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1pH Dependent plasmon-driven surface-catalysis reactions of p,p'-dimercaptoazobenzene produced from para-aminothiophenol and 4-nitrobenzenethiol显示文摘In this paper,we studied the pH dependent plasmon-driven surface-catalysis(PDSC) reactions of p,p'-dimercaptoazobenzene(DMAB) produced from para-aminothiophenol(PATP) and 4-nitrobenzenethiol(4NBT) both theoretically and experimentally.The surface enhanced Raman spectrum(SERS) of DMAB produced from PATP and 4NBT on Ag films in solutions with various pH values has been measured.The simulation and experimental results indicated that the pH dependence of PATP appeared in acidic environment and came from the amino group NH2.Furthermore,the ratio of intensity of Raman peak caused by PATP and DMAB indicated that this acidic sensor had higher pH sensitivity when it was excited by photons of higher energy.HUANG YingZhou DONG Bin 2012Science China Chemistry2012,55,12:2
2Ferromagnetism in sp^(2) carbon显示文摘The bulk,pristine sp^(2) carbons,such as graphite,carbon nanotubes,and graphene,are usually assumed to be typical diamagnetic materials.However,over the past two decades,there have been many reports about the ferromagnetism in these sp^(2) carbon materials,which have attracted intense interest for basic research and potential applications.In this review,we focus on the evidence and developments of the emergent ferromagnetism in sp^(2) carbon revealed by nine kinds of experimental methods:magnetic force microscopy(MFM),magnetization measurements with physical property measurement system(PPMS),X-ray magnetic circular dichroism(XMCD),scanning tunneling microscopy(STM),miniaturized magnetic particle inspection(MPI),anomalous Hall effect(AHE),mechanical deflection of carbon nanotube cantilevers,magnetoresistance,and spin-related devices(spin field effect transistor and spin memory).The advantages,conclusions,challenges,and future of these methods are discussed.The ferromagnetism in sp^(2) carbon will open a door to explore exotic physical phenomena and lay the basis for the development of integrated circuit of spintronics,which is fundamentally different from charge-based conventional electronics.Wenxiang Wang Julienne Impundu Jiyou Jin Zhisheng Peng Hui Liu Zheng Wei Yushi Xu Yu Wang Jiawang You Weimin Fan Yong Jun Li Lianfeng Sun 2023Nano Research2023,16,12:0
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