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| 1 | 注浆成型法制备氧化钇稳定的氧化锆透氧膜及其性能显示文摘采用注浆成型法制备8%(摩尔分数)氧化钇稳定氧化锆(8YSZ)透氧膜,分析浆料特性、烧结特性和电学性能并将其用于固体透氧膜(SOM)法制备金属。结果表明:当添加4%(质量分数)柠檬酸作为8YSZ浆料分散剂时,浆料相对黏度为1.82,Zeta电位为–43.7mV。透氧膜素坯经1 700℃煅烧2 h后,物相全部转化为立方相,相对密度达到99.1%。在500℃时,1 700℃烧结成型的透氧膜总电阻最小,为149.38Ω,总电导率最大,为5.84×10–4 S/cm。该法制备的膜管经SOM法电解脱氧实验证明具有优良的控氧性能和抗熔盐侵蚀特性。 | 沈斌 邹星礼 程红伟 赖冠全 鲁雄刚 | 2015 | 硅酸盐学报2015，43，6： | 3 |
| 2 | Design of optimum solid oxide membrane electrolysis cells for metals production显示文摘Oxide to metal conversion is one of the most energy-intensive steps in the value chain for metals production.Solid oxide membrane(SOM)electrolysis process provides a general route for directly reducing various metal oxides to their respective metals,alloys,or intermetallics.Because of its lower energy use and ability to use inert anode resulting in zero carbon emission,SOM electrolysis process emerges as a promising technology that can replace the state-of-the-art metals production processes.In this paper,a careful study of the SOM electrolysis process using equivalent DC circuit modeling is performed and correlated to the experimental results.A discussion on relative importance of each resistive element in the circuit and on possible ways of lowering the rate-limiting resistive elements provides a generic guideline for designing optimum SOM electrolysis cells. | Xiaofei Guan Uday B.Pal | 2015 | Progress in Natural Science:Materials International2015，25，6： | 0 |
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