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| 1 | Recent progress of surface coating on cathode materials for high-performance lithium-ion batteries显示文摘Lithium-ion batteries (LIB) have received substantial attention in the last 10 years,as they offer great promise as power sources that can lead to the electric vehicle (EV) revolution in the next 5 years.Since the cathode serves as a key component in LIB,its properties significantly affect the performance of the whole system.Recently,the cathode surface modification based on coating technique has been widely employed to enhance the electrochemical performances by improving the material conductivity,stabilising the physical structure of materials,as well as preventing the reactions between the electrode and electrolyte.In this work,we reviewed the present of a number of promising cathode materials for Li-ion batteries.After that,we summarized the very recent research progress focusing on the surface coating strategies,mainly including the coating materials,the coating technologies,as well as the corresponding working mechanisms for cathodes.At last,the challenges faced and future guidelines for optimizing cathode materials are discussed.In this study,we propose that the structure of cathode is a crucial factor during the selection of coating materials and technologies. | Peiyuan Guan Lu Zhou Zhenlu Yu Yuandong Sun Yunjian Liu Feixiang Wu Yifeng Jiang Dewei Chu | 2020 | Journal of Energy Chemistry2020，29，4： | 28 |
| 2 | Electrochemical corrosion behavior of arc sprayed Zn-Al coatings显示文摘Cored wires and high velocity arc spraying (HVAS) technique were applied to produce high Al content Zn-Al alloy coatings on low carbon steel substrates. The electrochemical corrosion behaviors of Zn, Al and Zn-Al coatings were studied with potentiodynamic measurement in 5 % NaCl solution. Compared with pure Zn, pure Al and Zn-15Al coatings, Zn-26Al coatings show a higher corrosion resistance in salt solution. The potentiodynamic polarization tests show that the corrosion resistance of Zn-Al coatings increases as Al content is raised. Pure Al coating exhibits different electrochemical behaviors with other coatings. The corrosion initiated at the micro-pores of the coating and the underlying corrosion mechanism is very similar to that of the pitting corrosion. | LIU Yan ZHU Zi-xin CHEN Yong-xiong XU Bin-shi MA Shi-ning LI Zhuo-xin | 2004 | 中国有色金属学会会刊:英文版2004，14，z1： | 22 |
| 3 | Preparation and electrochemical properties of Sn/C composites显示文摘The metal tin(Sn),as one potential anode material for lithium-ion batteries,rapidly degrades its cyclic performance due to huge volume expansion/contraction during lithium intercalation/de-intercalation process.Amorphous carbon was adopted as conductive and buffer matrix to form Sn/C composites.The products were prepared by hydrothermal reaction and carbothermal reduction using tin tetrachloride and glucose as raw materials.The composites were characterized by X-ray diffraction(XRD),Raman spectroscopy,scanning electron microscopy(SEM),transmission electron microscopy(TEM),cyclic voltammetry(CV) and galvanostatic charge/discharge measurements.The results show that relative smaller metallic tin particles in 1:8 Sn/C composite are formed and distributed more uniformly in the carbon matrix.The lithium intercalation capacity of Sn/C composites reaches 820.4 mAh·g-1,and the capacity retention over 60 cycles remains 54.1%.1:8 Sn/C composite exhibits enhanced rate performance and cyclic stability compared to1:5 and 1:10 samples. | Bei-Ping Wang Rui Lv Dong-Sheng Lan | 2019 | Rare Metals2019，38，10： | 17 |
