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1湘东北仁里-传梓源矿床5号伟晶岩岩相学、地球化学特征及成矿时代显示文摘湘东北幕阜山地区由东北向西南,稀有金属矿化种类由单一至复杂,成矿规模逐渐增大,显示出明显的空间规律性。本文选取幕阜山地区西南部岩浆分异演化程度最高、矿化种类最复杂的仁里-传梓源稀有金属矿床,开展典型伟晶岩脉矿物学、地球化学及云母Ar-Ar年代学研究,旨于揭示Be-Nb-Ta-Li-Cs伟晶岩地球化学特征,探讨其与花岗岩围岩成因关系,并限定矿床稀有金属成矿时代。仁里-传梓源矿床5号伟晶岩脉表现出相对富碱(Na2O+K2O=5.11%~14.02%,平均9.4%)、过铝质(A/CNK=1.04~2.26,平均为1.4)的特征,微量、稀土元素含量极低,总体上富集Ta、Nb、Hf、Zr等高场强元素(HFSE),相对亏损Ba、Sr等离子亲石元素(LILE),不相容元素Rb、Cs、Nb、Ta、Zr、Hf等的强烈富集表明岩浆分异演化程度极高。矿物学及地球化学特征显示,仁里-传梓源矿床5号伟晶岩脉由边部至核部分异演化程度逐渐升高,但其化学指数与花岗岩围岩相比表现出较明显的突变关系。结合野外接触关系、年代学等证据,推断围岩二云母花岗岩并非稀有金属伟晶岩母岩。仁里-传梓源矿床显示出稀有金属岩浆-热液两阶段成矿的特征,伟晶岩中锂云母Ar-Ar坪年龄为125.0±1.4 Ma,代表了岩浆分异演化晚阶段,近热液体系中稀有金属聚集成矿的时代。李鹏 刘翔 李建康 黄志飚 周芳春 张立平 2019地质学报2019,93,6:41
2幕阜山地区新元古代花岗岩地球化学特征及成因探讨显示文摘位于湘鄂赣三省交界、江南造山带中段的幕阜山地区是我国重要的稀有金属矿集区,其南部的新元古代三墩花岗岩体为中细粒弱片麻状二云母斜长花岗岩。全岩地球化学分析显示,三墩花岗岩具有高钠、铝等特点,A/CNK=1. 15~1. 39,A/NK=1. 39~1. 69,为过铝质花岗岩;∑REE在(70. 45~84. 36)×10^(-6),LaN/YbN在10. 82~11. 23,轻稀土元素中度富集,Eu弱亏损(δEu=0. 99~0. 77);富集大离子亲石元素,Nb亏损。综合分析,该岩体为I型花岗岩,形成于大陆火山弧构造背景,推测为江南造山带形成过程中格林威尔造山运动板块碰撞形成,为聚合板块边缘俯冲带岩浆作用的产物。黄志飚 李鹏 周芳春 刘翔 李建康 肖国强 张立平 陈虎 汪宣民 2018桂林理工大学学报2018,38,4:22
3幕阜山南缘似斑状黑云母花岗岩锆石U-Pb年龄、Hf同位素组成及其地质意义显示文摘幕阜山复式花岗岩基南缘的长庆黑云母花岗岩与其内部Be伟晶岩呈渐变接触关系,为Be伟晶岩的母岩,其成岩时代及同位素特征可指示幕阜山地区黑云母花岗岩阶段的Be成矿时代及成矿物质来源。本次研究对长庆地区的似斑状黑云母二长花岗岩进行了LA-ICP-MS锆石U-Pb定年和Hf同位素组成测试,结果显示,该岩体成岩年龄为(142.9±0.9)Ma,代表了幕阜山复式花岗岩体黑云母花岗岩演化阶段的稀有金属成矿时代,此次成矿为华南地区中生代大规模成岩成矿作用的组成部分;继承锆石核的存在表明区域可能存在古老基底。长庆地区似斑状黑云母二长花岗岩的εHf(t)值主要变化于-9.2^-5.5,二阶段模式年龄主要为1.6~1.8 Ga,与幕阜山岩体不同类型花岗岩的εHf(t)和Hf同位素TDM2相近,暗示它们的源岩具有相似源区特征,为同源岩浆不同演化阶段的产物。此外,长庆似斑状黑云母二长花岗岩的源区物质中还有少量古元古代壳源物质(εHf(t)=-16)和新元古代地层物质加入,反映源区物质的复杂性。结合区域内其他年代学与同位素研究资料,表明幕阜山地区伟晶岩稀有金属成矿作用发生于早白垩世,岩浆连续分异演化过程中伴随着多阶段稀有金属成矿作用,最早在黑云母花岗岩阶段开始出现Be矿化,之后随着岩浆的分异演化程度不断增高,矿化规模越来越大,矿种由单一元素(Be)向综合演化(Be-Nb-Ta-Li)。成矿物质来源方面,幕阜山岩体锆石的TDM2与冷家溪群的锆石Hf同位素二阶段模式年龄的一个峰值(1.7~2.0 Ga)接近,表明二者的源岩在此时同时脱离地幔形成,为幕阜山岩体形成于冷家溪群部分熔融提供了支持,冷家溪群可能为稀有金属成矿提供了主要的物质来源。许畅 李建康 施光海 李鹏 刘翔 张立平 2019矿床地质2019,38,5:19
4湘东北仁里-传梓源铌钽矿床隐伏花岗岩锆石U-Pb年龄、Hf同位素特征及其地质意义显示文摘幕阜山复式花岗岩基位于扬子板块与华夏板块交接处的江南隆起带中段,是我国重要的稀有金属矿集区。仁里‒传梓源超大型铌钽矿床位于幕阜山复式花岗岩基南缘的冷家溪群片岩中,是我国少有的高品位花岗伟晶岩型铌钽矿床,其下盘隐伏花岗岩为粗中粒似斑状黑云母二长花岗岩。全岩地球化学分析结果显示,隐伏岩体属过铝质高钾钙碱性岩系列,明显富集轻稀土元素(LREE),相对亏损高场强元素(如Nb、Ti)。锆石LA-ICP-MS U-Pb定年结果表明,该隐伏岩体形成于晚侏罗世(146.2±0.2 Ma)。岩石的εHf(t)值和二阶段模式年龄tDM2分别为−10.8~−5.3和1884~1537 Ma。结果表明,仁里‒传梓源铌钽矿床隐伏花岗岩原岩源于中元古代地壳的熔融,并受到一定程度下地壳物质的影响。结合区域地质背景,该岩体形成于陆内挤压造山阶段结束后,挤压环境向伸展环境转变的大地构造背景,深部物质的加入也为仁里‒传梓源铌钽矿床提供了成矿物质来源。李鹏 周芳春 李建康 刘翔 黄志飚 张立平 2020大地构造与成矿学2020,44,3:18
5夹皮沟片麻杂岩对吉林南部地区太古宙地壳演化的制约——来自岩相学、地球化学、锆石U-Pb年代学方面的证据显示文摘吉林南部地区是华北克拉通北缘重要的太古宇出露区。为探讨华北克拉通新太古代构造-岩浆热事件的性质及早前寒武地壳的形成与演化,选择吉林南部夹皮沟TTG片麻杂岩进行研究。研究表明这套岩石高Al(Al2O3=14.97%~16.28%),富Na(Na2O=3.73%~4.54%)、低Mg(MgO=1.96%~2.56%)且平均镁指数为43;富集LREE,亏损HREE,Eu异常并不明显;富集Sr(358×10^(-6)~1114×10^(-6))、Ba(613×10^(-6)~1200×10^(-6))等大离子亲石元素,亏损Nb(6.39×10^(-6)~11.2×10^(-6))、Ta(0.384×10^(-6)~0.679×10^(-6))等高场强元素;Yb(1.17×10^(-6)~1.89×10^(-6))和Y(9.93×10^(-6)~19.3×10^(-6))含量也很低,Sr/Y比值很高(36.0~57.7),以上地球化学特征表明其残留相主要为石榴子石、角闪石和含Ti矿物,没有斜长石,属于高压型TTG岩类。LA-ICPMS锆石U-Pb结果表明其形成于~2509Ma,属于新太古代晚期的产物。结合以往TTG片麻岩类的地球化学研究及Nd模式年龄,这期岩浆事件可能代表古老地壳(~2.8Ga)的重熔。岩相学和锆石形态学研究表明研究区经历了多期变质作用,其中~2509Ma的高级变质事件与岩浆事件几乎同时,可能与地幔柱环境下的岩浆底侵作用有关。宋健 刘志宏 王超 高翔 孙理难 2018地质学报2018,92,5:3
