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| 1 | Stimuli-responsive Membranes: Smart Tools for Controllable Mass-transfer and Separation Processes显示文摘As emerging artificial biomimetic membranes, smart or intelligent membranes that are able to respond to environmental stimuli are attracting ever-increasing interests from various fields. Their permeation properties including hydraulic permeability and diffusional permeability can be dramatically controlled or adjusted self-regulatively in response to small chemical and/or physical stimuli in their environments. Such environmental stimuli-responsive smart membranes could find myriad applications in numerous fields ranging from controlled release to separations. Here the trans-membrane mass-transfer and membrane separation is introduced as the beginning to initiate the requirement of smart membranes, and then bio-inspired design of environmental stimuli-responsive smart membranes and four essential elements for smart membranes are introduced and discussed. Next, smart membrane types and their applications as smart tools for controllable mass-transfer in controlled release and separations are reviewed. The research topics in the near future are also suggested. | 褚良银 谢锐 巨晓洁 | 2011 | Chinese Journal of Chemical Engineering2011,19,6: | 18 |
| 2 | 环境响应型智能开关膜的研究进展显示文摘综述环境响应型智能开关膜的制备方法和分类,并分别介绍温度响应型、光响应型、电场响应型、pH响应型以及分子识别响应型等智能开关膜的研究现状. | 谢锐 褚良银 | 2007 | 膜科学与技术2007,27,4: | 10 |
| 3 | 智能膜材料研究新进展显示文摘能感知和响应外界物理和化学信号的智能膜是仿生功能膜领域的重要技术进展之一,已成为国际上膜科学领域研究的新热点。本文综述了智能膜材料方面的研究新进展,重点介绍了温度响应型、pH响应型、光响应型、葡萄糖浓度响应型以及分子识别响应型等环境刺激响应型智能膜的研究进展。 | 褚良银 谢锐 巨晓洁 | 2011 | 化工进展2011,30,1: | 6 |
| 4 | 智能化微囊膜研究新进展显示文摘智能化控制释放系统一直是国内外科技工作者的研究热点,迄今已经研究报道了多种具有不同工作原理的环境感应型智能化微囊膜。本文介绍作者近几年在温度感应型、葡萄糖浓度感应型以及分子识别型等环境感应型智能化微囊膜方面取得的成果,并展望该领域的发展趋势。 | 褚良银 | 2007 | 中国科技论文在线2007,2,8: | 2 |
| 5 | 环境响应型控制释放微载体材料研究新进展显示文摘环境响应型智能微载体材料可以响应温度、pH值、磁场、化学物质等环境刺激的微小变化,实现物质的自律式控制释放,在药物送达、酶和细胞固定化、分离纯化等领域显示出突出的优越性,具有广泛应用前景。综述了环境响应型控制释放微载体材料的研究进展,介绍了'开-关模式'控释微囊和'突释模式'控释微囊等环境响应型控释微载体材料的研究新进展,着重介绍了温度响应型、血糖浓度响应型、离子识别响应型'开-关模式'控释微囊以及温度响应型、pH响应型、离子识别响应型'突释模式'控释微囊的制备与性能方面的研究新成果。目前,环境响应型智能微载体材料仍多处于基础研究阶段,还需要进一步系统深入研究和开发完善。 | 巨晓洁 谢锐 褚良银 | 2012 | 中国材料进展2012,31,2: | 2 |
| 6 | 聚(N-异丙基丙烯酰胺-共-苯并-18-冠-6丙烯酰胺)共聚高分子的醇和离子综合响应性能(英文)显示文摘In this paper, we report on the comprehensive alcohol-/ion-responsive properties of a smart copolymer poly(Nisopropylacrylamide-co-benzo-18-crown-6-acrylamide)(P(NIPAM-co-BCAm)). The orthogonal design method is adopted for experimental design. The experimental results show that alcohol can trigger the shrinking and Ba2+can induce the swelling of the P(NIPAM-co-BCAm) copolymer. According to the phase transition temperature(LCST) change results of the copolymer, the influence of variables on the LCST changes weakens in the following order: alcohol concentration N alcohol species N metal ion species N BCAm concentration N ion concentration. The larger the alcohol concentration and the larger the molecular size of alcohols, the lower the LCST value; on the contrary, the more the BCAm content in the copolymer or the larger the BCAm/ion complex stability constant(lgK) or the larger the ion concentration is, the higher the LCST value. For a P(NIPAM-co-BCAm)copolymer with a fixed BCAm content, a binary function of ion concentration and lgK of BCAm/ion is developed to precisely predict the LCST values of the copolymer in different metal ion solutions. The results provide valuable information for fabricating artificial biomimetic G-protein-gated inwardly rectifying potassium(GIRK) channels that are activated by alcohol and inhibited by Ba^(2+). | 巨晓洁 皮硕伟 谢锐 郭晓静 柳杰译 余亚兰 江潞 陆小华 陈谦明 褚良银 | 2014 | Chinese Journal of Chemical Engineering2014,22,9: | 0 |
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