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1含杯芳烃的高分子功能材料的研究与应用显示文摘作为第三代超分子大环化合物的代表 ,杯芳烃具有特殊的分子识别能力和独特的结构易修饰性。将杯芳烃掺杂或键合于高分子材料中 ,可得到各种具有分子识别功能的高分子材料。本文综述了含杯芳烃的高分子材料在化学传感器。王丽 施宪法 胡晓均 刘宇 2002化学进展2002,14,3:6
2Sol-Gel Synthesized Adsorbents for Metal Separation显示文摘A series of organo-ceramic adsorbents have been synthesized by a sol-gel processing technique for metal ion extraction. These adsorbents generally have significantly high metal uptake capacities, good physical-chemical stabilities, and well-designed pore geometries compared to other pre-existing metal-chelating ceramic-based adsorbents. This work describes the synthesis and evaluation of pyrazole and calix[4]arene crown adsorbents for selective separation of platinum, palladium, and gold and cesium ions, respectively, from solutions. These materials exhibit mesoporous properties with high surface areas and pore volumes. The sol-gel synthesis starting with precursor silanes and titania results in gel particles of de-sired pore characteristics and high capacity and stability. Characterization studies, such as adsorption iso-therms, breakthrough curves for fixed bed operation, and material stability, show promising results for appli-cations to metal sepation.L. L. Tavlarides J. S. Lee K. H. Nam N. Agarwal 2006Tsinghua Science and Technology2006,11,2:2
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