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| 1 | An experimental and modeling study of n-hexadecane autoignition under low-to-intermediate temperatures显示文摘N-hexadecane is a potential candidate of diesel surrogate fuels and is also the largest linear alkane(n-alkanes)with known chemical kinetic models.The objective of this study is to investigate the autoignition characteristics of n-hexadecane in the lowto-intermediate temperature region and to validate the existing kinetic models.In this study,the ignition delay times(IDTs)of nhexadecane were measured using a heated rapid compression machine(RCM)at two pressures of 7 and 10 bar,and over equivalence ratios ranging from 0.5 to 1.3.Two-stage ignition characteristic and the negative temperature coefficient(NTC)behavior of total ignition delay time were experimentally captured.This study paid special attention to the influence of pressure,equivalence ratio,and oxygen content on the IDTs of n-hexadecane.It is observed that both the total IDTs and the first-stage IDTs decrease with the rise of those parameters.It is worth noting that the first-stage IDT is found to show a greater dependence on temperature but a weaker dependence on other parameters compared to the total IDT.The observed IDT dependence in the lowtemperature region(LTR)were quantitatively described by ignition delay time correlations.The newly measured IDTs were then validated against two kinetic models(LLNL and CRECK).Simulation results show that both models underpredict the first-stage IDT but generally capture the temperature dependence.The CRECK model well predicts the total IDTs of n-hexadecane while the LLNL model significantly underpredicts the total IDTs at most investigated conditions.To the best of our knowledge,this study is the first investigation on n-hexadecane autoignition under low-to-intermediate temperatures,which deepens the understanding of large n-alkane oxidation and contributes to the improvement of the existing kinetic models. | YU Liang WANG WenYu WANG SiXu FENG Yuan QIAN Yong LU XingCai | 2020 | Science China(Technological Sciences)2020，63，5： | 2 |
| 2 | Applicability of high dimensional model representation correlations for ignition delay times of n-heptane/air mixtures显示文摘It is difficult to predict the ignition delay times for fuels with the two-stage ignition tendency because of the existence of the nonlinear negative temperature coefficient (NTC) phenomenon at low temperature regimes. In this paper, the random sampling-high dimen-sional model representation (RS-HDMR) methods were employed to predict the ignition delay times of n-heptane/ air mixtures, which exhibits the NTC phenomenon, over a range of initial conditions. A detailed n-heptane chemical mechanism was used to calculate the fuel ignition delay times in the adiabatic constant-pressure system, and two HDMR correlations, the global correlation and the stepwise correlations, were then constructed. Besides, the ignition delay times predicted by both types of correlations were validated against those calculated using the detailed chemical mechanism. The results showed that both correlations had a satisfactory prediction accuracy in general for the ignition delay times of the n-heptane/air mixtures and the stepwise correlations exhibited a better performance than the global correlation in each subdo-main. Therefore, it is concluded that HDMR correlations are capable of predicting the ignition delay times for fuels with two-stage ignition behaviors at low-to-intermediate temperature conditions. | Wang LIU Jiabo ZHANG Zhen HUANG Dong HAN | 2019 | Frontiers in Energy2019，13，2： | 2 |
| 3 | 基于快速压缩机的二甲醚燃烧特性研究显示文摘为了研究二甲醚(DME)的燃烧特性,在初始温度293 K、驱动压力0.6 MPa、初始压力0.04~0.08 MPa、氮气稀释率47.29%~60.81%、压缩比8.82~12.02的实验条件下,利用快速压缩机(RCM)研究了初始压力、氮气稀释率、压缩比对DME-O2-N2混合气着火延迟期和最高燃烧压力的影响。结果表明:DME-O2-N2混合气出现两阶段放热现象与两阶段着火延迟期;随着压缩比的增加,混合气的着火延迟期出现负温度系数(NTC)现象,随初始压力的升高,出现NTC现象的温度向高温方向发展;随氮气稀释率的增加,出现NTC现象的温度向低温方向发展;初始压力一定,不同压缩比下,随氮气稀释率的增加,混合气的最高燃烧压力和第2阶段着火延迟期呈相反的变化趋势;氮气稀释率一定,不同初始压力下,随压缩比的增加,混合气的最高燃烧压力和总着火延迟期呈相反的变化趋势。 | 石智成 刘昊 张红光 卢海涛 | 2015 | 兵工学报2015，36，7： | 1 |
| 4 | Effects of fuel combination and IVO timing on combustion and emissions of a dual-fuel HCCI combustion engine显示文摘This paper experimentally and numerically studied the effects of fuel combination and intake valve opening(IVO)timing on combustion and emissions of an n-heptane and gasoline dual-flicl homogeneous charge compression ignition(HCCI)engine.By changing the gasoline fraction(GF)from 0」to 0.5 and the IVO timing from-15°CA ATDC to 35°CA ATDC,the in-cylinder pressure traces,heat release behaviors,and HC and CO emissions were investigated.The results showed that both the increased GF and the retarded IVO timing delay the combustion phasing,lengthen the combustion duration,and decrease the peak heat release rate and the maximum average combustion temperature,whereas the IVO timing has a more obvious influence on combustion than GF.HC and CO emissions are decreased with reduced GF,advanced IVO timing and increased operational load. | Xin LIANG Jianyong ZHANG Zhongzhao LI Jiabo ZHANG Zhen HUANG Dong HAN | 2020 | Frontiers in Energy2020，14，4： | 1 |
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