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    题名 作者 年代 出处 被引量
1壮医药高等教育发展现状与问题分析显示文摘壮医药高等教育是新兴的医药教育,具有浓郁的民族特色和地方特色。对广西壮医药高等教育的现状进行了广泛的调研,对存在问题和对策进行分析探讨,并为解决问题提出了相应的对策。罗婕 庞宇舟 2014大众科技2014,16,2:7
2Self-assembly behavior of phenyl modified β-cyclodextrins显示文摘The self-assembly behavior of mono(6-phenolic-6-deoxy)-β-cyclodextrin (1) both in solu- tion and the solid state is comparatively studied by X-ray crystallography and 1H NMR spectroscopy. The results obtained show that the phenolic groups in the crystal 1 can successively penetrate into the adjacent β-cyclodextrin cavities from the secondary side to form head-to-tail linear polymeric su- pramolecule with a 2-fold screw axis. The self-assembly behavior also can be determined in D2O so- lution, giving a self-association constant of 240 mol?1?L. Using the present and previous structures reported for the relevant β-cyclodextrin derivatives, i.e., mono(6-anilino-6-deoxy)-β-cyclodextrin (2), mono(6-phenylselenyl-6-deoxy)-β-cyclodextrin (3), and mono(6-phenylthio-6-deoxy)-β-cyclodextrin (4), we further reveal the factors governing the formations of supramolecular assemblies.ZHAO Yanli LIU Yu 2006Science China Chemistry2006,49,3:1
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