| 4 | A highly alkaline-stable metal oxide@metal-organic framework composite for high-performance electrochemical energy storage显示文摘Most metal-organic frameworks(MOFs) hardly maintain their physical and chemical properties after exposure to alkaline aqueous solutions,thus precluding their use as potential electrode materials for electrochemical energy storage devices.Here,we present the design and synthesis of a highly alkaline-stable metal oxide@MOF composite,Co3O4 nanocube@Co-MOF(Co3O4@Co-MOF),via a controllable and facile one-pot hydrothermal method under highly alkaline conditions.The obtained composite possesses exceptional alkaline stability,retaining its original structure in 3.0 M KOH for at least 15 days.Benefitting from the exceptional alkaline stability,unique structure,and larger surface area,the Co3O4@Co-MOF composite shows a specific capacitance as high as 1020 F g-1 at 0.5 A g-1 and a high cycling stability with only 3.3% decay after 5000 cycles at 5 A g-1.The as-constructed solid-state flexible device exhibits a maximum energy density of 21.6 mWh cm-3. | Shasha Zheng Qing Li Huaiguo Xue Huan Pang Qiang Xu | 2020 | National Science Review2020，7，2： | 16 |
| 5 | 烧结温度对Ti/IrO_2-Ta_2O_5纳米氧化物阳极微观结构和电催化性能的影响(英文)显示文摘采用Pechini法制备Ti/IrO2-Ta2O5纳米氧化物阳极,通过SEM、EDX、XRD、极化曲线、循环伏安、电化学阻抗谱及强化电解寿命试验等测试手段,研究了烧结温度对Ti/IrO2-Ta2O5阳极微观结构和电催化性能的影响。结果表明,阳极涂层成分分布均匀,IrO2晶粒偏析不明显;Ta在铱钽固溶体中的固溶度随烧结温度升高而增大,涂层晶粒逐渐细化。随着烧结温度的升高,阳极析氧电催化活性降低,电化学活性表面积减小;500℃下所得Ti/IrO2-Ta2O5阳极表现出最高的强化电解寿命。 | 辛永磊 许立坤 王均涛 李相波 | 2010 | 稀有金属材料与工程2010，39，11： | 16 |
| 6 | Current technology development for CO2 utilization into solar fuels and chemicals:A review显示文摘The continuous consumption of fossil fuels causes two important impediments including emission of large concentrations of CO2 resulting in global warming and alarming utilization of energy assets.The conversion of greenhouse gas CO2 into solar fuels can be an expedient accomplishment for the solution of both problems,all together.CO2 reutilization into valuable fuels and chemicals is a great challenge of the current century.Owing to limitations in traditional approaches,there have been developed many novel technologies such as photochemical,biochemical,electrochemical,plasma-chemical and solar thermochemical.They are currently being used for CO2 capture,sequestration,and utilization to transform CO2 into valuable products such as syngas,methane,methanol,formic acid,as well as fossil fuel consumption reduction.This review summarizes different traditional and novel thermal technologies used in CO2 conversion with detailed information about their working principle,types,currently adopted methods,developments,conversion rates,products formed,catalysts and operating conditions.Moreover,a comparison of these novel technologies in terms of distinctive key features such as conversion rate,yield,use of earth metals,renewable energy,investment,and operating cost has been provided in order to have a useful review for future research direction. | Azeem Mustafa Bachirou Guene Lougou Yong Shuai Zhijiang Wang Heping Tan | 2020 | Journal of Energy Chemistry2020，29，10： | 16 |
| 7 | Recent progress on lithium-ion batteries with high electrochemical performance显示文摘Lithium-ion batteries(LIBs) have been widely used in many fields such as portable electronics and electric vehicles since their successful commercialization in the 1990 s. However, the electrochemical performance of current commercial LIBs still needs to be further improved to meet the continuously increasing demands for energy storage applications. Recently, tremendous research efforts have been made in developing next-generation LIBs with enhanced electrochemical performance. In this review, we mainly focus on the recent progress of LIBs with high electrochemical performance from four aspects, including cathode materials, anode materials, electrolyte, and separators. We discuss not only the commercial electrode materials(LiCoO_2,LiFePO_4, LiMn_2O_4, LiNi_xMn_yCo_zO_2, LiNi_xCo_yAl_zO_2, and graphite) but also other promising next-generation materials such as Li-, Mn-rich layered oxides, organic cathode materials, Si, and Li metal. For each type of materials, we highlight their problems and corresponding strategies to enhance their electrochemical performance. Nowadays, one of the key challenges to construct high-performance LIBs is how to develop cathode materials with high capacity and working voltage. This review provides an overview and future perspectives to develop next-generation LIBs with high electrochemical performance. | Yong Lu Qiu Zhang Jun Chen | 2019 | Science China Chemistry2019，62，5： | 16 |
