|
|
|
题名
|
作者
|
年代
|
出处
|
被引量
|
| 1 | Efficient C_(2) Hydrocarbons and CO_(2) Adsorption and Separation in a Multi-site Functionalized MOF显示文摘A multi-site functionalized microporous metal-organic framework(MOF),H[Zn2(BDP)0.5(ATZ)3]·0.5 H_(2)O·0.5DMF(1),was synthesized through mixed ligands strategy.The pore surface of complex 1 was modified by uncoordinated carboxylate O atoms,phenyl and pyridyl rings as well as-NH_(2) groups,which strengthen interactions with C2H6,C_(2)H_(4) and CO_(2) molecules and lead to efficiently selective C2H6,C_(2)H_(4) and CO_(2) uptake over CH_(4).The selective adsorption mechanism was discussed deeply based on Grand Canonical Monte Carlo(GCMC)simulations.It is expected that this study will provide a new perspective for the rational design and synthesis of MOFs with efficient gas adsorption and separation performance. | 李高鹏 李贞贞 谢红芳 付云龙 王尧宇 | 2021 | Chinese Journal of Structural Chemistry2021，40，8： | 6 |
| 2 | Two new pseudo-isomeric nickel(Ⅱ)metal-organic frameworks with efficient electrocatalytic activity toward methanol oxidation显示文摘Searching for non-noble metal catalysts with high activities and low price is critical to the commercialization of methanol oxidation in the process of fuel cells.Herein,two new pseudo-isomeric Ni metal-organic frameworks(Ni-MOFs)(CTGU-17/CTGU-18)have been prepared with 1,4-naphthalenedi-carboxylate(H_(2)NDC),4,4’-dipyridyl amine(DPA)and Ni(ClO_(4))_(2)under hydrothermal condition.Each phase contains one water molecule,but differs dramatically in its bonding to the framework,resulting in different topological networks with fourfold interpenetrating 4-connected dia net(CTGU-17)and(3,7)-connected net(CTGU-18)and diverse electrocatalytic performance for methanol oxidation reaction(MOR).Remarkably,by combining each MOF with the conductive additive,acetylene black(AB),a composite material,AB&CTGU-18(2:4)was confirmed to have an excellent performance for MOR with a high mass specific peak current of 442.3 mA·mg^(-1).The enhanced electrocatalytic activities and robustness might be attributed to the synergetic effect of acetylene black and the active metal centers of MOFs particles for methanol oxidation.The present work would provide a new insight for the rational design of MOFs-based composites with enhanced methanol oxidation reaction performance. | Shan Liu Xiao Wang Hong-Guang Yu Ya-Pan Wu Bo Li Ya-Qian Lan Tao Wu Jian Zhang Dong-Sheng Li | 2021 | Rare Metals2021，40，2： | 4 |
| 3 | 准MIL-53(Fe)光催化剂的合成及其可见光催化降解有机染料性能的提高显示文摘以MIL-53(Fe)(以下简称MFe)为原料,通过热解制备了具有多孔结构的准金属-有机骨架(MOFs)MFe-T(T℃代表煅烧温度)光催化剂。在测试的催化剂中,MFe-250表现出最高的光降解性能,在90 min内降解99%亚甲基蓝(MB)。从光电流和电化学阻抗谱的结果来看,MFe-250的电子传输能力超过了MFe。此外,捕获实验表明,在光催化降解MB过程中,羟基自由基(·OH)是必不可少的中间体。此外,还提出了光催化过程的机理。 | 邹启超 马岩 池殿军 乔红斌 张珺影 陈倩 孙玉蝶 张建 张奎 刘胜军 | 2021 | 无机化学学报2021，37，12： | 3 |
| 4 | FeVO4/Cu3(BTC)2(H2O)3异质结制备及光催化性能显示文摘以Cu片和1,3,5-苯三甲酸为原料,电化学法制备经典Cu-MOF材料Cu3(BTC)2(H2O)3,即HKUST-1,作为基底金属有机框架材料(MOFs),采用室温沉积法制备FeVO4/HKUST-1异质结复合材料,通过XRD、SEM、BET、UV-Vis DRS等对其晶体结构、形貌、比表面积、光吸收性能等进行了表征。结果表明:FeVO4与HKUST-1复合形成异质结后,有利于光生电子-空穴的产生和转移,对目标染料污染物罗丹明B(RhB)的降解性能显著增强。可见光照射120 min后,异质结体系中RhB的降解率可达93%,而单一FeVO4或HKUST-1体系中仅为12%和5%。此外,对材料的组成比例进行了优化,当FeVO4与HKUST-1摩尔比为1∶1时,制备的FeVO4/HKUST-1复合材料具有最佳的光催化性能。进一步,考察了其循环使用的稳定性,循环5次后对RhB的降解效率仍保持在90%以上,稳定性良好。 | 刘颖琪 翁文斌 岑檠 肖维 王齐 丛燕青 张轶 | 2020 | 复合材料学报2020，37，12： | 3 |
