| 1 | Geological and geochemical characteristics of the Baogudi Carlintype gold district(Southwest Guizhou, China) and their geological implications显示文摘The newly discovered Baogudi gold district is located in the southwestern Guizhou Province,China,where there are numerous Carlin-type gold deposits.To better understand the geological and geochemical characteristics of the Baogudi gold district,we carried out petrographic observations,elemental analyses,and fluid inclusion and isotopic composition studies.We also compared the results with those of typical Carlin-type gold deposits in southwestern Guizhou.Three mineralization stages,namely,the sedimentation diagenesis,hydrothermal(main-ore and late-ore substages),and supergene stages,were identified based on field and petrographic observations.The main-ore and late-ore stages correspond to Au and Sb mineralization,respectively,which are similar to typical Carlin-type mineralization.The mass transfer associated with alteration and mineralization shows that a significant amount of Au,As,Sb,Hg,Tl,Mo,and S were added to mineralized rocks during the main-ore stage.Remarkably,arsenic,Sb,and S were added to the mineralized rocks during the late-ore stage.Element migration indicates that the sulfidation process was responsible for ore formation.Four types of fluid inclusions were identified in ore-related quartz and fluorite.The main-ore stage fluids are characterized by an H2O–NaCl–CO2–CH4±N2system,with medium to low temperatures(180–260℃)and low salinity(0–9.08%NaCl equivalent).The late-ore stage fluids featured H2O–NaCl±CO2±CH4,with low temperature(120–200℃)and low salinity(0–7.48%Na Cl equivalent).The temperature,salinity,and CO2and CH4concentrations of ore-forming fluids decreased from the main-ore stage to the late-ore stage.The calculated δ^13C,d D,and δ^18O values of the ore-forming fluids range from-14.3 to-7.0%,-76 to-55.7%,and 4.5–15.0%,respectively.Late-ore-stage stibnite had δ^34S values ranging from-0.6 to 1.9%.These stable isotopic compositions indicate that the ore-forming fluids originated mainly from deep magmatic hydrothermal fluids,with minor contributions from strata.Collectively,the Baogudi metallogenic district has geological and geochemical characteristics that are typical of Carlin-type gold deposits in southwest Guizhou.It is likely that the Baogudi gold district,together with other Carlin-type gold deposits in southwestern Guizhou,was formed in response to a single widespread metallogenic event. | Songtao Li Yong Xia Jianzhong Liu Zhuojun Xie Qinping Tan Yimeng Zhao Minghua Meng Lijin Tan Rong Nie Zepeng Wang Guanghong Zhou Haiyan Guo | 2019 | Acta Geochimica2019，38，4： | 1 |
| 2 | 滇东南洒西钨铍矿床成矿流体来源和演化:来自流体包裹体和H-O同位素证据显示文摘洒西钨铍矿床位于滇东南老君山钨锡多金属成矿区。确定早期似层状矿体和晚期脉状矿体的流体性质、来源和演化过程,并对其流体地球化学和同位素进行约束,可以有效探讨洒西钨铍矿床成矿机制,为老君山矿集区下一步找矿工作提供理论思考。洒西钨铍矿床脉状矿体的形成经历了硅酸盐阶段、氧化物-硫化物阶段和碳酸盐-萤石阶段,白钨矿和绿柱石主要形成于前两阶段。对洒西钨铍矿床脉状矿体不同阶段石英中的流体包裹体进行了岩相学特征、显微测温、激光拉曼光谱分析等研究,并对早期似层状矿体和晚期脉状矿体矿石中石英的氢-氧同位素组成进行了测试。结果表明:该矿床内脉状矿体的流体包裹体主要有富液相包裹体、富气相包裹体和含子矿物多相包裹体3种类型。流体包裹体的气相成分以H_(2)O主,含少量还原性气体如C_(2)H_(2)等,液相成分也以H_(2)O为主。从硅酸盐阶段到碳酸盐-萤石阶段,包裹体的均一温度和盐度(NaCl_(eq))峰值范围分别为240~360℃、2.35%~13.81%;220~310℃、4.03%~9.86%和190~270℃、2.41%~6.88%。从硅酸盐阶段到碳酸盐-萤石阶段,成矿流体的温度呈现降低趋势,盐度也呈降低趋势。成矿流体总体上属中-高温度、低盐度、贫CO_(2)、含部分还原性气体的NaCl-H_(2)O流体体系。早期似层状矿体石英样品δD_(V-SMOW)值变化范围小,为-102.8‰~-99.0‰,δ^(18)O_(V-SMOW)值为11.7‰~13.0‰,δ^(18)OH_(2)O值为3.16‰~6.46‰;晚期脉状矿体氧化物-硫化物阶段石英样品δD_(V-SMOW)值变化范围较大,为-99.6‰~-69.5‰,δ^(18)O_(V-SMOW)值为11.2‰~14.1‰,δ^(18)OH_(2)O值为3.08‰~6.73‰。综合表明成矿流体主要是岩浆水,混合有少量大气降水或有机水,流体可能发生了沸腾作用,加之温度的降低,导致晚期脉状矿体氧化物-硫化物阶段主要成矿物质的沉淀。洒西钨铍矿床属于中高温热液矿床。 | 盛夏 张达 阙朝阳 毕珉峰 狄永军 祖世元 马慧慧 | 2023 | 地质科技通报2023，42，1： | 0 |
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