| 8 | Biomass-derived nitrogen-doped hierarchical porous carbon as efficient sulfur host for lithium–sulfur batteries显示文摘Lithium-sulfur(Li-S) battery is a potential energy storage technology with high energy density and low cost. However, the gap between theoretical expectation and practical performance limits its wide implementation. Herein, we report a nitrogen-doped porous carbon derived from biomass pomelo peel as sulfur host material for Li-S batteries. The hierarchical porous architecture and the polar surface introduced by N-doping render a favorable combination of physical and chemical sulfur confinements as well as an expedite electron/ion transfer, thus contributing to a facilitated and stabilized sulfur electrochemistry. As a result, the corresponding sulfur composite electrodes exhibit an ultrahigh initial capacity of 1534.6 mAh g^-1, high coulombic efficiency over 98% upon 300 cycles, and decent rate capability up to 2 C. This work provides an economical and effective strategy for the fabrication of advanced carbonaceous sulfur host material as well as the significant improvement of Li-S battery performance. | Qinghuiqiang Xiao Gaoran Li Minjie Li Ruiping Liu Haibo Li Pengfei Ren Yue Dong Ming Feng Zhongwei Chen | 2020 | Journal of Energy Chemistry2020，29，5： | 15 |
| 9 | CORROSION MONITORING OF LY12 IN SODIUM CHLORIDE SOLUTION WITH ELECTROCHEMICAL NOISE TECHNIQUE显示文摘Spontaneous electrochemical noise (EN) can be a rich source of information concerning the processes simultaneously occurring on a corroding interface. But the noise signal is often difficult to be analyzed due to the complicated nature of the specific systems being investigated. In this paper the potential noise fluctuations during the bee corrosion of commercial aluminum alloy LY12 in sodium chloride solution was recorded and analyzed with different techniques. The typical results showed that the fractal dimension (Dn) obtained from spectral power density (SPD) is mainly directly proportional to the intensity of pitting corrosion and to the value of pitting parameter (SE) derived hem dimensional analysis, while the fractal dimension (DE) obtained from EIS is mainly related to the uniform corrosion. | J.Q. Zhang, Z. Zhang, J.M. Wang, H.B. Shao and C.N. Cao (Department of Chemistry, Zhejiang University , Hangzhou 310027, China) (State Key Laboratory for Corrosion and Protection of Metals, Institute of Metal Research, The Chinese Academy of Sciences, She | 2001 | Acta Metallurgica Sinica(English Letters)2001，14，2： | 14 |
| 10 | Electrochemical performance of a nickel-rich LiNi0.6Co0.2Mn0.2O2 cathode material for lithium-ion batteries under different cut-off voltages显示文摘A spherical-like Ni_(0.6)Co_(0.2)Mn_(0.2)(OH)_2 precursor was tuned homogeneously to synthesize LiNi_(0.6)Co_(0.2)Mn_(0.2)O_2 as a cathode material for lithium-ion batteries.The effects of calcination temperature on the crystal structure,morphology,and the electrochemical performance of the as-prepared LiNi_(0.6)Co_(0.2)Mn_(0.2)O_2 were investigated in detail.The as-prepared material was characterized by X-ray diffraction,scanning electron microscopy,laser particle size analysis,charge–discharge tests,and cyclic voltammetry measurements.The results show that the spherical-like LiNi_(0.6)Co_(0.2)Mn_(0.2)O_2 material obtained by calcination at 900°C displayed the most significant layered structure among samples calcined at various temperatures,with a particle size of approximately 10 μm.It delivered an initial discharge capacity of 189.2 m Ah×g^(-1) at 0.2C with a capacity retention of 94.0% after 100 cycles between 2.7 and 4.3 V.The as-prepared cathode material also exhibited good rate performance,with a discharge capacity of 119.6 m Ah×g^(-1) at 5C.Furthermore,within the cut-off voltage ranges from 2.7 to 4.3,4.4,and 4.5 V,the initial discharge capacities of the calcined samples were 170.7,180.9,and 192.8 m Ah×g^(-1),respectively,at a rate of 1C.The corresponding retentions were 86.8%,80.3%,and 74.4% after 200 cycles,respectively. | Kai-lin Cheng Dao-bin Mu Bo-rong Wu Lei Wang Ying Jiang Rui Wang | 2017 | International Journal of Minerals,Metallurgy and Materials2017，24，3： | 14 |
