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1Construction of multiple interfaces and dielectric/magnetic heterostructures in electromagnetic wave absorbers with enhanced absorption performance:A review显示文摘The construction of structures with multiple interfaces and dielectric/magnetic heterostructures enables the design of materials with unique physical and chemical properties,which has aroused intensive interest in scientific and technological fields.Especially,for electromagnetic(EM)wave absorption,enhanced interface polarization and improved impedence match with high Snoek's limitation could be achieved by multiple interfaces and dielectric/magnetic heterostructures,respectively,which are benificial to high-efficiency electromagnetic wave absorption(EWA).However,by far,the principles in the design or construction of structures with multiple interfaces and dielectric/magnetic heterostructures,and the relationships between those structures or heterostructures and their EWA performance have not been fully summarized and reviewed.This article aims to provide a timely review on the research progresses of high-efficency EM wave absorbers with multiple interfaces and dielectric/magnetic heterostructures,focusing on various promising EWA materials.Particularly,EM attenuation mechanisms in those structures with multiple interfaces and dielectric/magnetic heterostructures are discussed and generalized.Furthermore,the changllenges and future developments of EM wave absorbers based on those structures are proposed.Junye Cheng Huibin Zhang Yingfei Xiong Lingfeng Gao Bo Wen Hassan Raza Hao Wang Guangping Zheng Deqing Zhang Han Zhang 2021Journal of Materiomics2021,7,6:7
2Atomic-Scale Layer-by-Layer Deposition of Fe SiAl@ZnO@Al_(2)O_(3) Hybrid with Threshold Anti-Corrosion and Ultra-High Microwave Absorption Properties in Low-Frequency Bands显示文摘Developing highly efficient magnetic microwave absorb-ers(MAs)is crucial,and yet challenging for anti-corrosion properties in extremely humid and salt-induced foggy environments.Herein,a dual-oxide shell of ZnO/Al_(2)O_(3) as a robust barrier to FeSiAl core is introduced to mitigate corrosion resistance.The FeSiAl@ZnO@Al_(2)O_(3) layer by layer hybrid structure is realized with atomic-scale precision through the atomic layer deposition technique.Owing to the unique hybrid structure,the FeSiAl@ZnO@Al_(2)O_(3) exhibits record-high micro-wave absorbing performance in low-frequency bands covering L and S bands with a minimum reflection loss(RLmin)of-50.6 dB at 3.4 GHz.Compared with pure FeSiAl(RLmin of-13.5 dB,a bandwidth of 0.5 GHz),the RLmin value and effective bandwidth of this designed novel absorber increased up to~3.7 and~3 times,respectively.Fur-thermore,the inert ceramic dual-shells have improved 9.0 times the anti-corrosion property of FeSiAl core by multistage barriers towards corrosive medium and obstruction of the electric circuit.This is attributed to the large charge transfer resistance,increased impedance modulus|Z|0.01 Hz,and frequency time constant of FeSiAl@ZnO@Al_(2)O_(3).The research demonstrates a promising platform toward the design of next-generation MAs with improved anti-corrosion properties.Wei Tian Jinyao Li Yifan Liu Rashad Ali Yang Guo Longjiang Deng Nasir Mahmood Xian Jian 2021Nano-Micro Letters2021,13,10:6
