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| 1 | Continental versus oceanic subduction zones显示文摘Subduction zones are tectonic expressions of convergent plate margins,where crustal rocks descend into and interact with the overlying mantle wedge.hey are the geodynamic system that produces maic arc volcanics above oceanic subduction zones but high-to ultrahigh-pressure metamorphic rocks in continental subduction zones.While the metamorphic rocks provide petrological records of orogenic processes when descending crustal rocks undergo dehydration and anataxis at forearc to subarc depths beneath the mantle wedge,the arc volcanics provide geochemical records of the mass transfer from the subducting slab to the mantle wedge in this period though the mantle wedge becomes partially melted at a later time.Whereas the mantle wedge overlying the subducting oceanic slab is of asthenospheric origin,that overlying the descending continental slab is of lithospheric origin,being ancient beneath cratons but juvenile beneath marginal arcs.In either case,the mantle wedge base is cooled down during the slab–wedge coupled subduction.Metamorphic dehydration is prominent during subduction of crustal rocks,giving rise to aqueous solutions that are enriched in luid-mobile incompatible elements.Once the subducting slab is decoupled from the mantle wedge,the slab–mantle interface is heated by lateral incursion of the asthenospheric mantle to allow dehydration melting of rocks in the descending slab surface and the metasomatized mantle wedge base,respectively.herefore,the tectonic regime of subduction zones changes in both time and space with respect to their structures,inputs,processes and products.Ophiolites record the tectonic conversion from sealoor spreading to oceanic subduction beneath continental margin,whereas ultrahigh-temperature metamorphic events mark the tectonic conversion from compression to extension in orogens. | Yong-Fei Zheng Yi-Xiang Chen | 2016 | National Science Review2016，3，4： | 57 |
| 2 | Fe-Mg同位素在蛇绿岩中铬铁矿床成因研究中的应用潜力显示文摘蛇绿岩中铬铁矿床成因一直存在较大争议,其主要原因可归结为:寄主蛇绿岩存在成因争议、产出状态不清、矿石及围岩矿物组合单一以及主要矿物成分简单但矿物包裹体复杂多样.针对这些研究瓶颈,率先对西藏普兰和罗布莎、土耳其Kizildag和Kop蛇绿岩中的地幔橄榄岩和铬铁岩进行了全岩和单矿物Fe-Mg同位素的探索性研究工作.结果表明:(1)蛇绿岩中的地幔橄榄岩具有较均一的Fe-Mg同位素组成,与世界上其他地区的地幔橄榄岩相似;(2)铬铁岩中铬铁矿和橄榄石之间存在明显的Fe-Mg同位素分馏,铬铁矿多具有比共存橄榄石轻的Fe同位素组成,与地幔橄榄岩中的尖晶石和橄榄石相反,Mg同位素变化较大;(3)铬铁矿和橄榄石的Fe-Mg同位素主要受控于结晶分异和Fe-Mg交换,且这两个过程造成的同位素变化趋势明显不同.因此,Fe-Mg同位素在揭示铬铁矿母岩浆来源、性质及成矿过程方面具有较大的应用潜力. | 苏本勋 肖燕 陈晨 白洋 刘霞 梁子 彭青山 | 2018 | 地球科学2018，43，4： | 10 |
| 3 | 绿帘石记录俯冲带变质流体活动显示文摘俯冲带是连接地球表生圈层和深部圈层的关键纽带,深刻影响着地球内部的运行方式和人类宜居环境。俯冲板片脱水释放的高压-超高压变质流体控制着俯冲带诸多重要地质过程,如地幔楔交代和部分熔融、岛弧岩浆活动、中/深源地震以及地球内部的元素迁移和分异等等。深入了解这些流体的源区、运移、成分和物理化学条件是理解这些流体性质和行为的前提和关键。绿帘石是俯冲带变质岩中一个常见的含水造岩矿物,具有较宽广的稳定温压范围(绿片岩相-榴辉岩相)、较高的微量元素含量和缓慢的体扩散行为(如Sr、Pb、Th、U、Cr、V和LREE),能够指示俯冲带(多期)变质流体活动和地球化学效应。本文总结了近年来俯冲带变质绿帘石研究的主要进展及其在揭示俯冲带流体活动方面的重要应用,包括探究俯冲带流体的起源、成分特征、运移方式、氧逸度条件、交代效应和多期次结晶行为。这些研究表明绿帘石是一个极好的变质流体活动记录器,能够为理解俯冲带流体活动和深部元素迁移提供关键信息。 | 唐盼 郭顺 | 2019 | 岩石学报2019，35，7： | 8 |
