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| 1 | 塔里木盆地塔深1井超深层白云岩储层成因新认识:来自原位碳氧同位素分析的证据显示文摘塔里木盆地超深层钻井塔深1井揭示在埋深8 408 m条件下依然具有优质白云岩储层,但储集空间的成因机制存在较大争议。在详细的岩心描述、显微岩石学观察与孔洞胶结物充填序列分析基础上,对阴极发光分析后的加厚薄片,通过原位微区取样方法分别获取基质、早期白云石胶结物和晚期白云石胶结物样品并进行碳氧同位素分析。早期白云石胶结物与白云岩基质具有相对一致的碳氧同位素分布特征,而晚期白云石胶结物δ13C值和δ18O值偏负。胶结物充填序列与碳氧同位素分析结果表明,不同类型白云石是多阶段白云石化作用的产物,即孔洞在白云石化作用发生的时候已经形成并随着埋深增加不断消亡。中寒武统阿瓦塔格组深灰色孔洞型白云岩储集空间的形成可能与准同生期近地表成岩事件有关。 | 曹自成 尤东华 漆立新 云露 胡文瑄 李宗杰 钱一雄 刘永立 | 2020 | 天然气地球科学2020，31，7： | 8 |
| 2 | 中国沉积学发展战略:沉积地球化学研究现状与展望显示文摘沉积地球化学是沉积学的重要研究内容和手段,在认识地球表层系统圈层相互作用和资源环境效应方面发挥着不可替代作用。随着国家科研经费投入的增加,以及地球化学分析测试的平台建设和技术进步,中国沉积地球化学进入快速发展期,在国际上的学术影响力逐渐增强,但是在技术方法与理论的创新、及高质量成果产出等方面,仍有待改进。因此,中国沉积地球化学应加强统筹规划和布局,在战术上重视理论、方法和技术的发展与创新,提升沉积—成岩过程年代的约束能力,重视对地球化学数据的精细提取和模型定量分析;在战略上加强沉积地球化学在大时空尺度的应用与探索,深化对关键地质时期地球环境—生物协同演化,以及沉积矿产和化石能源的形成与演化等重大科学问题的研究。在此基础上,中国沉积地球化学将进一步提升研究水平和国际地位,并有望实现跨越式发展。 | 周锡强 陈代钊 刘牧 胡建芳 | 2017 | 沉积学报2017，35，6： | 7 |
| 3 | 四川盆地南江栖霞组白云岩岩石学、地球化学特征及成因显示文摘四川盆地南江桥亭剖面中二叠统栖霞组二段灰岩局部白云岩化,基质白云岩主要由非平直晶面他形晶白云石构成,孔洞缝中充填鞍形白云石和结晶方解石,溶解作用主要发生在白云石中。在岩石学研究基础上,综合运用碳氧同位素、元素、包裹体均一化温度、阴极发光测试手段,结合埋藏史、热史以及峨眉山玄武岩喷发非正常地热增温事件,研究了基质白云石和鞍形白云石的特征和成因。研究表明:基质白云石、鞍形白云石和结晶方解石的包裹体均一化温度分别为100~110,130~230,130~230℃;富含基质白云石、鞍形白云石和结晶方解石样品的δ18OPDB值分别为-4.27‰^-6.28‰,-4.87‰^-5.80‰,-5.16‰^-6.50‰,δ13CPDB值分别为3.97‰~5.22‰,4.88‰~5.35‰,2.73‰~4.29‰;与基质白云岩相比较,鞍形白云石和结晶方解石的δ18O值略负,并显示三者碳源为同时期海水。反演的基质白云岩形成流体的δ18OSMOW值分布在3‰~6‰之间,鞍形白云石δ18OSMOW主要分布在7‰~14‰之间,盐度均显著高于同期海水,因而两者都是在高温和高盐度的流体中形成的。三者都受到了峨眉山玄武岩喷发活动所引起的热事件影响,高温和高盐度克服了白云石沉淀的动力学屏障,形成交代灰岩的基质白云岩和孔洞缝中充填的鞍形白云石,流体的持续高温和Mg2+的消耗,导致了高温方解石的沉淀,显示热液对碳酸盐岩的改造作用。 | 李小宁 黄思静 黄树光 黄可可 袁桃 罗文 | 2016 | 石油实验地质2016，38，2： | 6 |
| 4 | 塔里木盆地西缘上寒武统下丘里塔格群热液白云岩改造时限:来自古地磁的约束显示文摘成岩流体活动时间的确定一直都是学界难以解决的问题。上寒武统下丘里塔格群广泛发育有热液白云石,但热液改造的时间缺乏可靠约束。基于热液改造形成的广泛重磁化对热液改造时间进行约束,在巴楚永安坝和柯坪水泥厂下丘里塔格群中共采集43个热液白云石脉定向古柱状样品,并制样测试了64件古地磁样品,再对其中的29件样品进行了岩石磁学分析。大多数样品磁性在580℃时也没有被完全清洗掉,一部分在高外部磁场上才得到饱和等温剩磁,指示高矫顽力、高阻挡温度载磁矿物,推测为赤铁矿;另一部分样品在低外部磁场上迅速达到饱和,指示低矫顽力、高阻挡温度载磁矿物,推测为磁铁矿。许多样品的退磁数据较离散,但少数样品退磁曲线具有典型的双分量特征。柯坪水泥厂2号采样点和永安坝2号采样点的高温特征剩磁分量对应的古地磁极位置能与前人在同地区测的早二叠世与晚二叠世古磁极位置良好对应。考虑到所测样品均为热液白云石脉,这部分高温特征剩磁分量显然是热液活动引起化学重磁化的结果,说明热液白云岩改造与塔里木板块二叠纪强烈的岩浆活动有关系。 | 陈代钊 张艳秋 周锡强 董少锋 | 2020 | 石油与天然气地质2020，41，1： | 6 |
| 5 | Application of Stable Strontium Isotope Geochemistry and Fluid Inclusion Microthermometry to Studies of Dolomitization of the Deeply Buried Cambrian Carbonate Successions in West-Central Tarim Basin, NW China显示文摘Detailed petrographic,geochemical(O-C-Sr isotopes)and fluid inclusion studies of the deeply buried Cambrian carbonates in the West-central Tarim Basin revealed three types of crystalline dolomites(fine-crystalline,nonplanar-a(s),dolomite(RD1),fine-to medium-crystalline,planar-e(s)dolomite(RD2),and medium-to coarse-crystalline,nonplanar-a dolomite(RD3)),medium-to coarsecrystalline,nonplanar-a saddle dolomite cement(CD)and early and later-stage calcite cement.The occurrence of RD1 along low-amplitude stylolites points to link with pressure dissolution by which minor Mg ions were likely released for replacive dolomitization during early-to intermediate-burial seawater dolomitization.The increasing crystal sizes of RD2 and RD3 with irregular overgrowth rims suggests intense recrystallization and replacement upon the RD1 or remaining precursor limestones by dolomitizing fluids during late intermediate burial dolomitization.The