| 11 | Recent progress on earth abundant electrocatalysts for hydrogen evolution reaction(HER) in alkaline medium to achieve efficient water splitting–A review显示文摘Developing earth-abundant-electrocatalysts for hydrogen evolution reaction is one of the promising ways to achieve efficient water-splitting for hydrogen production(a clean chemical fuel).This paper reviews the activity,stability and durability for hydrogen evolution reaction in alkaline medium of different types of recently reported potential electrocatalysts such as Ni,Co,NiCo,Fe,Cu,W,Mo,Se,Mn.Zn,V,and metal free based earth-abundant-electrocatalysts.Further,this paper reviews the strategies used to achieve the remarkably low overpotential(including r/i0:<35mV),high long term stability(including^:100 h)and high durability(including>5000 cycles)of potential earth-abundant-electrocatalysts for hydrogen evolution reaction in alkaline medium and those are better or well comparable with the state-of-the-art,noble,Pt/C electrocatalyst.Finally,this paper summarizes the efficient strategies such as preparing porous structured materials,preparing nanostructured materials with superaerophobic surface,preparing nanostructured materials,preparing carbon composites/integrating electrocatalysts with carbon,preparing amorphous materials,preparing materials w让h oxygen vacancies/defects,preparing metal chalcogenides,preparing bimetallic/multi-metallic materials,doping metals or heteroatoms,preparing electrocatalysts with core-shell structure,decorating electrocatalysts with amines,preparing homojunction/heterojunction structured materials,preparing hollow structured materials,and preparing boronrich surface to enhance the activity,stability,and durability for HER. | Jamesh Mohammed-Ibrahim xiaoming Sun | 2019 | Journal of Energy Chemistry2019，28，7： | 14 |
| 12 | Effect of temperature on corrosion behavior of 3003 aluminum alloy in ethylene glycol–water solution显示文摘The effect of temperature on the corrosion behavior of 3003 aluminum alloy in ethylene glycol–water solution was investigated by potentiodynamic polarization and electrochemical impedance spectroscopy(EIS) techniques. The surface characterization was observed and determined by scanning electron microscopy(SEM), atomic force microscopy(AFM) and energy dispersive spectrometer(EDS). The results demonstrate that the anodic aluminum dissolution and the cathodic oxygen reduction were accelerated by the increased temperature. However, as temperature was over60 °C, the solubility and concentration of oxygen decreased, resulting in the inhibition of cathodic reaction. The cathodic reaction rate of 3003 aluminum alloy rose to the maximum at 60 °C. The Warburg impedance in Nyquist diagram diminished and then was replaced by a negative capacitance caused by the absorption of intermediate corrosion product on electrode. On the other hand,after potentiodynamic measurements, 3003 aluminum alloy suffered pitting corrosion. The dissolution of aluminum alloy around secondary phase particles expanded both horizontally and vertically. | Chen Xin Tian Wenming Li Songmei Yu Mei Liu Jianhua | 2016 | Chinese Journal of Aeronautics2016，29，4： | 14 |
| 13 | Electrochemical synthesis of ammonia using a cell with a Nafion membrane and SmFe_(0.7)Cu_(0.3-x)Ni_xO_3(x=0―0.3) cathode at atmospheric pressure and lower temperature显示文摘Samaria-doped ceria Ce0.8Sm0.2O2-δ(SDC) and SmFe0.7Cu0.3-xNixO3 have been synthesized by the sol-gel method and characterized by X-ray diffraction(XRD),transmission electron microscopy(TEM) and scanning electron microscopy(SEM).The electrochemical synthesis of ammonia was investigated at atmospheric pressure and low temperature,using the SFCN materials as the cathode,a Nafion membrane as the electrolyte,nickel-doped SDC(Ni-SDC) as the anode and silver-platinum paste as the current collector.Ammonia was synthesized from 25 to 100℃ when the SFCN materials were used as cathode,with SmFe0.7Cu0.1Ni0.2O3 giving the highest rates of ammonia formation.The maximum rate of evolution of ammonia was 1.13 × 10-8 mol·cm-2·s-1 at 80℃,and the current efficiency reached as high as 90.4%. | XU GaoChao,LIU RuiQuan & WANG Jin College of Chemistry and Chemical Engineering,Xinjiang University,Urumqi 830046,China | 2009 | Science China Chemistry2009，52，8： | 11 |