| 4 | Subduction-zone peridotites and their records of crust-mantle interaction显示文摘Subduction is the core process of plate tectonics. The mantle wedge in subduction-zone systems represents a key tectonic unit, playing a significant role in material cycling and energy exchange between Earth's layers. This study summarizes research progresses in terms of subduction-related peridotite massifs, including supra-subduction zone(SSZ) ophiolites and mantle-wedge-type(MWT) orogenic peridotites. We also provide the relevant key scientific questions that need be solved in the future. The mantle sections of SSZ ophiolites and MWT orogenic peridotites represent the mantle fragments from oceanic and continental lithosphere in subduction zones, respectively. They are essential targets to study the crust-mantle interaction in subduction zones. The nature of this interaction is the complex chemical exchanges between the subducting slab and the mantle wedge under the major control of physical processes. The SSZ ophiolites can record melt/fluid-rock interaction, metamorphism,deformation, concentration of metallogenic elements and material exchange between crust and mantle, during the stages from the generation of oceanic lithosphere at spreading centers to the initiation, development, maturation and ending of oceanic subduction at continental margins. The MWT orogenic peridotites reveal the history of strong metamorphism and deformation during subduction, the multiple melt/fluid metasomatism(including silicatic melts, carbonatitic melts and silicate-bearing C-HO fluids/supercritical fluids), and the complex cycling of crust-mantle materials, during the subduction/collision and exhumation of continental plates. In order to further reveal the crust-mantle interaction using subduction-zone peridotites, it is necessary to utilize high-spatial-resolution and high-precision techniques to constrain the complex chemical metasomatism, metamorphism,deformation at micro scales, and to reveal their connections with spatial-temporal evolution in macro-scale tectonics. | Jianping ZHENG Qing XIONG Yi ZHAO Wenbo LI | 2019 | Science China Earth Sciences2019，62，7： | 8 |
| 5 | 金红石-榍石转变过程中元素地球化学行为——以雅鲁藏布江缝合带角闪岩为例显示文摘金红石边缘形成榍石冠状边结构在变质中-基性岩中普遍存在,是金红石与退变质流体携带的SiO_2与CaO作用的结果,反应形成的榍石微量元素特征受到金红石和流体的共同影响。雅鲁藏布江缝合带中角闪岩LZ06-04在抬升过程经历近等温降压退变质作用,石榴子石分解导致同一样品中含石榴子石部分与不含石榴子石部分的退变质流体成分的差异。两种流体分别与金红石反应,对应形成的榍石具有相似的Nb、Ta含量和Nb/Ta比值特征,但截然不同的REE特征。榍石的Nb、Ta来源于金红石,残余金红石与含水流体再平衡Nb、Ta的分配系数增大,且D_(Nb)^(Rt/Fluid)≥D_(Ta)^(Rt/Fluid);虽然Nb和Ta在含水流体中都表现为不活动元素,但相对于Nb,Ta在含水流体中活动性较高。榍石的Zr-Hf体系特征受到锆石、石榴子石等矿物的综合影响,并且Zr-Hf在含水流体中表现出比Nb-Ta更高的活动性。榍石的REE特征受流体中REE特征、榍石与流体配分系数以及共生矿物的影响。在岩浆或变质体系,榍石形成过程中,REE富集矿物(如石榴子石、锆石、褐帘石、独居石、磷灰石等)形成或分解将影响榍石的REE分布特征或形成REE环带结构。含水流体中金红石退变质形成榍石反应的进行受流体中TiO_2、CaO和SiO_2活度的影响。因此榍石常见于钙碱性岩浆岩、富Ca基性变质岩和矽卡岩中。流体中CaO活度的变化影响榍石的形成,进而影响Ti、Nb、Ta在流体中的运移能力。俯冲板片产生流体在交代上覆富Ca地幔楔物质过程中形成榍石残留同样可以造成部分熔融体具有亏损HFSE特征。 | 赵令浩 曾令森 胡明月 孙冬阳 | 2017 | 岩石学报2017，33，8： | 5 |
