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1过渡金属氧化物在光电化学传感器中的应用研究进展显示文摘近年来,光电化学传感器的研究已经成为人们关注的热点。光敏材料作为光电化学传感器的关键部分,其性能对传感器的灵敏度、选择性和稳定性等特征起着决定性的作用。该文简要介绍了光电化学传感器的原理和光电材料的分类,阐述了在光电化学传感器中常见过渡金属氧化物及其复合物的光电材料的制备方法与应用,对光电化学传感器及光电化学材料的发展前景进行了展望(引用文献67篇)。杨萍 钟立 魏小平 李建平 2020理化检验(化学分册)2020,56,1:3
2含Co配合物的ZnO纳米棒复合材料光电化学性质显示文摘在氧化铟锡(Indium Tin Oxide,ITO)玻璃上制备ZnO纳米棒,并采用一种简单的自组装方法在含有ZnO纳米棒的ITO玻璃上制备Co(2. 6-NDC)(4,4'-Bipy)0. 5配合物。实验表明,含Co配合物并没有和ZnO纳米棒发生反应,而是比较均匀地沉积在ZnO纳米棒上。在光电化学实验中,做了仅有ZnO和含Co配合物的ZnO纳米棒的线性伏安法测试对比实验,证明含Co配合物起到了良好的催化能力。说明这种简单的自组装方法制备的金属氧化物半导体和MOFs组成的复合材料在光电化学中具有潜在的应用价值。齐悦 杨洁 2018实验室研究与探索2018,37,10:2
3One-step synthesis of Cu(Ⅱ) metal–organic gel as recyclable material for rapid, efficient and size selective cationic dyes adsorption显示文摘Efficient removal of non-biodegradable and hazardous dyes from wastewater remains a hot research topic.Herein,a rationally designed a Cu(Ⅱ)-based metal–organic gel(Cu-MOG)with a nanoporous 3 D network structure prepared via a simple one-step mixing method was successfully employed for the removal of cationic dyes.The Cu-MOG exhibited high efficiency,with an adsorption capacity of up to 650.32 mg/g,and rapid adsorption efficiency,with the ability to adsorb 80%of Neutral Red within 1 min.The high adsorption efficiency was attributed to its large specific surface area,which enabled it to massively bind cationic dyes through electrostatic interaction,and a nanoporous structure that promoted intra-pore diffusion.Remarkably,the Cu-MOG displayed size-selective adsorption,based on adsorption studies concerning dyes of different sizes as calculated by density functional theory.Additionally,the adsorption performance of the Cu-MOG still maintained removal efficiency of 100%after three regeneration cycles.These results suggested that the Cu-MOG could be expected to be a promising and competitive candidate to conveniently process wastewater.Qing Wu Li He Zhong Wei Jiang Yang Li Ting Ting Zhao Yu Han Li Cheng Zhi Huang Yuan Fang Li 2019Journal of Environmental Sciences2019,31,12:1
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