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1挥发性有机化合物催化氧化技术显示文摘基于环境友好,对使用催化氧化法去除挥发性有机化合物(VOCs)的原理、特点以及催化剂、工艺流程等研究进行综述。挥发性有机化合物完全催化氧化机理分为:Mars-van Krevelen(MVK)模型、Langmuir-Hinshelwood(L-H)模型和Eley-Rideal(E-R)模型。复合金属氧化物催化剂是研究的热点,去除VOCs的核心是使反应温度降低,即具有低温和高活性的催化剂。延长催化剂寿命、提高去除效率也可以带来良好的节能效果和降低投资成本。对于低浓度和大体积VOCs排放,可通过吸附+催化混合法先进技术实现去除,且成功应用于实践。张胜硕 武燕娟 张伟 雍晓静 张安贵 2020工业催化2020,28,4:1
2Influence of monovalent cations and CuO nanoparticles on X-nanozeolite in uranium anionic species separation from contaminated drinking water显示文摘The main purpose of this work was the modification of NaX nanozeolite using copper oxide nanoparticles and various monovalent cations such as K^+, Cs^+, and Ag^+in order to make the negatively charged zeolite surface accessible for anionic forms of uranium which are the most dominant species of uranium in the contaminated radioactive waters at natural p H. Various methods such as the X-ray fluorescence(XRF), X-ray powder diffraction(XRD), field emission scanning electron microscopy(FE-SEM), transmission electron microscopy(TEM), Fourier transform infrared spectroscopy(FT-IR), and atomic absorption spectroscopy(AAS) were used to characterize the final synthesized absorbents. Batch technique was used to study the adsorption behavior of uranium ions from polluted drinking water by Na X nanozeolite and its modified forms. In order to better understand the performance of them, the results were compared with those that were obtained for synthesizing bulk NaX zeolite and Na-form of clinoptilolite natural zeolite. Preliminary results indicated that uranium sorption increased as the loading level of CuO nanoparticles on NaX nanozeolite increased from 2.1 wt% to 11.2 wt%. In addition,from the obtained data, an increase in uranium removal efficiency resulted as charge/ionic radius ratio of exchanged cation decreased. Also, the effect of contact time, solid–liquid ratio, initial concentration and temperature on the adsorption process was studied. It is worth mentioning that, in this study, the sorption of uranium was performed under natural conditions of pH and the presence of competing cations and anions which are available in drinking waters.H.R. Shakur Kh. Rezaee Ebrahim Saraee M.R. Abdi G. Azimi 2017Chinese Journal of Chemical Engineering2017,25,6:0
3Design of Copper Oxide Nanosheets-Loaded Zeolite with Efficient Inhibition of Marine Bacteria显示文摘Copper oxide-loaded zeolite 4A nanocomposites(CuO-zeolite NCs)were successfully prepared by modifying zeolite 4A with CuSO_(4)aqueous solution as the copper source.Zeolite 4A showed an important role in hosting copper oxide,and CuO-zeolite NCs exhibited a controlled release of copper ions.XRD patterns confirmed the appearance of new diffraction peaks of copper oxide at 35.83°and 38.83°.CuO nanosheets formed on the surface of zeolite 4A were about 30–40 nm thick over a width of 200–300 nm.CuO-zeolite NCs were primarily composed of Cu,Si,Al and O,as measured by XPS.Cu 2p_(3/2) and Cu 2p_(1/2) peaks were fitted into two main peaks centered at 934.7 eV and 954.6 eV,which were attributed to Cu(II).Zeolite 4A and CuO-zeolite NC displayed reversible Langmuir isotherm(type-I)characteristics and showed maximum adsorption quantities of almost 200 cm^(3) g^(−1) at a relative pressure of 1.0 by CO_(2)adsorption-desorption experiments.The antibacterial efficiencies of the CuO-zeolite NC were 99.4%,96.7%,and 96.8%against Pseudoalteromonas tetraodonis(P.tetraodonis),Micrococcus luteus(M.luteus),and Shewanella putrefaciens(S.putrefaciens),respectively.These values showed that nano CuO-loaded zeolite 4A acted as a strong bactericide against marine bacteria.CuO-zeolite NCs can be further applied to marine antifouling coating.HOU Jin YE Yongcheng 2022Journal of Ocean University of China2022,21,5:0
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