| 6 | Li同位素在矿床学中的应用:现状与展望显示文摘矿床的形成受制于多种复杂的地质作用,包括全球尺度的板块构造运动、岩浆活动、变质沉积改造等过程,并普遍伴随热液活动、流体迁移、水-岩相互作用、元素分异及同位素分馏等一系列局部区域地质和地球化学过程.在过去的矿床学研究中,地球化学方法主要围绕在主、微量元素和传统的稳定同位素等手段,解决了很多矿床成因问题.但仍存在不少的多解和难解问题,比如许多矿床在矿化类型、蚀变分带与金属矿物组合方面具有诸多相似之处,常规地球化学指标难以区分.随着测试精度的提高和自然储库组成的完善,Li同位素近些年来已成为新兴的稳定同位素体系.Li同位素在自然界过程中高达80‰的同位素分馏使其具有更好的辨识能力,同时兼有直接和间接指示作用,有潜力成为研究各种复杂成矿过程的良好示踪剂.本文总结了近年来有关矿床学中Li同位素的研究和应用进展,以俯冲带成矿为主,阐述了斑岩型-热液矿床、伟晶岩型矿床和沉积矿床等类型矿床的Li同位素地球化学特征,并探究新的Li同位素方法在矿床中的应用前景.基于Li同位素体系在各类矿床的应用实例,我们认为Li同位素体系将为矿床学研究提供更多的指示信息和依据. | 陆一敢 肖益林 王洋洋 万红琼 李东永 仝凤台 余成龙 | 2021 | 地球科学2021，46，12： | 4 |
| 7 | 镁同位素地球化学研究新进展及其在碳酸岩研究中的应用显示文摘镁(Mg)同位素有3个,^(24)Mg、^(25)Mg和^(26)Mg,其中^(24)Mg和^(26)Mg的相对质量差较大,高达8.33%,这种大的相对质量差使地壳活动或其他地质过程中Mg同位素因化学物理条件的变化而发生明显的同位素质量分馏.目前,自然界可观测到的δ^(26)Mg变化范围为-5.60‰~0.92‰,约6.5‰.镁在低温地球化学过程中分馏显著,而在高温环境下分馏不明显,因而Mg同位素是地质过程的潜在地球化学指标和示踪剂,在低温风化作用、高温部分熔融与岩浆结晶分异、变质作用、板片俯冲及壳幔物质循环、热液蚀变和矿床成因等方面取得重要进展.为此,简要介绍了镁同位素分析方法,系统总结了Mg同位素在地球各储库中的组成与分布特征以及地质作用过程中的镁同位素分馏机理;其次重点介绍了镁同位素近年来在碳酸岩研究中的应用;最后对有关问题进行了探讨,包括幔源岩石低δ26Mg成因解释(与俯冲再循环的碳酸盐岩、洋壳物质有关或与矿物分离结晶有关)和Li-Mg-Ca同位素联合示踪岩浆碳酸岩岩石成因.并对碰撞反应池多接收器电感耦合等离子体质谱仪(Nu Sapphire MC-ICP-MS)分析优势和Li-Mg-Ca等金属同位素联合示踪在稀土元素富集机制的应用进行了展望. | 陈洁 龚迎莉 陈露 向蜜 田世洪 | 2021 | 地球科学2021，46，12： | 3 |
| 8 | 中国变质岩研究近十年新进展显示文摘变质岩是组成硅酸盐地球的三大岩石之一,对了解深部地壳的组成和地壳演化、研究地壳热结构历史记录、恢复变质岩原岩建造和指导找矿都具有重要意义。本文综述了近十年来我国变质岩学科在超高压/高温变质作用、相平衡、变质流体以及变质岩地球化学等几方面的研究进展。在已有研究基础上,近十年来我国学者又相继在柴北缘野马滩、南阿尔金、东昆仑、北秦岭及西南天山的不同类型岩石中发现了柯石英、斯石英假象(副象)以及其他一些特征的超高压变质指示矿物和结构,确定了这些超高压变质带的野外分布特征。在超高温变质作用研究方面,识别并确定了华北克拉通孔兹岩带超高温变质岩石的出露规模,准确的变质时代和时间尺度的限定以及P-T-t轨迹的构建,尤其是在进变质阶段的确定方面取得了一系列进展。在变质相平衡研究方面,在热力学数据库和矿物相及熔体活度模型进一步完善的基础上,开发了新的模拟计算软件GeoPS,建立了基于ACF组分分析的变质基性岩完整相平衡关系;同时在深熔作用与花岗质岩石成因的定量模拟方面也有重要进展。在矿物温压计研究方面,首次建立了与斜长石无关的GBAQ压力计、二云母压力计和白云母Ti温度计。在元素地球化学方面,高场强元素(如Ti、Nb、Ta、Zr、Hf等)和卤族元素(如F、Cl、Br和I)在变质脱水过程中的迁移和分异,以及变价元素(如V、Fe、W和Mo等)对指示氧逸度的变化研究方面都取得了一系列进展。在变质流体研究方面,对俯冲带高压-超高压流体活动的证据、流体成分的确定及流体活动时限等方面的研究也取得了明显进展。 | 张贵宾 刘良 魏春景 肖益林 焦淑娟 吕增 张立飞 | 2021 | 矿物岩石地球化学通报2021，40，6： | 2 |
| 9 | The partitioning behavior of trace elements in subduction zones:Advances and prospects显示文摘The partitioning behavior of trace elements is of key importance for understanding the geochemical process and material cycle mechanism in subduction zones.This paper focuses on the advances and prospects on the studies of trace element partitioning in subduction zones from the following four aspects.