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| 1 | 光(电)催化氮气还原合成氨研究进展显示文摘光(电)催化氮气还原技术利用天然太阳能作为能源,具有成本低、反应条件温和等众多优势,可解决传统工业合成氨Haber-Bosch工艺的高能耗以及高CO_2排放等问题,被认为是目前最具前景的新兴合成氨技术之一。由于氮气为非极性分子,在水中溶解度极低,且本身呈现化学惰性,难以被活化,使得整体的氮气还原转化合成氨效率较低。同时,光生载流子的利用率也显著影响整体的催化效率。为此,光(电)催化氮气还原技术的关键在于催化剂的设计和催化反应体系的优化。本文在介绍光(电)催化氮气还原合成氨反应过程以及机理的基础上,主要从促进氮气溶解扩散、氮气吸附和活化以及强化载流子分离和传输等具体反应过程出发,重点综述近期国内外在光(电)催化氮气还原合成氨领域基于上述反应过程强化的最新研究现状。最后,指出了目前光(电)催化氮气还原合成氨研究领域面临的挑战,并对此领域的未来发展趋势进行了分析与展望。 | 任晓玲 严孝清 龚湘姣 吴志强 杨伯伦 魏进家 杨贵东 | 2020 | 化工进展2020，39，12： | 6 |
| 2 | Anti-vapor-penetration and condensate microdrop self-transport of superhydrophobic oblique nanowire surface under high subcooling显示文摘It is well-known that microscale gaps or defects are ubiquitous and can be penetrated by vapor,resulting in the failure of superhydrophobic effect and undesired condensate flooding under high subcooling.Here,we propose and demonstrate that such problem can be solved by the oblique arrangement of nanowires.Such a structure has been demonstrated to own anti-vapor-penetration and microdrop self-transport functions under high subcooling,unaffected by the microscale gaps.This is because vapor molecules can be intercepted by oblique nanowires and preferentially nucleate at near-surface locations,avoiding the penetration of vapor into the microscale gaps.As-formed microdrops can suspend upon the nanowires and have low solid-liquid adhesion.Besides,oblique nanowires can generate asymmetric surface tension and microdrop coalescence can release driving energy,both of which facilitate the microdrop self-removal via sweeping and jumping ways.This new design idea helps develop more advanced condensation mass and heat transfer interfaces. | Rui Wang Feifei Wu Fanfei Yu Jie Zhu Xuefeng Gao Lei Jiang | 2021 | Nano Research2021，14，5： | 1 |
| 3 | Two-dimensional oxide derived from high-temperature liquid metals via bubble templating显示文摘Two-dimensional(2D)oxide can be continuously produced by bubbling oxygen into liquid metals and the harvesting of these oxide relies on the proper choice of dispersion solvents.The mass-production of ligand-free 2D materials from high melting-point metals will not be possible if the limited stability of the traditional dispersion solvents is not circumvented.Herein,liquid tin was used for the first time in the bubbling protocol and 2D tin oxide was obtained in molten salts.The nanosheets were studied with combined microscopic and spectroscopic techniques,and high-density grain boundaries was identified between the sub-5-nm nano-crystallites in the nanosheets.It gives rise to the high performance in electrocatalytic CO_(2) reduction reaction.Density-functional-theory based calculation was applied to achieve a deeper understanding of the relationship between the activity,selectivity,and the grain-boundary features.The molten-salt based protocol could be explored for the synthesis of a library of functional 2D oxides. | Zheng Hu Tingbiao Yuan Hui Li Yishu Qiu Wei Zhou Jiangwei Zhang Yuxin Zhao Shi Hu | 2021 | Nano Research2021，14，12： | 0 |
| 4 | 钴铁层状双金属氢氧化物空心多面体用于高效电催化二氧化碳还原显示文摘可再生能源驱动电催化二氧化碳还原制备高附加值化学燃料,是一种实现二氧化碳资源化的有效途径.以金属有机骨架(MOF)为模板制备的层状双金属氢氧化物空心多面体已成为当前电催化领域的热门材料.然而,该类材料的高析氢活性严重阻碍了其在电催化二氧化碳还原中的应用.基于此,本文报道了一种在离子液体电解液中可高效稳定电催化二氧化碳还原的钴铁层状双金属氢氧化物空心多面体(CoFe LDH/HP),其最大法拉第转换效率可达86%±3%(-0.9 V相对于可逆氢电极),且可连续电解30 h.实验结果表明此CoFe LDH/HP因其独特的空心结构可暴露更多的活性位点,从而具有更快的电催化二氧化碳还原动力学;理论计算表明CoFe LDH/HP中Co-O-Fe键有利于稳定关键中间体(*COOH)并降低相应的活化势垒.本研究可为其他层状双金属氢氧化物用于二氧化碳固定的设计提供参考. | 杨淼森 孙甲强 秦永吉 杨慧 张书胜 刘熙俊 罗俊 | 2022 | Science China Materials2022，65，2： | 0 |
| 5 | Hydrophobic 1-octadecanethiol functionalized copper catalyst promotes robust high-current CO_(2) gas-diffusion electrolysis显示文摘The electrocatalytic reduction of CO_(2) presents a promising strategy in addressing environmental and energy crisis.Significant progress has been achieved via CO_(2) gas diffusion electrolysis,to react at high selectivity and high rate.However,the gas diffusion layer(GDL)of the gas diffusion electrode(GDE)still suffers from low tolerance and limited active sites.Here,the hydrophobic 1-octadecanethiol molecular was functionalized over the Cu catalyst layer of the GDE,which simultaneously stabilizes the GDL and exposes abundant active solid-liquid-gas three-phase interfaces.The resultant GDE exhibits multi-carbon(C_(2+))product selectivity over faradaic efficiency(FE)of 70.0%in the range of 100 to 800 mA·cm^(-2),with the peak FE^(c2+)of 85.2%at 800 mA·cm^(-2).Notably,the strengthened GDE could continuously drive high-current electrolysis for more than 100 h without flooding.This work opens a new way to improve CO_(2) gas diffusion electrolysis via surface molecular engineering. | Liangyao Xue Xuefeng Wu Yuanwei Liu Beibei Xu Xuelu Wang Sheng Dai Pengfei Liu Huagui Yang | 2022 | Nano Research2022，15，2： | 0 |
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