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| 1 | Pd-Catalyzed Intermolecular Dearomative Heck Reaction of Indole Derivatives显示文摘Dearomatization of indole derivatives[1,2]provides a straightforward approach for synthesizing diverse indolines which serve as the structural core of numerous natural products and pharmaceuticals.[3]Over the past decade,Pd-catalyzed Heck reaction[4]has been applied in the dearomatization of indoles.In this regard,several elegant intramolecular dearomative Heck reactions of indoles have been developed.[s]However,to date,the reported works are mainly limited to intramolecular reactions,which proceed viaβ3-hydride elimination or trapping by an additional nucleophile(Scheme 1(a)).However,additional synthetic elaboration is usually required to access appropriate substrates for the key dearomatization step,thus reducing the synthetic efficiency. | Ping Yang | 2020 | Chinese Journal of Chemistry2020，38，5： | 1 |
| 2 | Pd-Catalyzed Asymmetric Intramolecular Arylative Dearomatization of para-Aminophenols显示文摘Background and Originality Content.In recent years,Pd-catalyzed arylative dearomatization reactions have attracted wide interests of organic chemists for the efficient construction of privileged molecular scaffolds that appear in important natural products.[l]A large array of aromatic compounds,such as anilines,121 phenols,[3]indoles,[4]pyrroles,[3]pyridines[6]and furans171 have been successfully applied in the arylative dearomatization strategy via Pd-catalyzed cross coupling reactions. | Ren-Qi Xu Ping Yang Chao Zheng Shu-Li You | 2020 | Chinese Journal of Chemistry2020，38，7： | 1 |
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