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| 1 | Recent Advances in Nonlinear Optical Phosphate Materials显示文摘In recent years, motivated by the discovery of deep-UV(wavelengths below 200 nm) nonlinear optical(NLO) phosphates, Ba_3P_3O_(10)X(Cl, Br), phosphates have entered into a passionate research era. In this review, recently discovered phosphate materials containing different anionic groups, i.e., isolated [PO_4], [P_2O_7] dimer, [P_3O_(10)] trimer, and [PO_3]∞ chain, are summarized, including their syntheses, structures, NLO performances and properties. Especially phosphates with short absorption edges in the deep-UV region and good SHG efficiency are introduced in detail. We hope that this work will present a clear view of the crystal chemistry of phosphates and promote the discovery of new high-performing second-order NLO materials to meet the urgent needs in laser science. | 陈洁 Khan Muhammad Ali 肖传馨 鄢雨欣 代漪 陈玲 | 2017 | Chinese Journal of Structural Chemistry2017，36，11： | 2 |
| 2 | Sodium Holmium Polyphosphate NaHo(PO_3)_4 with [P_4O_(12)]^(4-)Spiral Chains: Synthesis, Crystal Structure, and Luminescent Properties显示文摘Sodium holmium polyphosphate crystal, NaHo(PO3)4, has been synthesized by the high temperature solution reaction and characterized by X-ray diffraction analysis, EDX, IR, UV-vis-NIR, and PL spectra. The structure belongs to the monoclinic system, space group P21/n with Z = 4, a = 7.181(3), b = 13.059(5) and c = 9.730(4) ?. It is described as a three-dimensional(3D) architecture made up of [P4O12]4- anionic spiral chains and HoO8 polyhedra by corner-sharing. The 8-coordinated sodium atoms are located in infinite tunnels. The results of EDX and IR spectrum are in good agreement with the crystallographic analysis. In addition, NaHo(PO3)4 exhibits visible light emission in the solid state at room temperature. | 朱静 孔慧兰 陈晖 朱忠其 | 2014 | Chinese Journal of Structural Chemistry2014，33，4： | 0 |
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