was dissolved,allowing a higher conversion(up to 80%) and selectivity to the corresponding dibenzothiophene sulfone.The sulfone compound is more polar than DBT and diffused into the polar solvent as indicated by the data obtained via gas chromatography–mass spectrometry(GC–MS).Nayara T.do Prado Ana P.Heitmann Herman S.Mansur Alexandra A.Mansur Luiz C.A.Oliveira Cinthia S.de Castro 2017Journal of Environmental Sciences2017,29,7:2
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