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| 1 | 基于石墨烯基电极染料敏化太阳能电池的研究进展显示文摘对近几年石墨烯基电极染料敏化太阳能电池的研究成果进行了追踪,分析了多种改性石墨烯电极应用于染料敏化太阳能电池后能量转换效率变化的原因,深入研究了改善石墨烯对电解质的还原电催化反应活性物理机理,为解决该电池存在的问题理清了思路,对该方向未来的研究工作给出了建议,探索和制备新材料以进一步打破石墨烯的层间堆叠是提高该电池性能的关键。 | 谢世伟 肖啸 谭建军 刘愈 张志友 杜惊雷 高福华 | 2014 | 中国光学2014，7，1： | 15 |
| 2 | 不同方法制备的Pt对电极染料敏化太阳能电池的光电性能研究显示文摘采用磁控溅射(sputtering)、高温热分解(high-temp)H2Pt Cl6·6H2O溶液和低温化学还原(low-temp)H2Pt Cl6·6H2O溶液等方法在FTO导电基片上制备了三类不同的Pt对电极,通过改变磁控溅射时间或旋涂退火循环次数,对FTO上不同对电极的载Pt量进行了调节.分析了三种不同方法制备的对电极的晶相结构、表面形貌以及透光率等特性.基于纳米管阵列和不同条件制备的对电极组装了系列染料敏化太阳能电池.测量了正照射和背照射条件下的电池光电性能,并分析了制备方法对对电极微结构和形貌的影响,以及对组装电池光电性能的影响,并对其各自的适用性和优缺点进行了比较分析. | 李思倩 王刚 张军 王浩 | 2014 | 中国科学:技术科学2014，44，12： | 7 |
| 3 | Photoelectrochemical properties of MWCNT-TiO_2 hybrid materials as a counter electrode for dye-sensitized solar cells显示文摘The MWCNT-TiO_2 hybrid materials were prepared by a simply mixing method and used as a counter electrode(CE) for dye-sensitized solar cells.Compared with the platinum CE,MWCNT-TiO_2 CE has the similar redox voltage and current response in the cyclic voltammetry.The electrochemical catalytic activity was characterized by the electrochemical impedance spectroscopy and Tafel curve,including the equivalent circuit,the exchange current density,the limiting diffusion current density,and the diffusion coefficient of triiodide/iodide redox species.The results indicate that the reduction process from triiodide to iodide is determined by the kinetic-controlled and diffusion-limited processes.The device performance is optimal based on the MWCNT-TiO_2(mass ratio of 2:1) CE,such as the open-circuit voltage of 0.72 V,the short-circuit photocurrent density of 15.71 mA/cm^2,the fill factor of 0.68,and the photon-to-electron conversion efficiency of 7.69%. | Yu-Qiao Wang Xue-Ling Gao Bo Song Yun-Liang Gu Yue-Ming Sun | 2014 | Chinese Chemical Letters2014，25，4： | 4 |
| 4 | 一步法热分解制备染料敏化太阳能电池Pt对电极显示文摘用旋涂热分解前驱H2PtCl6·6H2O溶液制备Pt/FTO对电极,研究了旋涂退火次数对Pt/FTO对电极的载铂量、透光率和组装的染料敏化太阳能电池光电性能的影响。结果表明,用5次旋涂退火的对电极组装的电池具有最佳的能量转换效率(6.78%),高于用传统的磁控溅射对电极组装的电池。基于在最佳光电性能情况下对电极的旋涂次数和载Pt量,进一步优化H2PtCl6?6H2O前驱液的浓度和使用体积。采用一步滴涂退火处理,得到了具有高透光性、低载Pt量和高的组装电池效率的Pt/FTO对电极。用此一步法制备的Pt/FTO对电极,组装成的电池能量转换效率达到6.92%。 | 李思倩 黄杰 谢剑 张军 叶葱 王浩 | 2015 | 材料研究学报2015，29，9： | 2 |
| 5 | 硫化钴/碳纳米纤维膜对电极的制备与优化显示文摘用静电对喷的方法将电催化性能优异的硫化钴(CoS)纳米颗粒负载到纳米纤维膜上,然后经过碳化得到硫化钴/碳纳米纤维膜(CoS/CNFs)对电极,CoS虽然电催化性能优异,但其导电性不佳,为了进一步提高CoS/CNFs的导电性与电催化性能,引入导电性优良并具备一定电催化性能的纳米银(Ag)颗粒制备硫化钴-银/碳纳米纤维膜(CoS-Ag/CNFs)对电极,并研究了它们的力学性能、柔韧性、导电性及电催化性能。结果表明,与CoS/CNFs对电极相比,纳米银颗粒的引入导致CoS-Ag/CNFs的力学性能及柔韧性下降,但却提高了它的导电性与电催化性能。 | 周洋洋 宋立新 关迎利 熊杰 | 2018 | 现代纺织技术2018，26，3： | 1 |
| 6 | 一种高导电性透明金属有机骨架物薄膜(英文)显示文摘金属有机框架(MOFs)以其优良的特性和广泛的应用而备受关注.然而,当应用于透明导电薄膜器件时,其导电性差且透光率低.因此提高MOF基材料的导电性和透光性成为最棘手的难题.本文报道了一种将高导电性PEDOT:PSS引入透明金属有机骨架ZIF-8薄膜中并成功合成具有高导电性、高透光性的PEDOT:PSS@ZIF-8 (PPZ)金属有机骨架复合薄膜的有效方法.相对于近乎绝缘的纯ZIF-8薄膜,我们制备的PPZ薄膜的最高导电率高达16.37 S cm-1.加入PEDOT:PSS后, ZIF-8薄膜透光率降低,因此我们利用二甲亚砜对PPZ薄膜进一步改性.改性后的PPZ薄膜比原PPZ薄膜具有更高的导电性和更好的透光性,其最高导电率为57.03 S cm-1,是未改性PPZ薄膜的3.5倍. PPZ薄膜展现了其应用于透明导电器件的巨大潜力,并为制备具有高导电性和良好透光性的MOF基材料提供了新途径. | 李卓异 郭弈 应文 陈丹科 王小彬 马旭 赵星 邓正 彭新生 | 2019 | Science China Materials2019，62，9： | 1 |