(1)The properties of fluids derived from subducting slabs and their ability in element transport.How slab-derived solute-rich fluids and supercritical fluids are formed and what the roles and key control factors of these fluids are in transferring of elements(especially the high field strength elements)from slab to wedge are discussed.We point out that the detailed investigations of supercritical fluids may provide a new perspective for the element migration mechanism,material cycle process,arc magma genesis and so on.(2)The behavior of transition elements during mantle wedge melting.The behavior of the first row transition elements(Sc,Ti,V,Cr,Mn,Fe,Co,Ni,Cu,Zn)in the mantle partial melting process is compatible or incompatible,depending on residual mineral assemblage and physicochemical conditions.The partitioning behavior of the elements such as Sc,Ti,Co,Ni and Zn whose valence states do not change in the melting process mainly depends on the residual mineral assemblage and temperature,whereas the partitioning behavior of the multivalent elements such as V and Fe is also the function of oxygen fugacity(fO_(2))in addition to mineral assemblage and temperature.Therefore,the partitioning behavior of transition elements has important applications in tracing lithologic inhomogeneity and fO_(2)of the mantle wedges.(3)The specificity of element partitioning behavior during arc magma evolution.Garnet has Dy/Yb partitioning behavior different from amphibole,and rutile has Nb/Ta partitioning behavior different from amphibole.Dy/Yb and Nb/Ta partitioning differences for these minerals enable to distinguish the specific evolution process of arc magmas.The Dy/Yb and Nb/Ta generally decrease with the increase of SiO_(2)in arc magmas,indicating that amphibole fractionation should be the most important during arc magma differentiation.(4)The behavior of sulfur and chalcophile elements and porphyry metallogeny.In subduction zones,the behavior of chalcophile elements such as Cu and Au is controlled by sulfide and fluid.Therefore,the stability of sulfide,the time at which the fluid exsolves from the melt relative to sulfide saturation,the fluid/sulfide mass ratio and fluid/melt Cu and Au partition coefficients in intermediate-felsic magma-H_(2)O systems are especially important in understanding Cu and Au enrichment in magma-hydrothermal processes.Intermediate-felsic magmas mainly originate from the differentiation of arc magmas at lower crustal reservoirs,and thus the fluid exsolution from the lower crustal reservoirs and the fluid/melt and fluid/sulfide partition coefficients of Cu and Au should be the keys to understanding quantitatively how Cu and Au are migrated from the deep crust to the shallow site of mineralization. | Xiaolin Xiong Xingcheng Liu Li Li Jintuan Wang Wei Chen Mengfei Ruan Ting Xu Zhongxing Sun Fangfang Huang Jianping Li&Lei Zhang | 2020 | Science China Earth Sciences2020，63，12： | 2 |