| 14 | Study on stabilities and electrochemical behavior of V(V) electrolyte with acid additives for vanadium redox flow battery显示文摘Several acid compounds have been employed as additives of the V(V) electrolyte for vanadium redox flow battery(VRB) to improve its stability and electrochemical activity. Stability of the V(V) electrolyte with and without additives was investigated with ex-situ heating/cooling treatment at a wide temperature range of-5 ?C to 60 ?C. It was observed that methanesulfonic acid, boric acid, hydrochloric acid, trifluoroacetic acid,polyacrylic acid, oxalic acid, methacrylic acid and phosphotungstic acid could improve the stability of the V(V) electrolyte at a certain range of temperature. Their electrochemical behaviors in the V(V) electrolyte were further studied by cyclic voltammetry(CV), steady state polarization and electrochemical impedance spectroscopy(EIS). The results showed that the electrochemical activity, including the reversibility of electrode reaction, the diffusivity of V(V) species, the polarization resistance and the flexibility of charge transfer for the V(V) electrolyte with these additives were all improved compared with the pristine solution. | Gang Wang Jinwei Chen Xueqin Wang Jing Tian Hong Kang Xuejing Zhu Yu Zhang Xiaojiang Liu Ruilin Wang | 2014 | Journal of Energy Chemistry2014，23，1： | 10 |
| 15 | ZnO@MOF@PANI core-shell nanoarrays on carbon cloth for high-performance supercapacitor electrodes显示文摘Hierarchical ZnO@metal-organic framework @polyaniline(ZnO@MOF@PANI) core-shell nanorod arrays on carbon cloth has been fabricated by combining electrodeposition and hydrothermal method. Well-ordered Zn O nanorods not only act as a scaffold for growth of MOF/PANI shell but also as Zn source for the formation of MOF. The morphology of ZnO@MOF@PANI composite is greatly influenced by the number of PANI electrodeposition cycles. Their structural and electrochemical properties were characterized with different techniques. The results indicate that the Zn O@MOF@PANI with 13 CV cycles of PANI deposition demonstrates the maximum specific capacitance of 340.7 F g-1 at 1.0 A g-1, good rate capability with84.3% capacitance retention from 1.0 to 10 A g-1 and excellent cycling life of 82.5% capacitance retention after 5000 cycles at high current density of 2.0 A g-1. This optimized core-shell nanoarchitecture endows the composite electrode with short ion diffusion pathway, rapid ion/electron transfer and high utilization of active materials, which thus result in excellent electrochemical performance of the ternary composite. | Chunmei Zhu Ying He Yijun Liu Natalia Kazantseva Petr Saha Qilin Cheng | 2019 | Journal of Energy Chemistry2019，28，8： | 10 |
| 16 | Nanodendrites of platinum-group metals for electrocatalytic applications显示文摘Developing highly efficient and durable catalysts for future electrochemical and energy applications is one of the main subjects of current studies in renewable energy generation.In the past several years,researchers have developed Pt-based ,alloy electrocatalyst nanomaterials that exhibit promising electrocatalytic properties for various electrochemical applications.The efficient structural and morphological control of Pt-based alloy materials plays a decisive role in achieving these enhanced electrocatalytic properties.The present review article emphasizes the recent progress and important developments in the synthesis and electrocatalytic applications of Pt-group-based nanodendrite materials.The following review will help the exploration and development of better catalysts for practical applications and aims to elucidate the nanodendrite structure of Pt-group metals. | Nitin K.Chaudhari Jinwhan Joo Hyuk-bu Kwon Byeongyoon Kim Ho Young Kim Sang Hoon Joo Kwangyeol Lee | 2018 | Nano Research2018，11，12： | 10 |
