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1Preparation of CIP@TiO_(2) composite with broadband electromagnetic wave absorption properties显示文摘Scholars aim for the improved impedance matching (Z) of materials while maintaining their excellent wave absorption properties. Based on the hydrolysis characteristics of isopropyl titanate, a simple preparation process for the coating of carbonyl iron powder(CIP) with TiO_(2) was designed. Given the TiO2coating, the Z of the CIP@TiO_(2) composite was adjusted well by decreasing the dielectric constant. Moreover, the interfacial polarization of CIP@TiO_(2) was enhanced. Ultimately, the electromagnetic-wave (EMW) absorption property of the CIP@TiO_(2)composite was improved substantially, the minimum reflection loss reached-46.07 dB, and the effective absorption bandwidth can reach 8 GHz at the composite thickness of 1.5 mm. Moreover, compared with CIP, the oxidation resistance of CIP@TiO_(2)showed remarkable improvement. The results revealed that the oxidation starting temperature of CIP@TiO_(2) as about 400℃,whereas the uncoated CIP had an oxidation starting temperature of approximately 250℃. Moreover, the largest oxidation rate temperature of CIP@TiO_(2) increased to around 550℃. This work opens up a novel strategy for the production of high-performance EMW absorbers via structural design.Qiang Su Hanqun Wang Yunfei He Dongdong Liu Xiaoxiao Huang Bo Zhong 2024International Journal of Minerals,Metallurgy and Materials2024,31,1:0
2Self-assembly tungsten selenide hybrid ternary MOF derived magnetic alloys via multi-polarization to boost microwave absorption显示文摘Confronted with severe electromagnetic wave pollution,the development of high-performance electromagnetic wave shielding or absorbing materials is an effective way to deal with it.Notably,double transition metal alloys and transition metal dichalcogenides have attracted extensive attention in electromagnetic wave absorption,but few reports have studied the effects of these two materials on electromagnetic wave absorption at the same time.In this work,cobalt-based alloy with magnetic loss mechanism was selected for composition optimization.The ternary metal-organic framework was prepared by the one-step method,and then CoCu/C was prepared by high temperature annealing.Finally,in the hydrothermal process,ultra-thin tungsten selenide nanosheets were coated on the surface of magnetic component,and the final polyhedral WSe_(2)/CoCu/C composites with multiple heterogeneous interfaces were obtained.The synergistic effect of dielectric and magnetic components optimizes impedance matching and allows more electromagnetic waves to enter the absorber.Subsequently,through the conduction loss of high conductivity graphitized carbon,interfacial polarization,and dipole polarization of heterogeneous interfaces between the components,the magnetic loss provided by CoCu alloy can work together to maximize the attenuation ability of electromagnetic waves.Exactly,the minimum reflection loss(RLmin)value of the composite reaches-53.43 dB when the matched thickness is 2.1 mm,while the maximum effective absorption bandwidth(EABmax)reaches 6.0 GHz at a thin thickness of 1.8 mm.This work provides some support and reference for the design of novel electromagnetic wave absorbing materials via the dielectric/magnetic loss synergistic mechanism.Tianbao Zhao Tingting Zheng Di Lan Yan Zhang Zhengshuo Sun Chao Wang Zirui Jia Guanglei Wu 2024Nano Research2024,17,3:0
3Three-dimensional macroscopic absorbents: From synergistic effects to advanced multifunctionalities显示文摘The accelerated arriving of 5G era has brought a new round of intelligent transformation which will completely emancipate smart terminal devices.While the subsequent deleterious effect of electromagnetic wave on electronic devices is increasingly serious,driving the growth of next-generation electromagnetic wave absorbents.As a tactful combination of components and structures,three-dimensional(3D)macroscopic absorbents with fascinating synergy afford exceptional electromagnetic wave absorption,and tremendous efforts have been devoted to this investigation.However,in terms of macroscopic absorbents and their synergistic effect,few reviews are proposed to comb the latest achievements and detailed synergy.This review article focuses on the synergistic effect of macro-architectured absorbents mainly including structure-induced synergy,structure-components synergy,and multiple-components induced synergy.And then the potential construction principles and strategies of macroscopic absorbents are combed.Significantly,the key information for structures and components manipulation including nano-micro design and components regulation is further dissected by critically selected cutting-edge 3D macroscopic absorbents.Moreover,a brief summary of multifunctional electromagnetic wave absorbents(EWAs)-based macroscopic structures is presented.Finally,the development prospects and challenges of these materials are discussed.Shijie Zhang Di Lan Xingliang Chen Yueyuan Gu Junwen Ren Suxuan Du Shichang Cai Xiaomiao Zhao Zhiwei Zhao Guanglei Wu 2024Nano Research2024,17,3:0
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