| 5 | 高分散Ag/C_(3)N_(4)的制备及对硝基苯酚催化还原性能的研究显示文摘金属纳米颗粒的聚集现象严重影响了催化效率,利用简单的方法制备高分散的金属基催化剂具有一定的挑战性;首先利用柔喷雾技术在液液界面上制备了3种银配位的超分子前驱体膜,即三聚氰胺/三聚氰酸/硝酸银超分子(MC-Ag)、三聚氰胺/巴比妥酸/硝酸银超分子(MB-Ag)和三聚氰胺/三聚氰酸/巴比妥酸/硝酸银超分子(MCB-Ag);再热缩聚得到高分散的MC-Ag/C_(3)N_(4)、MB-Ag/NC和MCB-Ag/NC这3种银负载材料。在对硝基苯酚的催化还原实验中,MC-Ag/C_(3)N_(4)、MB-Ag/NC和MCB-Ag/NC表观速率常数(k_(app))分别为192.5×10^(-3)、126.8×10^(-3)和128.8×10^(-3)min^(-1);MC-Ag/C_(3)N_(4)展现出了优良的催化性能,在20 min内催化效率高达99.8%,经过5次循环后催化效果仍保持在97%以上,催化性能主要是MC-Ag/C_(3)N_(4)具有g-C_(3)N_(4)二维结构使银纳米粒子更加分散,更有利于接触更多的活性位点;同时柔喷雾技术为纳米颗粒的制备和形貌的调控提供了新的思路。 | 陈兵兵 解鹤 康建 马钰 薛亮 付昱 | 2024 | 化学试剂2024，46，2： | 0 |
| 6 | Synthesis,Structures,Luminescence and Catalytic Activity in the Knoevenagel Condensation Reaction of Two Cd(Ⅱ)Coordination Polymers Based on a Biphenyl-dicarboxylic Acid显示文摘Two cadmium(II)coordination polymers,namely[Cd(μ-dda)(H2 biim)]n(1)and[Cd(μ4-dda)(py)]n(2)have been constructed hydrothermally using H2 dda(H2 dda=4,4?-dihydroxybiphenyl-3,3?-dicarboxylic acid),H_(2)biim(H_(2)biim=2,2?-biimidazole),py(py=pyridine),and cadmium chloride at 160°C.The products were isolated as stable crystalline solids and were characterized by IR spectra,elemental analyses,thermogravimetric analyses(TGA),and single-crystal X-ray diffraction analyses.Single-crystal X-ray diffraction analyses revealed that both compounds crystallize in the monoclinic system,space group C2/c.Compound 1 discloses a 1 D chain structure.Compound 2 features a 3 D framework.The luminescent properties of compounds 1 and 2 were evaluated.Besides,the catalytic activities in the Knoevenagel condensation reaction of two compounds were investigated.Compound 1 exhibits an excellent catalytic activity in the Knoevenagel condensation reaction at room temperature. | 吴疆 顾金忠 | 2022 | Chinese Journal of Structural Chemistry2022，41，2： | 0 |
| 7 | Two Co(Ⅱ)-based Coordination Polymers Constructed fromπ-electron-rich Polycarboxylate Aryl Ether Ligand:Structural Insights and Photocatalytic Dye Degradation显示文摘In the present study,two new Co(Ⅱ)-based coordination polymers(CPs)with chemical formulas of{[Co_(3)(μ_(3)-OH)(L)(H_(2)O)_(3)]·2H_(2)O}n(1)and{[Co_(3)(μ_(3)-OH)(L)(H_(2)O)]·2DMF·3H_(2)O}n(2)have been successfully prepared by the reaction of Co(NO_(3))_(2)·6H_(2)O withπ-electron-rich polycarboxylate aryl ether ligand 5,5’-((5-carboxy-1,3-phenylene)bis(oxy))diisophthalic acid(H5L)under different solvothermal reaction conditions.Both CPs have been studied via single-crystal X-day diffraction,powder X-ray diffraction(PXRD)and thermogravimetric analysis(TGA).The photophysical studies indicated that complex 2 with good water stability is a potential semiconductive material,which could be applied for the degradation of methylene blue(MB)under UV light irradiation and exhibit good stability and recyclability. | 王笑峰 郭欣雨 刘涛 | 2021 | Chinese Journal of Structural Chemistry2021，40，6： | 0 |
您所在的机构暂未开通此部分的功能，请联系管理员