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| 1 | Rare earth element geochemistry of Post-to Neo-archean shales from Singhbhum mobile belt, Eastern India: implications for tectonic setting and paleo-oxidation conditions显示文摘In the present study, trace element(including rare earth element) chemical data has been interpreted with the aim to decipher the tectonic setting and paleo-redox conditions of the Post- to Neo-archean shales from the Singhbhum Mobile Belt, eastern India. The data show moderate enrichment of compatible elements [such as Cu(avg. 59.28 ppm), Ni(avg. 59.49 ppm), V(avg.234.24 ppm) and Cr(avg. 181.23 ppm)] relative to the Post-Archean Australian Shale. Their chondrite normalized light rare earth elements are moderately fractionated [(La/Sm)Nranges from 2.21 to 5.78], whereas heavy rare earth elements show a nearly flat pattern [(Gd/Lu)Nranges from0.74 to 1.68]; this indicates that the rare earth element(REE) concentrations, rather than being severely affected by the diagenesis and weathering processes, decreased gradually from Gd to Lu. The Post-Archean Australian Shale normalized multi-element diagram shows the slight enrichment of Cr, V, Zr, Y, U and Sc, whereas Sr, Pb, Hf and Th are depleted. The notable negative anomaly of Sr indicates the least accumulation of plagioclase, which is also supported by the negative Eu-anomaly in these rocks.The La–Th–Sc and Th–Zr–Sc tectonic setting diagrams indicate their continental arc setting. The geochemical parameters, such as U/Th, V/Cr, Ni/Co, and Cu/Zn, indicate that these shales were deposited under oxic to anoxic environmental conditions. | Akhtar R.Mir | 2015 | Chinese Journal Of Geochemistry2015，34，3： | 6 |
| 2 | Geochemistry of sedimentary rocks from Permian–Triassic boundary sections of Tethys Himalaya: implications for paleo-weathering, provenance, and tectonic setting显示文摘The geochemical characteristics of two sections—the Permian–Triassic boundary(PTB) Guryul Ravine section, Kashmir Valley, Jammu and Kashmir,India; and the Attargoo section, Spiti Valley, Himachal Pradesh, India—have been studied in the context of provenance, paleo-weathering, and plate tectonic setting.These sections represent the siliciclastic sedimentary sequence from the Tethys Himalaya. The PTB siliciclastic sedimentary sequence in these regions primarily consists of sandstones and shales with variable thickness. Present studied sandstones and shales of both sections had chemical index of alteration values between 65 and 74; such values reveal low-to-moderate degree of chemical weathering. The chemical index of weathering in studied samples ranged from 71 to 94, suggesting a minor K-metasomatism effect on these samples. Plagioclase index of alteration in studied sections ranged from 68 to 92, indicating a moderate degree of weathering of plagioclase feldspars. The provenance discriminant function diagram suggests that the detritus involved in the formation of present studied siliciclastic sedimentary rocks fall in quartzose sedimentary and felsic igneous provenances. These sediments were deposited in a passive continental margin plate tectonic setting according to their location on a Si_2 O versus K_2O/Na_2 O tectonic setting diagram. | Akhtar R.Mir V.Balaram Javid A.Ganai Shamim A.Dar A.Keshav Krishna | 2016 | Acta Geochimica2016，35，4： | 3 |
| 3 | Boninitic geochemical characteristics of high-Mg mafic dykes from the Singhbhum Granitoid Complex,Eastern India显示文摘The high-Mg mafic dykes from the Singhbhum Granitoid Complex in East India have geochemical characteristics[e.g.,enrichment of the large ion lithophile elements and light rare earth elements(LREEs) relative to high field strength elements(HFSEs):high-MgO(>8%),high-SiO_2(>52%),low-TiO_2(<0.5%),and high CaO/Al_2O_3(>0.58)]similar to those found in boninitic/noritic rocks.Their high percentage of orthopyroxene as a mafic mineral and of plagioclase as a felsic mineral,and normative hypersthene content greater than diopside content are also indications of their boninitic/noritic affinity.On a triangular diagram of MgO-CaO-Al_2O_3 and on binary diagrams of Ti/V vs Ti/Sc and TiO_2 vs Zr,these samples show geochemical similarities with Phanerozoic boninites and Paleoproterozoic high-Mg norites.On major and trace element variation diagrams,these dykes show a normal crystallization trend and their Nb/La(<0.5) and Nb/Ce(<0.21) values lower than average bulk crust(0.69 and0.33,respectively) suggest no crustal contamination.Their low values of Rb/Sr(0.11-0.41) and Rb/Ba(0.10-0.27)also suggest little or no effect of post magmatic processes.Their TiO_2(0.27-0.50),Al_2O_3/TiO_2(19.30-42.48),CaO/TiO_2(12.96-32.52),and Ti/V(12-18) values indicate derivation from a depleted mantle source under oxidizing conditions such as a mantle wedge.Ni vs Zr modeling shows that the studied high-Mg dykes were generated by25-30%melting of a refractory mantle source.Enrichment of Rb,Th,U,Pb,Sr,and LREEs,and depletion of HFSEs—especially Nb,P,Ti,Zr—on primitive mantle—and chondrite-normalized spider diagrams,respectively,are clear signals that the slab-derived component played an important role in the formation of melts for these rocks in a supra-subduction zone setting. | Akhtar R.Mir Shabber H.Alvi V.Balaram | 2015 | Chinese Journal Of Geochemistry2015，34，2： | 0 |
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