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1Voltammetric determination of cysteamine at multiwalled carbon nanotubes paste electrode in the presence of isoproterenol as a mediator显示文摘A sensitive electrochemical sensor for the determination of cysteamine(CA) was developed using a modified multiwall carbon nanotube paste electrode(MWCNTPE) with isoproterenol(ISPT) as a mediator.This modified electrode showed very high electrocatalytic activity for the anodic oxidation of CA.Under the optimized conditions,the electrocatalytic peak current showed a linear relationship with CA concentration in the range of 0.3–450.0 mmol/L with a detection limit of 0.09 mmol/L CA.The modified electrode was used for the determination of CA in real samples such as urine and drug samples.Mohsen Keyvanfard Maryam Ahmadi Fatemeh Karimi Khadijeh Alizad 2014Chinese Chemical Letters2014,25,9:4
2Azide-functionalization of carbon nanotubes by electrochemical oxidation of N_3^-in situ显示文摘Azide-functionalization of single-walled carbon nanotubes(SWCNTs) was achieved by electrochemical oxidation of N_3^- in situ.The functionalized nanotubes were characterized in details by single internal reflection infrared spectroscopy(ATR-FTIR) and thermogravimetic analysis(TGA/MS).The results revealed that a covalent C-N bond had formed and this might provide an effective method for the preparation of azide-functionalized materials,especially carbon materials.The degree of functionalization was measured by X-ray photoelectron spectroscopy(XPS).Xiao-Tang Ji Zhong-Xue Ge Jian-Hua Bu Qing Liu Wei Wang Cheng Xu 2014Chinese Chemical Letters2014,25,2:1
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