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1Synthesis of TiO2@ZnIn2S4 hollow nanospheres with enhanced photocatalytic hydrogen evolution显示文摘In this work,we designed and prepared the novel TiO2@ZnIn2 S4 nano-sized hollow structure via templating method assisted by hydrothermal synthesis process.Its unique hollow structure and type-II heterojunction between TiO2 hollow nanospheres and ZnIn2 S4 nanosheet can provide enough interior cavities and transfer paths for the light absorption and charge quick migration.The crystal structure,morphology and charges separation property were measured.The characterization results show that the hollow-structured Ti O2@ZnIn2 S4 was successfully prepared,and the optimal sample exhibited excellent photocatalytic hydrogen generation compared with TiO2/ZnIn2 S4 cluster exceeding by a factor of 1.1 under overall light irradiation.Specially,the detailed mechanism of the photocatalytic H2 evolution and charge carrier migration for the as-prepared TiO2@ZnIn2 S4 hollow nanosphere was also studied.He Li Zi-Hao Chen Lei Zhao Gui-Dong Yang 2019Rare Metals2019,38,5:9
2Microwave-assisted hydrothermal synthesis of copper oxide-based gas-sensitive nanostructures显示文摘Hydrothermal methods are widely used in chemical synthesis of target products with specific morphology and nanostructure.Those methods are very efficient for the preparation of well-controlled structures but the reaction time is usually long.The assistance of microwave makes the reaction system heat up faster,more uniformly and reactions are accelerated,it also can be utilized to change the morphology or structure of materials,which improves the physic-chemical properties of synthesized products and influences its gas-sensing performance.Copper oxide(CuO)is widely applied in semiconductor gas sensors because of its good reactivity and stability.This review article briefly introduces the principle,mechanism and recent development of CuO nanostructures obtained by microwave-as sis ted hydrothermal synthesis(MWHS)process.It also discussed the relation between endopathic factors of material and its gas-sensitive performance.The technical challenges and prospective solutions for highperformance CuO-based gas-sensitive materials with unique nanostructure are proposed.It is pointed out that the hierarchical CuO-based nanostructures and their composite materials prepared by MWHS process are efficacious methods to improve the gas-sensitive performance of the materials.On the basis of the morphology,the materials are divided into nanorods,nanoflowers,nanosheets,nanospheres and other nanostructures.The influence of microwave parameters on the properties of synthetic products is analyzed.The influence followed by metal element loading on the structure and properties of CuO-based materials by MWHS process is further discussed.Then this review summarizes the research progress of graphene-CuO and metal oxide-CuO composites prepared by MWHS process in recent years.Ying Li Yu-Ling Lu Kai-Di Wu Dong-Zhi Zhang Marc Debliquy Chao Zhang 2021Rare Metals2021,40,6:3
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