3Advances in core–shell engineering of carbon-based composites for electromagnetic wave absorption显示文摘Electromagnetic(EM)absorption is paving the way to overcome the challenges related to conventional shielding strategy against EM pollution through sustainable energy dissipation.As characteristic functional media that can interact with electric or magnetic field branch,EM wave absorption materials(EWAMs)have received extensive attention and realized considerable development in the past two decades,where carbon-based composites are always considered as promising candidates for high-performance EMAWs due to their synergetic loss mechanism as well as diversified composition and microstructure design.Recent progress indicates that there is more and more interest in the fabrication of carbon-based composites with unique core–shell configuration.On one hand,core–shell configuration usually ensures good chemical homogeneity of final products and provides some positive protections for the components with susceptibility to corrosion,on the other hand,it creates enough heterogeneous interfaces between different EM components,which may bring enhanced polarization effect and intensify the consumption of EM energy.In this review,we firstly introduce EM wave absorption theory,and then highlight the advances of core–shell engineering in carbonbased composites in terms of built-in carbon cores and built-out carbon shells.Moreover,we also show some special core–shell carbon-based composites,including carbon/carbon composites,assembled composites,and decorated composites.After analyzing EM absorption performance of some representative composites,we further propose some challenges and perspectives on the development of core–shell carbon-based composites.Lixue Gai Honghong Zhao Fengyuan Wang Pan Wang Yonglei Liu Xijiang Han Yunchen Du 2022Nano Research2022,15,10:5
4Recent Advances in Design Strategies and Multifunctionality of Flexible Electromagnetic Interference Shielding Materials显示文摘With rapid development of 5G communication technologies,electromagnetic interference(EMI)shielding for electronic devices has become an urgent demand in recent years,where the development of corresponding EMI shielding materials against detrimental electromagnetic radiation plays an essential role.Meanwhile,the EMI shielding materials with high flexibility and functional integrity are highly demanded for emerging shielding applications.Hitherto,a variety of flexible EMI shielding materials with lightweight and multifunctionalities have been developed.In this review,we not only introduce the recent development of flexible EMI shielding materials,but also elaborate the EMI shielding mechanisms and the index for'green EMI shielding'performance.In addition,the construction strategies for sophisticated multifunctionalities of flexible shielding materials are summarized.Finally,we propose several possible research directions for flexible EMI shielding materials in near future,which could be inspirational to the fast-growing next-generation flexible electronic devices with reliable and multipurpose protections as offered by EMI shielding materials.Junye Cheng Chuanbing Li Yingfei Xiong Huibin Zhang Hassan Raza Sana Ullah Jinyi Wu Guangping Zheng Qi Cao Deqing Zhang Qingbin Zheng Renchao Che 2022Nano-Micro Letters2022,14,5:5
5原子层沉积法制备TiO2/碳复合纳米管负载的Pt基催化剂显示文摘以碳纳米管为模板,使用原子层沉积技术在碳纳米管表面依次沉积氧化钛薄膜和Pt纳米粒子,制备了氧化钛纳米管负载的Pt基催化剂,采用TEM,XRD,XPS,ICP-AES等分析手段对制备的Pt基催化剂进行表征,考察了Pt基催化剂的对硝基苯酚加氢反应活性。实验结果表明,原子层沉积技术可制备高效的TiO2载体负载的Pt基催化剂,由于Pt与载体TiO2之间存在相互作用,负载在氧化钛纳米管外壁的Pt基催化剂,相比于单纯负载在碳纳米管外壁的Pt催化剂,对硝基苯酚加氢反应活性得到较大提升。王眉花 李岩 高新丽 刘翠荣 刘夏瑜 2020石油化工2020,49,9:3
6钴/碳纤维复合材料的制备及其吸波性能显示文摘为解决碳纤维基吸波材料制备方法繁杂、能耗高的问题,以棉纤维为原料,Co^(2+)为金属源,2-甲基咪唑为配体,经配位自组装获得棉纤维表面均匀负载的ZIF-67,复合材料经惰性气氛下高温煅烧得到钴/碳纤维复合材料。结果表明:随煅烧温度升高,钴纳米粒子结晶度更高,材料的矫顽力和饱和磁化强度增强,铁磁特性明显;煅烧温度有助于碳组分由无定形碳向微晶石墨转变,碳组分石墨化程度升高;800℃时钴/碳纤维复合材料的吸波性能最佳,厚度为2 mm时,有效吸收带宽可达5.44 GHz(9.36~14.80 GHz),复合材料优异的吸波性能归因于适宜的阻抗匹配和介电损耗与磁损耗的协同增强,相互搭载的纤维结构为电磁波构筑了适宜的衰减空间,并在碳纤维导电网络中快速衰减,研究将为新型碳纤维基吸波材料的设计开发提供借鉴。强荣 冯帅博 马茜 陈博文 陈熠 2022纺织学报2022,43,2:2
7静电纺丝技术在电磁材料设计和制备中的应用显示文摘电磁波吸收材料能将入射的电磁波能量转换为其他形式的能量而极少被反射回去,是吸收和衰减入射电磁波的重要功能材料。人们在优化电磁波吸收材料结构方面进行了深入探索,在众多结构中,一维结构因其独特的各向异性和表面效应而受到广泛关注。静电纺丝是一种特殊的纤维制造工艺,聚合物溶液或熔体在强电场中进行喷射纺丝,可以生产出纳米级直径的聚合物细丝,具有可纺材料种类多、纺丝成本低、工艺参数可控性好等优点,已成为制备连续一维纳米纤维的重要方法之一。从制备方法的角度,包括电纺纤维的直接煅烧、电纺纤维的高温碳化以及与其他合成工艺相结合等方法,分类介绍了静电纺丝技术在制备高性能电磁波吸收材料中的研究进展,以期为未来设计高效吸波材料提供理论指导。刘悦 陈庆昌 刘久荣 孟凡军 张大舜 吴莉莉 2023科技与创新2023,,10:1
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