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| 1 | REE geochemical characteristics and depositional environment of the black shale-hosted Baiguoyuan Ag-V deposit in Xingshan,Hubei Province,China显示文摘By means of techniques such as inductively coupled plasma-mass spectrometry (ICP-MS) and X-ray fluorescence spectrometry (XRF),REE geochemical characteristics and depositional environment of the black shales in Baiguoyuan Ag-V deposit,Xingshan,Hubei Province,were studied in this work. The black shales in a typical TC5 profile of Doushantuo Formation of upper Sinian period were obviously enriched in REE,especially in LREE. The REE patterns of the investigated samples normalized by Post Archean Australian Shale (PAAS) showed a flat or slight rightward inclination. The characteristic elements,their ratio and correlation diagrams showed that it should be hot-water deposit and the black shale in the study area was of a sedimentary origin. Redox sensitive metal elements pattern,trace elements index measurement in anoxic environment,Ce anomaly and δEu negative anomaly showed that the deposit environment of the black shales was a reducing and anoxic one and a slight change of the sea level could be identified. The samples relatively focused on the superimposed area of sedimentary rock and basalt in the diagram of La/Yb-ΣREE and La/Yb-Ce/La. So there might be accession of hot-water sedimentation during the period of the formation of the black rock series,mostly in normal terrigenous sedimentation with the participation of deep hot-water deposit. | 杨波涌 胡 斌 鲍征宇 张肇淦 | 2011 | Journal of Rare Earths2011，29，5： | 6 |
| 2 | 重庆东北城口地区黑色岩系地球化学异常模式显示文摘重庆东北城口地区黑色岩系广泛发育,主要岩性有上震旦统到下武寒统的黑色碳质粉砂岩、含碳粉砂质板岩、含碳硅质岩等,在区内进行水系沉积物测量工作取得了良好的找矿效果。以区内的黑色岩系为重点研究对象,通过对样品分析数据的综合研究,指出了区内的主要成矿元素有Mn、V、Ag、Ba等,其中Mn主要富集在灯影组和陡山沱组中,V、Ag主要富集在鲁家坪组中,Ba则富集在巴山组中,初步确定了黑色岩系的地球化学异常模式,指明了区内黑色岩系的找矿方向。 | 雷恩 王丹 杨洪永 秦林 | 2012 | 地质科技情报2012，31，2： | 4 |
| 3 | Geochemical Characterization of Organic Rich Black Rocks of the Niutitang Formation to Reconstruct the Paleoenvironmental Settings during Early Cambrian Period from Xiangxi Area,Western Hunan,China显示文摘The Niutitang Formation in the South China Block might be a source of hydrocarbon as it contains an enormous quantity of organic matter.Black rock of the Early Cambrian Niutitang Formation is widely distributed in the Yangtze region,but detailed geochemical understanding of it is still emerging.This research discusses the detailed geochemical characteristics of the Niutitang Formation to reconstruct the paleoenvironmental conditions,employing total organic carbon(TOC)content,major,trace,and rare earth element data.For this purpose,black rock specimens of the Niutitang Formation from two outcrop sections were utilized for geochemical characterization,and the results compared with another eight sections from the South China Block.The average total organic carbon in these sediments is significantly higher(5.80 wt.%).In the platform region,lower quantities of TOC indicate a poor potential to produce hydrocarbons.At the same time,significantly higher TOC is observed in the deep shelf and slope sediments,indicating a significant potential to produce hydrocarbons.The average Ce,Eu and Y anomalies from both Longbizui and Sancha sections studied are 0.74,0.86,1.77,1.07,and 1.19,1.30,respectively.The chemical index of alteration(CAI)throughout the Yangtze block is higher(averaging 71.32)than that of Post Archean Australian Shale(PAAS 69),indicating a moderately weathered source of the Niutitang Formation relative to PAAS.As the sediments are moderately weathered,this suggests these rocks might have been derived from felsic rocks,mainly granite-granodiorite.The normalization of REEs in the black rocks reveals a reduction of light REEs with increase in heavy REEs enrichment.Similarly,a positive Eu anomaly,negative Ce anomaly,and a moderate Y/Ho(34.61)are clues to a hybrid depositional mechanism associated with hydrothermal action and terrigenous input.These anomalies are also evidence of upwelling in the paleo-ocean and mixing of organic matter,which created anoxic bottom water during the deposition of the Niutitang Formation in the basin and upper oxic water conditions before deposition.The main controlling factors for the distribution of rare earth elements in these black rocks of the Niutitang Formation are pH,terrigenous input,source rock composition,tectonism,an upwelling mechanism,and hydrothermal activity. | Rizwan Sarwar Awan Chenglin Liu Ashar Khan Khawaja Hasnain Iltaf Qibiao Zang Yuping Wu Sajjad Ali Muhammad Amar Gul | 2023 | Journal of Earth Science2023，34，6： | 0 |
| 4 | Occurrence modes of silver in the Ni-Mo-PGE polymetallic layer of the Lower Cambrian black shales in Zunyi, Guizhou Province, South China显示文摘The Ni-Mo-PGE polymetallic mineralization of the Lower Cambrian black shales locate in Zunyi, South China and contain abundant noble metals such as Ag, Au and PGE, and especially Ag with average concentration of 64×10-6. The occurrence modes of Ag have been investigated using methods of selective chemical dissolution and transmission electron microscopy. The results demonstrate that the occurrence modes of Ag are complex and diversiform. It might be associated with clay minerals, organic matter, sulfides and also occurred as native silver and sulfides with nanometer in size. Combined with results of previous studies, we suggest that the sulfides, clay minerals and organic matter which hosted in the Ni-Mo-PGE polymetallic ores of black shales can play the roles of important reduction and adsorption geochemical barriers for the enrichment and distribution of silver. This study further implies that the selective chemical dissolution and transmission electron microscopy may pave the way to study the occurrence modes of other noble metals in black shales. | HAN Tao ZHU Xiaoqing LIU Shirong LI Xiaoxia | 2014 | Chinese Journal Of Geochemistry2014，33，4： | 0 |
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