overlap ofδ^(18)O,δ^(13)C and ^(87)Sr/^(86)Sr values of RD1-RD3 and CD dolomite with coeval seawater values,suggests that the principal dolomitizing fluids that precipitated these dolomites was connate(Cambrian)seawater preserved in the host limestones/dolomites.Their high ^(87)Sr/^(86)Sr ratios suggest influx of radiogenic strontium into the Cambrian seawater.Two regimes of fluid flow are recognized in the study area:firstly,influx of magnesium-rich higher-temperature basinal brines along deep-seated faults/fractures,resulting in cementation by CD dolomite.Secondly,the incursion of meteoric waters,mixing with ascending highertemperature basinal brines,and an increase in Ca^(2+)/Mg^(2+)ratio in the fluids probably results in the precipitation of calcite cement in vugs and fractures. | Ngong Roger Ngia Mingyi Hu Da Gao Zhonggui Hu Chun-Yan Sun | 2019 | Journal of Earth Science2019，30，1： | 5 |
| 6 | The origin of bedding-parallel fibrous calcite veins in the Lower Permian Chihsia Formation in western Hubei Province,South China显示文摘Bedding-parallel fibrous veins occurring as lenticular to flattened intercalations were found in the organic-rich marlstone/calcareous shale of the upper Lower Permian Chihsia Formation in western Hubei Province,South China. They dominantly consist of fibrous calcite crystals with smooth and tight boundaries, forming fencelike inward, syntaxial growth clusters toward the vein center along which a median suture line generally occurs.Petrographic evidence indicates that these veins may form at relatively shallow burial depth, where fluid overpressures would have incrementally created the bed-parallel vein space, resulting in displacive growth of fibrous calcite.On the other hand, the C, O and S isotopic data across the vein reveal slightly depleted d13Ccarbvalues(-3.32 % to +0.19 % VPDB) and moderately depleted d18Ocarbvalues(-9.6 % to-7.3 % VPDB) with respect to those of coeval seawaters and slightly heavier d34Spyritevalues(-7.88 % CDT) with respect to those of ambient rocks.Stable isotope evidence consistently suggests significant contribution of bacterial sulfate reduction(BSR) to the formation of the fibrous calcite cements in the vein. The BSR could have been intensive with the availabilities of residual sulfate and abundant organic matters in theChihsia sediments during shallow burial, increasing the alkalinity of pore waters and further promoting carbonate precipitation. Thus, the bedding-parallel fibrous calcite vein in the upper Lower Permian Chihsia Formation is an important time-specific petrographic capsule, providing clues for understanding the diagenetic process in organicrich sediments. | Hao Yu Xiqiang Zhou Jianguo Wang Chuan Guo Hengye Wei Daizhao Chen | 2015 | Science Bulletin2015，60，20： | 4 |
| 7 | Oxygen Isotope Clue to Migration of Dolomitizing Fluid as Exampled by the Changxing Formation Dolomite at Panlongdong, Northeastern Sichuan显示文摘The Upper Permian Changxing dolomite reservoirs serves as one of the most important gas and oil reservoirs in the NE Sichuan Basin. Determining the dolomitizing fluid's pathway is regarded as the key to solve the 'dolomite problem' and further petroleum exploration. Outcrop samples from Upper Permian Changhsingian Panlongdong Section were studied using oxygen