| 7 | Electrodeposited transparent PEDOT for inverted perovskite solar cells:improved charge transport and catalytic performances显示文摘The acidic, corrosive effect of sodium polystyrene sulfonate(PSS) in poly 3,4-ethylenedioxythiophene:sodium polystyrene sulfonate(PEDOT:PSS) limits the stability of inverted perovskite solar cells(PSCs) based on the ITO/PEDOT:PSS/perovskite/PCBM/BCP/Ag structure. In this work, a poly 3,4-ethylenedioxythiophene(PEDOT) hole transport layer(HTL) with high hole mobility and good catalytic performance was prepared by electrochemical cyclic voltammetry(CV) method for inverted PSCs. By controlling the CV cycles(from 1 to 5 cycles) and EDOT monomer solution concentration(from0.5 to 2.0 mmol·L^(-1)) of electrochemical deposition, the thickness, morphology, optical and electrochemical properties of PEDOT could be accurately adjusted. The optimal photovoltaic performance with current density(J_(sc)) of 22.19 mA·cm^(-2), open circuit voltage(V_(oc)) of 0.94 V, fill factor(FF) of 0.65 and photoelectric conversion efficiency of 13.56% was obtained when deposition of PEDOT with 1 CV cycle and EDOT concentration of 0.5 mmol·L^(-1). At this point, the perovskite showed good crystallization,optimal optical, charge transport and recombination performance, resulting in better V_(oc)and photoelectric conversion efficiency(PCE) compared to the devices with higher CV cycle numbers and 3,4-ethylenedioxythiophene(EDOT) concentration. For comparison with spin-coated PEDOT:PSS, the device with electrodeposited PEDOT showed improved J_(sc)and comparable V_(oc), which may result from its better charge transport and catalytic ability.The device with spin-coated PEDOT:PSS showed photoelectric conversion efficiency of 12.25%, which was lower than that based on electrodeposited PEDOT(13.56%) with1 CV cycles and 0.5 mmol·L^(-1) EDOT concentration. And the device with electrodeposited PEDOT as HTLs showed more excellent air stability. In ambient air((32 ± 5) ℃ and RH: 70% ± 20%), it still maintained more than 80%of the initial photoelectric conversion efficiency after1000 h. In comparison, the photoelectric conversion efficiency of the device with PEDOT:PSS decreased to 20% of the initial value after storage for 500 h. From this study, a facial and low-cost way to prepare PEDOT HTL with high performances that better than the traditional PEDOT:PSS has been explored, which is expected to eliminate the acidic, corrosive effect of PSS in PEDOT:PSS. | Cong-Tan Zhu Ying Yang Fei-Yu Lin Yuan Luo Shu-Peng Ma Liu Zhu Xue-Yi Guo | 2021 | Rare Metals2021，40，9： | 1 |
| 8 | 柔性染料敏化太阳能电池的研究进展显示文摘柔性染料敏化太阳能电池(Dye-sensitized solar cell,DSSC)具有可弯曲、易加工、应用前景广阔等优点,引起了研究者的广泛关注。介绍了染料敏化太阳能电池的基本结构和工作原理,概述了柔性DSSC的研究进展,着重介绍了以聚合物、金属以及柔性玻璃等为基板的柔性光阳极,以及以金属铂和复合材料为柔性对电极的研究发展。最后对柔性DSSC未来的发展与应用进行了展望。 | 卢军 许晓玉 林琳 陈俊琛 何丹农 | 2015 | 材料导报(纳米与新材料专辑)2015，29，2： | 1 |
| 9 | Suppression of charge recombination by application of CueZnSnS4-graphene counter electrode to thin dye-sensitized solar cells显示文摘 | Yan Li Huafei Guo Xiuqin Wang Ningyi Yuan Jianning Ding | 2016 | Science Bulletin2016，61，15： | 1 |
| 10 | 磁控溅射法制备染料敏化太阳能电池Pt对电极显示文摘采用磁控溅射法,通过控制溅射时间在导电基底FTO上制备出了具有不同载Pt量的Pt/FTO对电极,分析了对电极的表面形貌、晶相结构、透过率等。同时,对不同光照模式下组装的染料敏化太阳能电池(dye sensitized solar cells,DSSCs)的光电性能进行了考察。实验表明,正照射模式下,溅射30 s制备的Pt/FTO对电极能获得优异的光电性能,其组装电池的最高能量转换效率达到8.3%,在正照射模式下具有很好的应用前景;由于所制备对电极透光性较差,背照射模式下组装电池的光电性能较低。 | 黄杰 石瑜 胡泊 张军 王浩 | 2015 | 广州化工2015，43，10： | 0 |
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