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| 1 | Syntheses, Crystal Structures and in vitro Anticancer Activities of Dibenzyltin Compounds Based on the N-(2-Phenylacetic acid)-aroyl Hydrazone显示文摘Two dibenzyltin compounds,{[C6H5O(O)C=N-N=C(Ph)COO](m-Cl-C6H4CH2)2-Sn(CH3OH)}2(1)and{[p-Me-C6H4O(O)C=N-N=C(Ph)COO](m-Cl-C6H4CH2)2Sn(CH3OH)}2(2),have been synthesized by microwave“one pot”reaction with benzoylhydrazine(or p-methyl benzhydrazine),phenylglyoxylic acid and di-m-chlorobenzyltin dichloride.Compound 2 contains two crystals 2a and 2b.The compounds have been characterized with IR,elemental analysis,1H,13C and 119Sn NMR spectra,H RMS.Three crystals are all binuclear molecules with a Sn2O2 four-membered ring plane,and each Sn atom center is seven-coordinated with[SnO4C2N]to form a distorted pentagonal bipyramidal configuration.In vitro antitumor activities of all compounds and carboplatin were evaluated by MTT against three human cancer cells such as NCI-H460(lung cancer cells),HepG2(liver cancer cells)and MCF7(breast cancer cells),and compound 2 exhibited better antitumor activity. | 蒋伍玖 莫天姿 张复兴 邝代治 谭宇星 | 2020 | Chinese Journal of Structural Chemistry2020，39，4： | 4 |
| 2 | 具有农药活性的1,2,3-噻二唑衍生物显示文摘1,2,3-噻二唑类衍生物因其独特的生物活性受到广泛的关注。针对1,2,3-噻二唑衍生物在农药活性研究中的进展,按照其不同的结构类型进行了分类综述,对其发展趋势及前景进行了展望。 | 王威 贺红武 王储备 毛明珍 苏天铎 王列平 王海洋 宁斌科 薛超 | 2015 | 农药2015，54，7： | 0 |
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