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| 1 | Mesoporous Graphene Hosts for Dendrite-Free Lithium Metal Anode in Working Rechargeable Batteries显示文摘Lithium(Li) metal anode has received extensive attentions due to its ultrahigh theoretical capacity and the most negative electrode potential. However, dendrite growth severely impedes the practical applications of the Li metal anode in rechargeable batteries. In this contribution, a mesoporous graphene with a high specific surface area was synthesized to host the Li metal anode. The mesoporous graphene host(MGH) has a high specific surface area(2090 m^2/g), which affords free space and an interconnected conductive pathway for Li plating and stripping, thus alleviating the volume variation and reducing the generation of dead Li during repeated cycles. More importantly, the high specific surface area of MGH efficiently reduces the local current density of the electrode, which favors a uniform Li nucleation and plating behavior, rendering a dendritefree deposition morphology at a low overpotential. These factors synergistically boost the Li utilization(90.1% vs. 70.1% for Cu foil) and life span(150 cycles vs. 100 cycles for Cu foil) with a low polarization of MGH electrode at an ultrahigh current of 15.0 mA/cm^2. The as-prepared MGH can provide fresh insights into the electrode design of the Li metal anode operating at high rates. | He Liu Xinbing Cheng Rui Zhang Peng Shi Xin Shen Xiaoru Chen Tao Li Jiaqi Huang Qiang Zhang | 2020 | Transactions of Tianjin University2020，26，2： | 9 |
| 2 | 锂离子在三维骨架复合锂金属负极中的沉积规律显示文摘锂金属具有极高的理论比容量和极低的氧化还原电极电势,成为了新一代高比能二次电池最理想的负极材料。然而,锂金属负极其走向大规模应用仍存在诸多问题与挑战。三维骨架复合负极可以控制金属锂均匀形核,低电流密度下均匀沉积,有望推动锂金属负极的实用化。为了更高效地指导锂金属负极设计和优化,采用相场理论,对三维骨架锂金属负极中比表面积对金属锂沉积过程的作用机制进行了定量分析和探究,发现了比表面积调控金属锂沉积的两阶段作用机理,并提出了基于比表面积参数的三维骨架负极设计与优化方向,从而最大程度发挥三维骨架在调控稳定金属锂负极上的积极作用。 | 张睿 沈馨 王金福 张强 | 2020 | 化工学报2020，71，6： | 9 |
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