| 17 | Effect of scanning speeds on electrochemical corrosion resistance of laser cladding TC4 alloy显示文摘In order to study the effect of scanning speed on the electrochemical corrosion resistance of laser cladding TC4 alloy in artificial seawater, the x-ray diffraction analysis, microstructure of cross-section, microhardness variation, and impedance spectrum have been studied in comparison with the TC4 titanium alloy. The results show that the main phase of cladding coating is α-Ti, and the change of scanning speed has no obvious effect on it; therefore, the supersaturated α-Ti solid solution is formed, and the acicular α martensite is obtained. As the scanning speed increases, the microstructure of cladding coating is orthogonal basket-weave, the crystal surface spacing decreases, and the average microhardness of laser cladding TC4 alloy slightly increases. When the scanning speed increases to 10 mm/s, the microhardness is about 14.71%higher than that of the substrate, and the electrochemical corrosion resistance of laser cladding TC4 alloy is also improved,which is about 2.48 times more than the substrate. Grain refinement has a great effect on enhancing the anti-electrochemical corrosion. | 冯晓甜 雷剑波 顾宏 周圣丰 | 2019 | Chinese Physics B2019，28，2： | 10 |
| 18 | Electrochemical behaviors of Zn-Fe alloy and Zn-Fe-TiO_2 composite electrodeposition显示文摘Electrochemical behaviors of Zn-Fe alloy and Zn-Fe-TiO2 composite electrodeposition in alkaline zincatesolutions were studied respectively by the methods of linear potential sweep and cyclic voltammetry. From the re-sults it can be concluded that Zn shows under potential deposition, Zn-Fe alloy codeposition is anomalous codeposi-tion and Zn-Fe alloy cathode polarization is increased with the introduction of additive. From the view point of elec-trochemistry, the reasons that the content of Fe in the Zn-Fe coating changes with the composition of the electrolyteand the process conditions altering and the relationship between the content of Fe and the appearance of the coatingare interpreted. The cathode polarization of Zn-Fe alloy codeposition is enhanced obviously with addition of additive.In the course of composite electrodeposition, TiO2 has less promotion to electrodeposition of zinc ions than to iron i-ons, while the electrodeposition of iron ions improves the content of TiO2 in composite coating, which is inagreement with the results of process experiments. | 王云燕 彭文杰 柴立元 舒余德 | 2003 | Journal of Central South University of Technology2003，10，3： | 10 |
| 19 | Li-Si合金中间相作为锂离子电池负极材料的研究(英文)显示文摘采用基于密度泛函理论的第一性原理平面波赝势方法计算了Li-Si各种合金相的物理性质和电化学性能。结果表明:除了在反应过程中生成传统的固态电解质SEI膜之外,形成的Li12Si7合金相也是部分导致首次不可逆容量损失的重要原因。另外,采用射频磁控溅射制备了纯Si薄膜电极,并运用XRD、循环伏安CV、恒流充放电CC表征和测试了材料的结构和电化学性能,结果表明首次不可逆容量损失非常大,无定型结构能有效抑制体积膨胀和改善循环性能。 | 侯贤华 胡社军 汝强 张志文 | 2010 | 稀有金属材料与工程2010，39，12： | 9 |
| 20 | Electrochemical processing of spent nuclear fuels:An overview of oxide reduction in pyroprocessing technology显示文摘The electrochemical reduction process has been used to reduce spent oxide fuel to a metallic form using pyroprocessing technology for a closed fuel cycle in combination with a metal-fuel fast reactor.In the electrochemical reduction process,oxides fuels are loaded at the cathode basket in molten Li_2O–LiCl salt and electrochemically reduced to the metal form.Various approaches based on thermodynamic calculations and experimental studies have been used to understand the electrode reaction and efficiently treat spent fuels.The factors that affect the speed of the electrochemical reduction have been determined to optimize the process and scale-up the electrolysis cell.In addition,demonstrations of the integrated series of processes(electrorefining and salt distillation) with the electrochemical reduction have been conducted to realize the oxide fuel cycle.This overview provides insight into the current status of and issues related to the electrochemical processing of spent nuclear fuels. | Eun-Young Choi Sang Mun Jeong | 2015 | Progress in Natural Science:Materials International2015，25，6： | 9 |
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