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| 1 | Adsorptive Recovery of Uranium from Nuclear Fuel Industrial Wastewater by Titanium Loaded Collagen Fiber显示文摘Effective recovery of UO2+2 from wastewater is essential for nuclear fuel industry and related industries.In this study,a novel adsorbent was prepared by loading titanium(Ti4+) onto collagen fiber(TICF),and its physical and chemical properties as well as adsorption to UO2+2 in nuclear fuel industrial wastewater were investigated.It is found that TICF can effectively recover UO2+2 from the wastewater with excellent adsorption capacity.The adsorption capacity is 0.62 mmol·g-1 at 303 K and pH 5.0 when the initial concentration of UO2+2 is 1.50 mmol·L-1.The adsorption isotherms can be described by the Langmuir equation and the adsorption capacity increases with temperature.The effect of co-existed F on the adsorption capacity for UO2+2 is significant,which can be eliminated by adding aluminum ions as complexing agent,while the other co-existed ions in the solutions,including HCO-3,Cl-,NO-3,Ca2+,Mg2+ and Cu2+,have little effect on the adsorption capacity for UO2+2.The saturated TICF after UO2+2 adsorption can be regenerated by using 0.2 mol·L-1 nitrate(HNO-3) as desorption agent,and the TICF can be reused at least three times.Thus the TICF is a new and effective adsorbent for the recovery of UO2+2 from the wastewater. | CHENG YuanMei SUN Xia LIAO Xuepin Sill Bi | 2011 | Chinese Journal of Chemical Engineering2011，19，4： | 5 |
| 2 | Simulation for the primary electronic donor of photosystem II in vitro显示文摘Histidine coordinated to Chl a is a distinct characteristic of Chl a in vivo. By usinghistidine analogue of 1-methylimidazole (C4H6N2) and measuring the UV/vis absorption, CD and MCD spectra of the interaction between C4H6N2and Chl a in CCI4, we have obtained that: (i) In pure CCI4 solvent, Chl a molecule is in five-coordinate state, and two Chl a molecules form an asymmetric compact-dimer with strong coupling interaction. We propose that the two Chl a molecules are connected by two unequally coordinated Mg-O bonds (the two oxygen atoms come from the C=O of C131 keto and C17 ester, respectively); (ii) when the molar ratio of C4H6N2/Chl a is 0.5 or 1 (corresponding to 2Chl a #1C4H6N2 and 2Chl a ·2C4H6N2, respectively), significant changes have been observed in the absorption, CD and MCD spectra, which indicate that the Chl a remains in dimer form, but the coupling interaction between them reduces greatly. We postulate that C4H6N2 replaces the ligation of C=O of C17 ester and C131 keto to Mg atoms | PAN Jie ZHANG Chunxi GONG Yandao LI Liangbi ZHAO Nanming KUANG Tingyun | 2000 | Chinese Science Bulletin2000，45，10： | 0 |
| 3 | The Thermal Conductivity Theory of Non-uniform Granular Flow and the Mechanism Analysis显示文摘According to the fractal characteristics appearing in non-uniform granular system, we found the fractal model to study the effective thermal conductivity in the mixed system. Considering the quasi-equilibrium, we bring forward the fractal velocity probability distribution function. The equipartition of energy is employed to the non-uniform granular system, and the granular temperature is derived. We investigate the thermal conductivity in granular flow due to the movement of the particles, namely the heat transfer induced by the streaming mode only. The thermal conductivity in the mixed system changes with the fractal parameters such as the solid fraction v, structural character parameter η, and fractal dimension D of size distribution. These parameters depict the characteristics of the thermal conductivity in the actual complex granular system. Comparing our conclusion with the correlative experimental data and the theoretical conclusion of binary mixture of granular materials, the results can qualitatively confirm the generality of our prediction on the granular system. | ZHANGDuan-Ming LEIYa-Jie YUBo-Ming PANGui-Jun | 2003 | Communications in Theoretical Physics2003，40，4X： | 0 |
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