6Geochemical and Petrological Studies on the Early Carboniferous Sidingheishan Mafic-Ultramafic Iintrusion in the Southern Margin of the Central Asian Orogenic Belt,NW China显示文摘The Sidingheishan mafic-ultramafic intrusion is located in the eastern part of the Northern Tianshan Mountain, along the southern margin of the Central Asian Orogenic Belt in northern Xinjiang autonomous region of China. The Sidingheishan intrusion is mainly composed of wehrlite, olivine websterite, olivine gabbro, gabbro and hornblende gabbro. At least two pulses of magma were involved in the formation of the intrusion. The first pulse of magma produced an olivine-free unit and the second pulse produced an olivine-bearing unit. The magmas intruded the Devonian granites and granodiorites.An age of 351.4±5.8 Ma(Early Carboniferous) for the Sidingheishan intrusion has been determined by U-Pb SHRIMP analysis of zircon grains separated from the olivine gabbro unit. A U-Pb age of 359.2±6.4 Ma from the gabbro unit has been obtained by LA-ICP-MS. Olivine of the Sidingheishan intrusion reaches 82.52 mole% Fo and 1414 ppm Ni. On the basis of olivine-liquid equilibria, it has been calculated that the MgO and FeO included in the parental magma of a wehrlite sample were approximately10.43 wt% and 13.14 wt%, respectively. The Sidingheishan intrusive rocks are characterized by moderate enrichments in Th and Sm, slight enrichments in light REE, and depletions in Nb, Ta, Zr and Hf. The ε_(Nd)(t) values in the rock units vary from +6.70 to +9.64, and initial ^(87)Sr/^(86)Sr ratios range between 0.7035 and0.7042. Initial ^(206)Pb/^(204)Pb, ^(207)Pb/^(204)Pb and ^(208)Pb/^(204)Pb values fall in the ranges of 17.23-17.91,15.45-15.54 and 37.54-38.09 respectively. These characteristics are collectively similar to the Heishan intrusion and the Early Carboniferous subduction related volcanic rocks in the Santanghu Basin, North Tianshan and Beishan area. The low(La/Gd)_(PM) values between 0.26 and 1.77 indicate that the magma of the Sidingheishan intrusion was most likely derived from a depleted spinel-peridotite mantle.(Th/Nb)_(PM)ratios from 0.59 to 20.25 indicate contamination of the parental magma in the upper crust.Crystallization modeling methods suggest that the parental magma of the Sidingheishan intrusion was generated by flush melting of the asthenosphere and subsequently there was about 10 vol%contamination from a granitic melt. This was followed by about 5 vol% assimilation of upper crustal rocks. Thus, the high-Mg basaltic parental magma of Sidingheishan intrusion is interpreted to have formed from partial melting of the asthenosphere during the break-off of a subducted slab.SUN Tao QIAN Zhuangzhi THAKURTA Joyashish YANG Shenghong XU Gang DUAN Jun GAO Bo WANG Jing 2018Acta Geologica Sinica(English Edition)2018,92,3:3