| 10 | 勘察加岛弧岩浆岩研究进展显示文摘西太平洋分布了全球大部分的洋内俯冲带,也是全球沟-弧-盆体系最发育的地区。勘察加(Kamchatka)半岛位于俄罗斯远东地区,地处太平洋西北部(51°~60°N、155°~164°E),是全球环太平洋岛弧的重要组成部分。前人对勘察加岛弧岩石地幔源区性质、熔融过程、岩浆结晶分异及熔/流体交代过程进行了详细的研究,并获得了丰硕的成果。最新的研究进展表明:(1)勘察加岛弧前缘火山和中部火山的源区主要为亏损地幔,而弧后区域则存在较为富集的地幔贡献;(2)勘察加岛弧不同区域的地幔源区流体性质具有一定的差异,导致从前缘火山至中部火山,地幔熔融程度逐渐降低;(3)勘察加岛弧不同区域岩石地球化学成分存在差异,而且,沿穿弧剖面某些元素或同位素(如δ11 B)表现出系统变化的特征,反应了俯冲板片流体通量和流体性质的差异;(4)勘察加半岛部分多期次火山(如Klyuchevskoy火山)地球化学成分复杂,可能反应了源区熔融条件的不同和岩浆结晶分异过程;(5)勘察加岛弧北部与阿留申岛弧近直角相交,导致异常的构造背景,促使该区域形成了具有埃达克质特征的岛弧岩浆。 | 刘海洋 薛颖瑜 孙卫东 | 2020 | 岩石学报2020，36，2： | 0 |
| 11 | Trace Element Mobility in Subducted Marble and Associated Eclogite:Constraints from UHP Rocks in the Shuanghe Area,Central-East China显示文摘In order to decipher element mobility in UHP meta-sedimentary rocks in the continental subduction zone,major and trace element compositions are investigated for a continuous profile from a representative UHP region in the Dabie Mountains.Among the lithologic contact zone,contents of K,Ca,LREE,and LILE exhibit varying degrees of downward trends in both marble and eclogite toward the contact zone,indicating that marble and their associated eclogite can release a large amount of K,Ca,and a small number of LILEs and LREEs.Titanite is the main Ti phase in both marble and eclogite.Titanite rims around rutile can occasionally be seen in eclogite.Contents of Ti and HFSE exhibit a well-coupled relation among marble and eclogite,indicating that substantial Ti and HFSEs were migrated from eclogite to marble,in accord with the capacity of a melt medium.Rutiles and titanites in marble exhibit a relatively limited variation in Nb/Ta ratios(12.9-16.2),similar to those of titanites in eclogite(14.2-16.7),which demonstrates that rutiles and titanites in marble were sourced from eclogite because of short-distance migrations of Ti and HFSEs.According to the P-T path and the temperature and pressure conditions of the peak metamorphism reported by previous studies,the eclogite associated with marble may not form supercritical fluids in the subduction zone because of the addition of carbonate minerals. | Xingao Hou Zhiqiang Yu Shefa Chen Lei Liu Yilin Xiao | 2024 | Journal of Earth Science2024，35，1： | 0 |
| 12 | 华北地幔橄榄岩锂同位素研究进展显示文摘作为非传统稳定同位素的代表,Li同位素已被广泛应用于示踪与熔体和流体相关的地质过程。地幔橄榄岩高度不均一的Li含量和Li同位素组成特征是熔/流体与地幔橄榄岩相互作用过程中同位素分馏作用及温度下降过程中Li在矿物之间扩散分馏的结果,同位素扩散现象通常被矿物颗粒边部的组成特征所记录。由于Li在橄榄石中的扩散速度比在辉石中慢,所以大颗粒橄榄石核部的Li含量和同位素组成更能反映岩石圈地幔的组成,而辉石的组成特征更多地记录了后期的过程。大量地幔捕虏体的锂同位素组成特征研究表明,华北克拉通岩石圈地幔经历了蚀变洋壳在俯冲过程中、残留俯冲板片在深部地幔、以及上涌的软流圈所释放的不同组成的熔/流体的改造过程。由于改造作用的多阶段性和改造程度的不同,华北克拉通东部与中部地幔橄榄岩的组成特征具有系统性的差异。Li同位素与其他地球化学指标的联合示踪是未来地幔地球化学研究的发展趋势。 | 汤艳杰 英基丰 | 2022 | 岩石学报2022，38，12： | 0 |
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