isotopic analysis, cathodoluminescence(CL) and major element analysis, in an attempt to determine the migration path way and properties of the dolomitizing fluid. Of the Changxing dolomite, the δ18O values ranged from-3.494‰ to-5.481‰, which decreased from the top layer to the bottom in the section; the MgO contents varied from 9.24% to 21.43%, CaO contents from 28.65% to 39.87%, the CaO/MgO ratio from 1.40 to 4.31 and the Mn O contents from 0.004% to 0.009 8%. The Mg O contents showed a downwardly decreasing trend in the section, while the Ca O/Mg O showed an opposite rule. All of the dolomites looked dull or dark when they were exposed to the electron beam of the cathodoluminescence device. None of the fine-to medium grained dolomite showed a banded structure. Given that dolomitizing fluid's salinity decreased during the dolomitization process in its pathway, we concluded that the dolomitizing fluid migrated downwardly in Changxing Formation after excluding the possibility of deep burial or meteoric-marine mixing-water influences. As the dolomitizing fluid's pathway has always been difficult to be determined in highly dolomitized Formation, this study showed an important application of oxygen isotope values in resolving this problem. | Rui Zhao Yasheng Wu Hongxia Jiang Qingsong Liu 无 | 2017 | Journal of Earth Science2017，28，2： | 4 |
| 8 | Saddle-Dolomite-Bearing Fracture Fillings and Records of Hot Brine Activity in the Jialingjiang Formation,Libixia Section,Hechuan Area of Chongqing City显示文摘Most vein minerals deposited in fractures of the Jialingjiang Formation from Libixia section,Hechan area include a large amount of saddle dolomite and accompanying celestite,calcite and fluorite.This study analyzed the nature,source,evolution of the fluids by plane-light petrography,fluid-inclusion methods,cathodoluminescence images,and stable isotopic compositions.The homogenization temperatures of two-phase aqueous fluid inclusions in dolomite range between100 and 270℃.Combined with theδ^(18)O data,it is suggested that the fluid responsible for the precipitation of fracture fillings haveδ^(18)O values between 10‰and 18‰(relative to SMOW).The saddle dolomite and the accompanying minerals were the result of activity of dense brines at elevated temperatures.Moreover,analysis shows that the fluid was derived from a mixture of marine-derived brine and deeper circulating flow.This fluid was enriched in Sr during diagenesis and formed celestite in fracture and for regional mineralization.Dissolution of saddle dolomite was attributed to the cooling of Mg/Ca-decreased fluids,which may relate to a leaching of gypsum to celestite in surrounding carbonates. | HUANG Keke ZHONG Yijiang HUANG Sijing LI Xiaoning FENG Mingshi | 2016 | Acta Geologica Sinica(English Edition)2016，90，1： | 2 |
| 9 | 微区原位碳氧同位素分析技术对碳酸盐岩成岩流体性质的约束——以塔里木盆地寒武系—奥陶系为例显示文摘随着分析测试水平的提高,微区原位地球化学分析作为揭示复杂沉积—成岩过程的重要技术手段,越来越受到广泛重视。通过微区原位碳氧同位素分析,结合常规分样方法获取的碳氧同位素数据,对比讨论了同生期—埋藏期海水胶结作用、表生期大气淡水的溶蚀—充填作用与多阶段白云石化流体交代—胶结充填作用。结果显示,微区原位取样碳氧同位素分析有利于揭示胶结物形成过程的多期、多阶段的流体性质演化。常规分样获取的此类胶结物碳氧同位素值可能是多期次产物的混合值。对于相对单一的产物,如碳酸盐岩基质组分、大气淡水成因方解石等,常规分样进行碳氧同位素分析基本可以满足研究需要。微区原位取样碳氧同位素分析提供了一种相对“低成本、高精度”的分析手段,对精确示踪碳酸盐岩成岩演化过程具有重要意义。 | 韩俊 尤东华 钱一雄 董少峰 彭守涛 | 2023 | 石油实验地质2023，45，1： | 0 |
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