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1Observation of ambipolar photoresponse from 2D MoS_(2)/MXene heterostructure显示文摘Two-dimensional materials have been demonstrated as promising toolboxes for optoelectronics.Transition metal carbides and nitrides(MXenes),members of an emerging family of two-dimensional materials,have drawn extensive attention in optoelectronics owing to their excellent conductivity and tunable electronic properties.Herein,a photodetector based on the two-dimensional van der Waals heterostructure of Ti_(3)C_(2)T_(x)MXene and a MoS_(2)monolayer was constructed to observe the ambipolar photoresponse,which showed a positive photoresponse in the visible spectrum(500-700 nm)and a negative photoresponse at longer wavelengths(700-800 nm).The device exhibited a high negative responsivity of 1.9 A/W and a detectivity of 2.1×10^(10)Jones under 750 nm light illumination.Detailed experiments demonstrate that the negative photoresponse arises from the heterostructureinduced trap energy level,which confines the excited photoelectrons and leads to an inverse current.This work demonstrates a unique optoelectronic phenomenon in MoS_(2)/MXene heterostructures and provides valuable insights into the development of new photodetection materials.Juntong Zhu Hao Wang Liang Ma Guifu Zou 2021Nano Research2021,14,10:3
2Realizing nearly isotropic thermoelectric properties in 2D-layered SnS nanomaterials through highly symmetric metastable-phase powder precursors显示文摘Metastable materials offer a broad and novel platform for the development of next-generation science and technology.Phase engineering including synthesis of materials with unconventional phases and phase transition of metastable materials has been explored in layered materials but has not tackled their anisotropy issue yet.The high anisotropy in layered materials further adds the cost of orientation screening of materials.Herein,we report the effect of Ag doping on facilitating the formation of metastableπ-cubic phase SnS during the solvothermal synthesis process.On this basis,we construct cubic-to-orthorhombic(CTO)samples and elucidate the intrinsic mechanisms of its nearly isotropic thermoelectric properties by characterizing the texturing information and analyzing the valence charge density calculated by density functional theory(DFT).This work demonstrates a convenient approach to synthesize layered materials with isotropic electrical and thermal transport behaviors through a precursor of metastable phase.Fanshi Wu Junjie Yuan Wenxin Lai Liangwei Fu Biao Xu 2022Nano Research2022,15,8:0
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