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| 1 | Microfossils and molecular records in oil shales of the Songliao Basin and implications for paleo-depositional environment显示文摘Several oil shale beds, over 10 m thick, occur at the base of the first member of the Upper Cretaceous Qingshankou Formation (K2qn1) in the Songliao Basin. They act both as excellent source rocks for conventional oil and as potential oil deposit for shale oil production. Here we combine micropaleon-tology with organic geochemistry to investigate the paleo-depositional environment and organic source characteristics of the oil shales and black shales. Our results indicate that algal remains are dominant microfossils in K2qn1 oil shales, and their relatively high abundance suggests a major algal thriving event during the oil shale deposition. The presence of fresh water and brackish water species, Sentusidinium, Vesperopsis and Nyktericysta, and marine or brackish water deltaic and lagoonal species such as Kiokansium and Dinogymniopsis demonstrate that this paleo-continental lake was influenced by marine transgressions at the time of K2qn1 oil shale formation. The extremely low pristine/phytane ratios, relatively high abundance of gammacerane and 4-methyl steranes, and low δ 13C values of C14-C37 n-alkanes in the oil shale organic extracts indicate the deposition of oil shales in anoxic and highly stratified water columns and the significant contribution of lacustrine algae to sedimentary organic matter. High molecular-weight paraffinic hydrocarbons with unusually high abundance of nC43, nC45, and nC47 may be related to special algal species associated with marine transgression events. The giant water body of Songliao paleo-lake and the change in the organic and chemical environment (such as nutrition source and water column salinity) associated with seawater transgression into the lake are among the most important reasons for oil shales in the Songliao Basin being different from mudstone and oil shale in other rifted basins. | FENG ZiHui FANG Wei WANG Xue HUANG ChunYan HUO QiuLi ZHANG JuHe HUANG QingHua ZHANG Lei | 2009 | Science China Earth Sciences2009，52，10： | 12 |
| 2 | 潮水盆地和民和盆地中侏罗统青土井组煤系烃源岩有机地球化学特征及其意义显示文摘随着非常规油气资源开采技术进步以及勘探范围日益扩大,煤系烃源岩日益获得重视。潮水盆地和民和盆地作为甘肃陇中、河西地区的典型侏罗系含煤沉积代表,其生烃能力及其差异性特征研究相对欠缺,为此对两地区煤系烃源岩展开综合有机地球化学参数特征及其对比研究。生物标志物特征指示:潮水盆地青土井组煤系烃源岩有机质来源以混合输入为主,处于低熟-成熟阶段,沉积环境上段为弱氧化-弱还原滨、浅湖相,下段为弱咸化半深湖-深湖相,出现高伽马蜡烷优势,指示水体出现分层现象;民和盆地窑街组煤系烃源岩有机质来源上段以低等水生生物输入为主,下段为陆相高等植物优势输入,有机质处于低熟-成熟阶段,沉积环境倾向于典型沼泽相煤系沉积。有机质丰度和类型数据揭示:潮水盆地烃源岩有机质类型主要为Ⅱ型;民和盆地烃源岩有机质类型Ⅰ型、Ⅱ型及Ⅲ型均有出现。综合分析各项有机地球化学参数,指示潮水盆地和民和盆地均具有一定生烃潜力,相对来说以低等水生生物输入为主的民和盆地煤系烃源岩可能具有相对较大的生液态烃潜力。 | 王森 张明震 李爱静 张静 杜圳 杜宝霞 吉利民 张献文 | 2020 | 天然气地球科学2020，31，2： | 5 |
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