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    题名 作者 年代 出处 被引量
1第一性原理研究α-Al_2O_3的电子结构、力学性质和德拜温度显示文摘采用基于密度泛函理论的平面波超软赝势的第一性原理方法,利用CASTEP软件计算了α-Al_2O_3的电子结构、力学性质和德拜温度。计算结果显示优化后的晶格常数与实验数据基本一致。能带结构图表明α-Al_2O_3具有典型的离子化合物特征,禁带宽度为5.964eV。计算的态密度表明α-Al_2O_3的下价带在-19.426^-15.370eV之间,态密度主要由O的2s轨道电子贡献;上价带在-7.178~0.711eV之间,态密度主要由O的2p轨道电子贡献;导带在5.698~14.977eV之间,态密度主要由Al的3s和3p轨道电子贡献。差分电荷密度分布表明α-Al_2O_3中存在离子键和共价键。力学性质的计算结果表明α-Al_2O_3的体积模量为224.885GPa,剪切模量为144.687GPa,弹性模量为357.411GPa,泊松比为0.235,各向异性指数为0.220;α-Al_2O_3剪切模量与体积模量的比值为0.643,表明α-Al_2O_3具有脆性。α-Al_2O_3的德拜温度为974.834K。燕云程 2018材料导报2018,32,A01:9
2Fabrication of ultrahigh density ZnO-Al_2O_3 ceramic composites by slip casting显示文摘The conditions of ZnO-Al2O3 aqueous suspensions and slip casting were optimized to obtain dense green compacts and further to obtain high density ZnO-Al2O3 ceramic composites.The Zeta potential of raw powders was measured.ZnO and Al2O3 powders have lower Zeta potential than-45 mV commonly at pH 8-10.3 with polyacrylic acid(PAA)added.The influence of pH and the mass fraction of the additives on the stability and fluidity of the suspensions added with PAA and polyethylene glycol(PEG) was investigated by experiments of viscosity and sedimentation.The suspensions have the lowest viscosity and the best stability at pH 9 with 0.2%PAA(mass fraction).The maximum density of green compacts is 66.6%of theoretical density(TD)with compacting and homogeneous green particles.An ultrahigh density sintered compact(>99.6%TD)could be obtained after pressureless sintering at 1 400℃for 2 h.孙宜华 熊惟皓 李晨辉 2010Transactions of Nonferrous Metals Society of China2010,20,4:6
3Microstructure and mechanical properties of ZrO_2(Y_2O_3)-Al_2O_3 nanocomposites prepared by spark plasma sintering显示文摘Zirconia (yttria)-alumina ceramic nanocomposites were fabricated from different powders by spark plasma sintering (SPS). One powder was a commercially available nanocomposite powder TZP-3Y20A, consisting of 3 mol% yttria-stabilized zirconia (3-YSZ) reinforced with 20 wt% alumina, and the other, used as a comparison, was a conventional mechanically mixed powder 3YSZ-20A, a blend made of 3 mol% yttria-stabilized zirconia powder ZrO2 (3Y) and 20 wt% -alumina powder. The effect of the sintering tem- perature on the densification, the sintering behavior, the mechanical properties and the microstructure of the composites was investigated. The results showed that the density increased with increasing sintering temperature, and thus, the mechanical properties were strengthened because of the increased densification. The nanocomposite powder TZP-3Y20A was easily sintered, and good mechanical properties were achieved as compared with the powder from the conventional mechanically mixed method, the maximum flexural strength and fracture toughness of which were 967 MPa and 5.27 MPa m1/2, respectively.Shufeng Li Hiroshi Izui Michiharu Okano Weihua Zhang Taku Watanabe 2012Particuology2012,10,3:5
4添加TiO_2和ZrO_2对火焰热喷涂Al_2O_3涂层性能的影响(英文)显示文摘采用火焰热喷涂技术在低碳钢表面上沉积制备添加25%ZrO_2(简称AZ-25)和3%TiO_2(简称AT-3)增强体的Al_2O_3涂层,对涂层的显微组织、相组成、显微硬度和摩擦学性能进行了研究。X射线衍射(XRD)结果表明,AT-3涂层的主要相组成为α-Al_2O_3,此外还含有一些亚稳的β-Al_2O_3和κ-Al_2O_3相。而AZ-25涂层的主要相组成为α-Al_2O_3,还有一些q-ZrO_2和m-ZrO_2相。在大多数实验条件下,AT-3涂层的摩擦学性能(摩擦因数、磨损率)均比AZ-25涂层要好。添加ZrO_2增强体会导致涂层的显微硬度降低,而添加TiO_2会使涂层硬度增加。Rassim YOUNES Mohand Amokrane BRADAI Abdelhamid SADEDDINE Youcef MOUADJI Ali BILEK Abderrahim BENABBAS 2016Transactions of Nonferrous Metals Society of China2016,26,5:2
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