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1A Short Review on Copper Calcium Titanate(CCTO) Electroceramic;Synthesis,Dielectric Properties,Film Deposition,and Sensing Application显示文摘Electroceramic calcium copper titanates(CaCu3Ti4O12,CCTO),with high dielectric permittivities(e) of approximately 105 and 104,respectively,for single crystal and bulk materials,are produced for a number of wellestablished and emerging applications such as resonator,capacitor,and sensor.These applications take advantage of the unique properties achieved through the structure and properties of CCTO.This review comprehensively focuses on the primary processing routes,effect of impurity,dielectric permittivity,and deposition technique used for the processing of electroceramics along with their chemical composition and micro and nanostructures.Emphasis is given to versatile and basic approaches that allow one to control the microstructural features that ultimately determine the properties of the CCTO ceramic.Despite the intensive research in this area,none of the studies available in the literature provides all the possible relevant information about CCTO fabrication,structure,the factors influencing its dielectric properties,CCTO immobilization,and sensing applications.Mohsen Ahmadipour Mohd Fadzil Ain Zainal Arifin Ahmad 2016Nano-Micro Letters2016,8,4:1
2(Li_(0.5)Nb_(0.5))^(3+)共取代对MgAl_(2)O_(4)介电性能的影响显示文摘采用固相反应法制备了MgAl_(2-x)(Li_(0.5)Nb_(0.5))_(x)O_(4)介电陶瓷,分析了样品的晶体结构特征、物相组成以及介电性能。XRD精修结果显示,MgAl_(2)O_(4)和Mg_(5)Nb_(4)O_(15)形成了一个稳定的两相系统。在1550℃烧结时,致密度随着(Li_(0.5)Nb_(0.5))^(3+)的含量增大而减小。品质因数Q_(f)的变化趋势与致密度、填充分数以及共价度密切相关。另外,谐振频率温度系数τ_(f)主要受Al位键价影响。MgAl_(2-x)(Li_(0.5)Nb_(0.5))_(x)O_(4)陶瓷在1550℃烧结4 h后拥有最优介电性能:ε_(r)=8.21,Q_(f)=81600 GHz和τ_(f)=-94×10^(-6)℃^(-1)。殷俊 杨习志 赖元明 张芹 戚聪 李潇 苏桦 巫崇胜 蒋刚 2023Journal of Central South University2023,30,5:0
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