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1Conjugated radical cation dimerization-driven generation of supramolecular architectures显示文摘This paper summarizes the recent advance in utilizing conjugated radical cation dimerization(CRCD) for constructing new unimolecular, such as foldamers, and supramolecular ordered structures, such as three-dimensional supramolecular polymers and two-dimensional supramolecular organic framework.Particularly, the stacking or dimerization of tetrathiafulvalene and 4,4'-dipyridium subunits has been highlighted, and the approaches for enhancing the stability of their radical cation dimers have been discussed.Lan Chen Yun-Chang Zhang Wei-Kun Wang Jia Tian Liang Zhang Hui Wang Dan-Wei Zhang Zhan-Ting Li 2015Chinese Chemical Letters2015,26,7:6
2A cucurbit [8] uril recognized rigid supramolecular polymer with photo-stimulated responsiveness显示文摘A rigid supramolecular polymer was constructed in aqueous solution via cucurbit[8]uril(CB[8]) host recognition with a rigid monomer containing an azobenzene unit and two 4,4'-bipyridin-1-ium(BP)moieties in the two ends, which also exhibited photo-responsiveness owing to the photoinduced trans–cis isomerization of azobenzene group.Tian-Tian Cao Xu-Yang Yao Jing Zhang Qiao-Chun Wang Xiang Ma 2015Chinese Chemical Letters2015,26,7:5
3A novel synthesis of nitroform by the nitrolysis of cucurbituril显示文摘Cucurbituril has a high symmetry and rigid structure.When cucurbit[6]uril(CB[6]) was nitrolyzed with the mixed solution of acetic anhydride in fuming nitric acid,nitroform(NF) was generated.NF also can be obtained by the nitration of both CB[5,7,8].This nitration procedure provides a lower risk,inexpensive,new preparation of nitroform,and the reaction condition of this new method is very mild.Hong-Yan Lu Jia-Rong Li De-Li Yang Qi Zhang Da-Xin Shi 2015Chinese Chemical Letters2015,26,3:2
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