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1Preparation of Gd-Ni alloy film in urea-NaBr melt显示文摘Electroreduction of Ni(Ⅱ) to metallic Ni in urea NaBr melt at 373 K is irreversible in one step. Gd(Ⅲ) is not reduced to Gd alone, but can be inductively codeposited with Ni(Ⅱ). The amorphous Gd Ni alloy films were obtained by potentiostatic electrolysis and galvanostatic electrolysis. With the cathode potential shift to negative direction and the increase of current density, the content of gadolinium in the alloy increases first, and then drops down gradually. The molar ratio of Gd(Ⅲ) to Ni(Ⅱ) and the time also influence the content of Gd. Crystalline GdNi 3 alloy was obtained after heat treatment of the deposit. [童叶翔 刘莉治 徐常威 刘贵华 杨绮琴 2001中国有色金属学会会刊:英文版2001,11,3:6
2显示文摘Potentiostatic and pulse electrolysis techniques were used to prepare La-Co-Fe alloy films using ethylenediamine (EN) as complexant. Surfaces of alloy films obtained by these two techniques are smooth, adhesive, compact and metallic luster. The contents of La in alloy films obtained by potentiostatic electrolysis technique are in the range of 13.23%~47.67%. The contents of La in alloy films deposited by pulse electrolysis technique are in the range of 10.67%~16.29%.Yuang, DS Huang, KS Liu, GK Tong, YX Sa, LC 2001中国有色金属学会会刊:英文版2001,11,6:0
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