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1Geochemical characteristics and oil family classi-fication of crude oils from the Markit Slope in the southwest of the Tarim Basin, Northwest China显示文摘Based on the chromatograms of oils and saturated hydrocarbons, biomarkers and stable carbon isotope analyses, the geochemical characteristics and oil family Classification of crude oils from the Markit Slope in the southwest of the Tarim Basin were investigated. The results showed that crude oils from the Markit Slope are divided into two oil family Classification. Oils collected from the Bashituo oilfield in the western part of the Markit Slope are characterized by high contents of tricyclic terpanes, pregnane, and homopregnane, low contents of garmmacerane (G/H<0.20), dibenzofuran, and methyl cyclohexane, and light stable carbon isotopic values (the δ13C values of satu-rated hydrocarbons and aromatic components are less than -34‰ and -32‰, respectively), with the distribution type of steranes being C27>>C28 -32‰ and -30.6‰, respectively), with the distribution type of steranes being C27>C28<CUI Jmgwei WANG Tieguan LI Meijun 2011Chinese Journal Of Geochemistry2011,30,3:4
2Geochemical characteristics of aromatic hydrocarbons in saline lacustrine crude oils and their significance as exemplified by the south area of western Qaidam Basin显示文摘Based on quantitative GC-MS analysis of 40 crude oil samples collected from the south area of western Qaidam Basin,one of the largest saline lacustrine basins in China,the geochemical characteristics of aromatic hydrocarbons in oils were studied systematically in this paper.Among those constitutes,naphthalene(43% 59%),phenanthrene(12% 21%) and taromatic-sterane series(6% 28%) were the main ones of aromatic hydrocarbons.The ratio of aromatic hydrocarbon maturity parameter vs.saturated hydrocarbon maturity parameter C 29 20S/(20S+20R) shows that some aromatic hydrocarbon maturity parameters are not suitable for low-mature oils,including MPI,MNR,DNR,etc.Meanwhile,maturity parameters for dibenzothiophene and taromatic-sterane series are more appropriate for low maturity saline lacustrine crude oils.Based on the ratio of 4,6-DMDBT/1,4-DMDBT,the R c values are within the range of 0.59% 0.72%.However,the abundance of dibenzothiophene(DBT) is low,and the dibenzofuran(DBF) content is even lower,suggesting that the crude oils were formed in a saline lacustrine anaerobic environment.The high abundance of C 26 triaromatic steroid also indicates that the source material is brackish water-saline water with strong reducibility.MO Xiaoye ZHANG Min 2012Chinese Journal Of Geochemistry2012,31,4:2
3Geochemical characteristics and genetic types of crude oils from Qinjiatun and Qikeshu oilfields in the Lishu Fault Depression, Songliao Basin, northeastern China显示文摘The Qinjiatun and Qikeshu oilfields are new Mesozoic petroleum exploration targets in Lishu Fault Depression of Songliao Basin, northeastern China. Currently, researches on geochemistry of crude oils from Qinjiatun and Qikeshu oilfields have not been performed and the genesis of oils is still uncertain. Based on bulk analyses, the crude oils in the Qinjiatun and Qikeshu oilfields of Lishu Fault Depression from the Lower Cretaceous can be classified as three types. TypeⅠoils, from Quantou and Denglouku formations of Qikeshu oilfield, are characterized by high C24tetracyclic terpane/C26tricyclic terpanes ratios, low gammacerance/C30hopane ratios, tricyclic terpanes/hopanes ratios, C29Ts/C29norhopane ratios and 17α(H)-diahopane/17α(H)-hopane ratios, indicating a brackish lacustrine facies. TypeⅡoils, from Shahezi Formation of Qikeshu oilfield show low C24tetracyclic terpane/C26tricyclic terpanes, high gammacerance/C30hopane ratios, tricyclic terpanes/hopanes ratios, C29Ts/C29 norhopane and C30diahopane/C30hopane ratios, thus suggesting that they originated from source rocks deposited in a weak reducing brackish lacustrine environment, or clay-rich sediments. Type oilsⅢ, from some wells of Qikeshu oilfield have geochemical characteristics intermediate between those two types and may be mixture of typeⅠand Ⅱoils.ZENG Wei LIU Haiyu ZHANG Min 2014Chinese Journal Of Geochemistry2014,33,1:1
4Geochemical characteristics of Ordovician crude oils in the northwest of the Tahe oil field, Tarim Basin显示文摘Forty-six crude oil samples were selected from the Ordovician in the northwestern part of the Tahe oilfield for detailed molecular geochemical and isotopic analysis, including group compositions, carbonhydrogen isotopes and gas chroma-tograms of saturated hydrocarbons, as well as the characteristics of terpane, sterane and other biomarkers, indicating that crude oils are of the same origin from different districts in the Tahe oilfield and were derived from the same source kitchen (or oil source formation), i.e., mainly stemming from marine hydrocarbons. Detailed studies of oil physical properties of 25-honpane revealed that such oils have heavy or thick oil qualities due to biodegradation. Comprehensive assessment in terms of five maturity parameters shows that the oils from the Ordovician with Ro values varying from 0.80% to 1.59% are widely distributed in the northwest of the Tahe oilfield.YU Qiuhua WEN Zhigang TANG Youjun 2011Chinese Journal Of Geochemistry2011,30,1:1
5Geochemical characteristics of oils among real cores in displacement model显示文摘Physical simulation experiment on oil displacement is an important approach to understand the mechanism and efficiency of displacement. Physical simulation experiments on water-flooding and chemical flood-ing in real cores with different lithologies and physical properties, reservoir Rock-Eval, TLC-FID, GC of saturated hydrocarbon fractions and GC-MS of saturated and aromatic hydrocarbon fractions were performed to investigate differences in the geochemistry of residual oils in the cores processed by water-flooding and chemical flooding. After fine sandstone was displaced with the two methods, the preferable replacement efficiency was displayed by the chemical constitutions of residual oils. As to glutenite, water-flooding is less effective, while chemical flooding has excellent performance according to changes in chemical compounds in oils. The results showed that the geochemical characteristics of the reservoir oils and lithology and physical properties of reservoir bed need to be considered in selecting replacement methods. In addition, the geochemical parameters for residual oils slightly changed during water-flooding and chemical flooding, which suggested the water-flooding and chemical flooding could not affect the application of these parameters in geochemistry.LI Hongbo ZHANG Min 2010Chinese Journal Of Geochemistry2010,29,2:0
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