7Timing of Anatexis within the Berere HTHP Complex Belt of Maevatanana Area,North-Central Madgascar,and its Geological Significance显示文摘The Berere HTHP Complex belt in Maevatanana area of north–central Madagascar formed in the^2.5 Ga orogeny and underwent high temperature(up to 1050℃)and high pressure(up to 11.5 kbar)granulite facies metamorphism.Then a widespread anatexis took place and numerous widely distributed felsic leucosomes formed.The majority of these leucosomes are parallel to the schistosity of the complex or are present as stockworks,as thin layers,or as lenses at different scales in the host rocks.Here,we report new petrographic data,zircon LA-ICP-MS U-Pb ages,and Lu–Hf isotopic data for felsic leucosomes within this complex.Anatexis,as identified by the petrological study of felsic leucosomes in the field and in thin sections,involved initial ternary feldspar exsolving to produce antiperthite and a quartz+plagioclase±K-feldspar+sericite mineral assemblage around feldspar grain boundaries.Dissolution is apparent along muscovite grain boundaries,and residual sericite is present around the margins of feldspar and quartz,all suggesting that anatexis was driven by reactions involving muscovite.Zircon U–Pb dating indicates that the felsic leucosomes within the complex formed at 2467–2369 Ma.The majority of samples have positiveεHf(t)values,although a few have negative values,suggesting their formation from magmas predominantly sourced from the depleted mantle,possibly with the involvement of minor amounts of crustal materials.Two-stage Hf model ages andεHf(t)values for these samples are consistent with those for gneisses of the basement,indicating that the felsic leucosomes were formed by the anatexis of gneisses and both of their protolith formed during the formation of continental crust in Meso-Neoarchean(ca.3.1–2.7 Ga).As such,the crystallization age of the felsic leucosome(~2.4 Ga)represents the timing of regional anatexis and a change to post-orogenic tectonism.And this anatexis is also corresponds to the thermal event in Dharwar craton in India which has a pronounced similar Precambrian geology with Madagascar,providing an important constraints on the correlation of the two continental fragments.LI Peng LIU Shanbao LI Jiankang SHI Guanghai LIU Xiang 2020Acta Geologica Sinica(English Edition)2020,94,5:0
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